Evidence for Shape Co-existence at medium spin in 76Rb

Four previously known rotational bands in 76Rb have been extended to moderate spins using the Gammasphere and Microball gamma ray and charged particle detector arrays and the 40Ca(40Ca,3pn) reaction at a beam energy of 165 MeV. The properties of two of the negative-parity bands can only readily be interpreted in terms of the highly successful Cranked Nilsson-Strutinsky model calculations if they have the same configuration in terms of the number of g9/2 particles, but they result from different nuclear shapes (one near-oblate and the other near-prolate). These data appear to constitute a unique example of shape co-existing structures at medium spins.Comment: Accepted for publication in Physics Letters

Delineation of Thermodynamic and Kinetic Factors that Control Stability in Non-fullerene Organic Solar Cells

Although non-fullerene small molecular acceptors (NF-SMAs) are dominating current research in organic solar cells (OSCs), measurements of thermodynamics drivers and kinetic factors determining their morphological stability are lacking. Here, we delineate and measure such factors in crystallizable NF-SMA blends and discuss four model systems with respect to their meta-stability and degree of vitrification. We determine for the first time the amorphous-amorphous phase diagram in an NF-SMA system and show that its deep quench depth can result in severe burn-in degradation. We estimate the relative phase behavior of four other materials systems. Additionally, we derive room-temperature diffusion coefficients and conclude that the morphology needs to be stabilized by vitrification corresponding to diffusion constants below 10−22 cm2/s. Our results show that to achieve stability via rational molecular design, the thermodynamics, glass transition temperature, diffusion properties, and related structure-function relations need to be more extensively studied and understood. In recent years, the performance of organic solar cells (OSCs) has greatly improved with the development of novel non-fullerene small molecular acceptors (NF-SMA). The rapid increase in power conversion efficiency, now surpassing 15%, highlights an immediate and increasing need to understand the longevity and lifetime of NF-OSCs. However, the field relies mainly on a laborious trial-and-error approach to select polymer:NF-SMA pairs with desirable device stability. Here, we provide a structure-property relation that explains the morphological stability and burn-in degradation due to excessive demixing or crystallization. The framework presented in our study shows that a specific balance of interactions between polymer and NF-SMA can offer a short-term solution against excessive demixing. Long-term morphological stability that also suppresses crystallization can only be achieved by freezing in the initial quenched morphology through the use of polymers and/or NF-SMAs with low flexibility. This research provides a structure-property relation that sheds light on morphological stability of NF-OSCs by using the thermodynamic and the kinetic perspectives. We show that NF-OSCs can suffer from excessive amorphous-amorphous phase separation in the blends and crystallization of NF-SMA. The former instability channel can be eliminated in systems with an optimal miscibility, whereas the excessive phase separation in low miscibility systems and NF-SMA crystallization need to be suppressed through the utilization of polymers or NF-SMAs with low flexibility

The UK Centre for Astrobiology:A Virtual Astrobiology Centre. Accomplishments and Lessons Learned, 2011-2016

Authors thank all those individuals, UK research councils, funding agencies, nonprofit organisations, companies and corporations and UK and non-UK government agencies, who have so generously supported our aspirations and hopes over the last 5 years and supported UKCA projects. They include the STFC, the Engineering and Physical Sciences Research Council (EPSRC), the Natural Environmental Research Council (NERC), the EU, the UK Space Agency, NASA, the European Space Agency (ESA), The Crown Estate, Cleveland Potash and others. The Astrobiology Academy has been supported by the UK Space Agency (UKSA), National Space Centre, the Science and Technology Facilities Council (STFC), Dynamic Earth, The Royal Astronomical Society, The Rotary Club (Shetlands) and the NASA Astrobiology Institute.The UK Centre for Astrobiology (UKCA) was set up in 2011 as a virtual center to contribute to astrobiology research, education, and outreach. After 5 years, we describe this center and its work in each of these areas. Its research has focused on studying life in extreme environments, the limits of life on Earth, and implications for habitability elsewhere. Among its research infrastructure projects, UKCA has assembled an underground astrobiology laboratory that has hosted a deep subsurface planetary analog program, and it has developed new flow-through systems to study extraterrestrial aqueous environments. UKCA has used this research backdrop to develop education programs in astrobiology, including a massive open online course in astrobiology that has attracted over 120,000 students, a teacher training program, and an initiative to take astrobiology into prisons. In this paper, we review these activities and others with a particular focus on providing lessons to others who may consider setting up an astrobiology center, institute, or science facility. We discuss experience in integrating astrobiology research into teaching and education activities.Publisher PDFPeer reviewe

