Photochemically produced SO2 in the atmosphere of WASP-39b

S.-M.T. is supported by the European Research Council advanced grant EXOCONDENSE (no. 740963; principal investigator: R. T. Pierrehumbert). E.K.H.L. is supported by the SNSF Ambizione Fellowship grant (no. 193448). X.Z. is supported by NASA Exoplanet Research grant 80NSSC22K0236. O.V. acknowledges funding from the ANR project ‘EXACT’ (ANR-21-CE49-0008-01), from the Centre National d’Études Spatiales (CNES) and from the CNRS/INSU Programme National de Planétologie (PNP). L.D. acknowledges support from the European Union H2020-MSCA-ITN-2109 under grant no. 860470 (CHAMELEON) and the KU Leuven IDN/19/028 grant Escher. This work benefited from the 2022 Exoplanet Summer Program at the Other Worlds Laboratory (OWL) at the University of California, Santa Cruz, a programme financed by the Heising-Simons Foundation. T.D. is an LSSTC Catalyst Fellow. J.K. is an Imperial College Research Fellow. B.V.R. is a 51 Pegasi b Fellow. L.W. is an NHFP Sagan Fellow. A.D.F. is an NSF Graduate Research Fellow.Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability1. However, no unambiguous photochemical products have been detected in exoplanet atmospheres so far. Recent observations from the JWST Transiting Exoplanet Community Early Release Science Program2,3 found a spectral absorption feature at 4.05 μm arising from sulfur dioxide (SO2) in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 MJ) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of around 1,100 K (ref. 4). The most plausible way of generating SO2 in such an atmosphere is through photochemical processes5,6. Here we show that the SO2 distribution computed by a suite of photochemical models robustly explains the 4.05-μm spectral feature identified by JWST transmission observations7 with NIRSpec PRISM (2.7σ)8 and G395H (4.5σ)9. SO2 is produced by successive oxidation of sulfur radicals freed when hydrogen sulfide (H2S) is destroyed. The sensitivity of the SO2 feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of about 10× solar. We further point out that SO2 also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations.Publisher PDFPeer reviewe

Investigating Trends in Atmospheric Compositions of Cool Gas Giant Planets Using Spitzer Secondary Eclipses

We present new 3.6 and 4.5 μm secondary eclipse measurements for five cool (T 1000 K) transiting gas giant planets: HAT-P-15b, HAT-P-17b, HAT-P-18b, HAT-P-26b, and WASP-69b. We detect eclipses in at least one bandpass for all planets except HAT-P-15b. We confirm and refine the orbital eccentricity of HAT-P-17b, which is also the only planet in our sample with a known outer companion. We compare our measured eclipse depths in these two bands, which are sensitive to the relative abundances of methane versus carbon monoxide and carbon dioxide, respectively, to predictions from 1D atmosphere models for each planet. For planets with hydrogen-dominated atmospheres and equilibrium temperatures cooler than ~1000 K, this ratio should vary as a function of both atmospheric metallicity and the carbon-to-oxygen ratio. For HAT-P-26b, our observations are in good agreement with the low atmospheric metallicity inferred from transmission spectroscopy. We find that all four of the planets with detected eclipses are best matched by models with relatively efficient circulation of energy to the nightside. We see no evidence for a solar-system-like correlation between planet mass and atmospheric metallicity, but instead identify a potential (1.9σ) correlation between the inferred CH4/(CO + CO2) ratio and stellar metallicity. Our ability to characterize this potential trend is limited by the relatively large uncertainties in the stellar metallicity values. Our observations provide a first look at the brightness of these planets at wavelengths accessible to the James Webb Space Telescope, which will be able to resolve individual CH4, CO, and CO2 bands and provide much stronger constraints on their atmospheric compositions

Atmospheric Metallicity and C/O of HD 189733 b from High-resolution Spectroscopy

We present high-resolution K-band emission spectra of the quintessential hot Jupiter HD 189733 b from the Keck Planet Imager and Characterizer. Using a Bayesian retrieval framework, we fit the dayside pressure-temperature profile, orbital kinematics, mass-mixing ratios of H2O, CO, CH4, NH3, HCN, and H2S, and the 13CO/12CO ratio. We measure mass fractions of logH 2 O = − 2.0 − 0.4 + 0.4 and logCO = − 2.2 − 0.5 + 0.5 , and place upper limits on the remaining species. Notably, we find logCH4 < −4.5 at 99% confidence, despite its anticipated presence at the equilibrium temperature of HD 189733 b assuming local thermal equilibrium. We make a tentative (∼3σ) detection of 13CO, and the retrieved posteriors suggest a 12C/13C ratio similar to or substantially less than the local interstellar value. The possible 13C enrichment would be consistent with accretion of fractionated material in ices or in the protoplanetary disk midplane. The retrieved abundances correspond to a substantially substellar atmospheric C/O = 0.3 ± 0.1, while the carbon and oxygen abundances are stellar to slightly superstellar, consistent with core-accretion models which predict an inverse correlation between C/O and metallicity. The specific combination of low C/O and high metallicity suggests significant accretion of solid material may have occurred late in the formation process of HD 189733 b. © 2024. The Author(s). Published by the American Astronomical Society.Open access journalThis item from the UA Faculty Publications collection is made available by the University of Arizona with support from the University of Arizona Libraries. If you have questions, please contact us at [email protected]