Social learning in LEADER: Exogenous, endogenous and hybrid evaluation in rural development

This paper considers the relationship between the centralised exogenous, institutions and the embedded, endogenous institutions of rural governance in Europe through an examination the evaluation procedures of the European LEADER programme. LEADER is presented in the literature as progressive in terms of innovation and stakeholder engagement. Yet while the planning and management of LEADER embraces heterogeneity and participation, programmatic evaluation is centralised and held at arms length from delivery organisations. The paper reviews previous efforts to improve evaluation in LEADER and considers alternative strategies for evaluation, contrasting LEADER practice with participatory evaluation methodologies in the wider international context. Can evaluation in itself be valuable as a mode of social learning and hence a driver for endogenous development in rural communities in Europe? The paper concludes by examining the challenges in producing a hybrid form of evaluation which accommodates endogenous and exogenous values

Relações granulométricas no processo de brunimento de arroz Granulometry relationship in the rice milling process

O brunimento é uma das etapas de beneficiamento do arroz que tem grande importância sobre o rendimento de engenho. Neste trabalho, analisaram-se relações granulométricas de frações de grãos na massa de arroz e seus efeitos sobre o rendimento de engenho, durante o processo de brunimento. As amostras usadas foram 78 g de arroz descascado, tendo essas partido de amostras originais de 100 g. Foram testadas cinco relações de composição de amostras a serem brunidas, variando as quantidades de grãos quebrados e de quirera que acompanhavam a massa de grãos inteiros, que foram: 1) somente grãos inteiros; 2) 6,16 g de quebrados e 1,04 g de quirera, conforme amostra original; 3) 3,60 g de quebrados e 3,60 g de quirera adicionados aos inteiros; 4) 7,20 g de quebrados adicionados aos inteiros, e 5) 7,20 g de quirera adicionada aos inteiros. Os procedimentos foram executados com uso de engenho de provas e com classificação manual. O rendimento de engenho foi significativamente superior, após a operação de brunimento de arroz, quando existem, na massa a ser brunida, grãos quebrados e quirera, variando entre 3,60 g a 7,20 g e 1,04 g a 7,20 g, respectivamente, comparada ao brunimento da massa composta por 100% de grãos inteiros.<br>Milling yield using five different rates of broken and head rice was tested. The samples were arranged to have different amounts of big and small broken kernels in the mass of grains. The size of each fraction of broken grains was established according to the Brazilian Rules of Rice Classification. The paddy sample had 100 g and the brown rice sample had 78 g. The brown rice was milled by adding different proportions of broken kernels to make five treatments as follows: 1) only whole kernels; 2) 6.16 g of big broken kernels and 1.04 g of small broken kernels were used as they appear in the original lot; 3) 3.6 g of big broken kernels and 3.6 g of small broken kernels were added to the whole kernels; 4) 7.2 g of big broken kernels were added to the whole kernels and 5) 7.2 g of small broken kernels were added to the whole kernels. A laboratory mill was used. The classification was made manually. The percentages of broken kernels varied from 3.6% to 7.2% in the fraction of big broken kernels and from 1.04% to 7.2% in the fraction of small broken kernels, respectively. The results showed that, in the milling process using broken kernels in the mass, the head rice yield was significantly higher than when 100% of head kernels were milled