12,056 research outputs found
Inverted polymer fullerene solar cells exceeding 10% efficiency with poly(2-ethyl-2-oxazoline) nanodots on electron-collecting buffer layers
Polymer solar cells have been spotlighted due to their potential for low-cost manufacturing but their efficiency is still less than required for commercial application as lightweight/flexible modules. Forming a dipole layer at the electron-collecting interface has been suggested as one of the more attractive approaches for efficiency enhancement. However, only a few dipole layer material types have been reported so far, including only one non-ionic (charge neutral) polymer. Here we show that a further neutral polymer, namely poly(2-ethyl-2-oxazoline) (PEOz) can be successfully used as a dipole layer. Inclusion of a PEOz layer, in particular with a nanodot morphology, increases the effective work function at the electron-collecting interface within inverted solar cells and thermal annealing of PEOz layer leads to a state-of-the-art 10.74% efficiency for single-stack bulk heterojunction blend structures comprising poly[4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b:4,5-b′]dithiophene-alt-3-fluorothieno[3,4-b]thiophene-2-carboxylate] as donor and [6,6]-phenyl-C71-butyric acid methyl ester as acceptor
Topological Schr\"odinger cats: Non-local quantum superpositions of topological defects
Topological defects (such as monopoles, vortex lines, or domain walls) mark
locations where disparate choices of a broken symmetry vacuum elsewhere in the
system lead to irreconcilable differences. They are energetically costly (the
energy density in their core reaches that of the prior symmetric vacuum) but
topologically stable (the whole manifold would have to be rearranged to get rid
of the defect). We show how, in a paradigmatic model of a quantum phase
transition, a topological defect can be put in a non-local superposition, so
that - in a region large compared to the size of its core - the order parameter
of the system is "undecided" by being in a quantum superposition of conflicting
choices of the broken symmetry. We demonstrate how to exhibit such a
"Schr\"odinger kink" by devising a version of a double-slit experiment suitable
for topological defects. Coherence detectable in such experiments will be
suppressed as a consequence of interaction with the environment. We analyze
environment-induced decoherence and discuss its role in symmetry breaking.Comment: 7 pages, 4 figure
Comparison of superoxide dismutase, allopurinol, coenzyme Q10, and glutathione for the prevention of warm ischemic injury
Measurement and Particle Statistics in the Szilard Engine
A Szilard Engine is a hypothetical device which is able to extract work from
a single thermal reservoir by measuring the position of particles within the
engine. We derive the amount of work that can be extracted from such a device
in the low temperature limit. Interestingly, we show this work is determined by
the information gain of the initial measurement rather than by the number and
type of particles which constitute the working substance. Our work provides
another clear connection between information gain and extractable work in
thermodynamical processes.Comment: 4 page
Fault Models for Quantum Mechanical Switching Networks
The difference between faults and errors is that, unlike faults, errors can
be corrected using control codes. In classical test and verification one
develops a test set separating a correct circuit from a circuit containing any
considered fault. Classical faults are modelled at the logical level by fault
models that act on classical states. The stuck fault model, thought of as a
lead connected to a power rail or to a ground, is most typically considered. A
classical test set complete for the stuck fault model propagates both binary
basis states, 0 and 1, through all nodes in a network and is known to detect
many physical faults. A classical test set complete for the stuck fault model
allows all circuit nodes to be completely tested and verifies the function of
many gates. It is natural to ask if one may adapt any of the known classical
methods to test quantum circuits. Of course, classical fault models do not
capture all the logical failures found in quantum circuits. The first obstacle
faced when using methods from classical test is developing a set of realistic
quantum-logical fault models. Developing fault models to abstract the test
problem away from the device level motivated our study. Several results are
established. First, we describe typical modes of failure present in the
physical design of quantum circuits. From this we develop fault models for
quantum binary circuits that enable testing at the logical level. The
application of these fault models is shown by adapting the classical test set
generation technique known as constructing a fault table to generate quantum
test sets. A test set developed using this method is shown to detect each of
the considered faults.Comment: (almost) Forgotten rewrite from 200
Improving the Representation of Cross-Boundary Transport of Anthropogenic Pollution in East Asia Using Radon-222.
We report on 10 years of hourly atmospheric radon, CO, and SO2 observations at Gosan Station, Korea. An improved radon detector was installed during this period and performance of the detectors is compared. A technique is developed whereby the distribution of radon concentrations from a fetch region can be used to select air masses that have consistently been in direct contact with land-based emissions, and have been least diluted en route to the measurement site. Hourly radon concentrations are used to demonstrate and characterise contamination of remote-fetch pollution observations by local emissions at this key WMO GAW site, and a seasonally-varying 5-hour diurnal sampling window is proposed for
days on which diurnal cycles are evident to minimise these effects. The seasonal variability in mixing depth and
“background” pollutant concentrations are characterised. Based on a subset of observations most representative of the
important regional fetch areas for this site, and least affected by local emissions, seasonal estimates of CO and SO2 in air
masses originating from South China, North China, Korea and Japan are compared across the decade of observations. 2016, © Taiwan Association for Aerosol Researc
Atomic Layer Deposition of Ni Thin Films and Application to Area-Selective Deposition
Ni thin films were deposited by atomic layer deposition (ALD) using bis(dimethylamino-2-methyl-2-butoxo)nickel [Ni(dmamb)(2)] as a precursor and NH3 gas as a reactant. The growth characteristics and film properties of ALD Ni were investigated. Low-resistivity films were deposited on Si and SiO2 substrates, producing high-purity Ni films with a small amount of oxygen and negligible amounts of nitrogen and carbon. Additionally, ALD Ni showed excellent conformality in nanoscale via holes. Utilizing this conformality, Ni/Si core/shell nanowires with uniform diameters were fabricated. By combining ALD Ni with octadecyltrichlorosilane (OTS) self-assembled monolayer as a blocking layer, area-selective ALD was conducted for selective deposition of Ni films. When performed on the prepatterned OTS substrate, the Ni films were selectively coated only on OTS-free regions, building up Ni line patterns with 3 mu m width. Electrical measurement results showed that all of the Ni lines were electrically isolated, also indicating the selective Ni deposition. (C) 2010 The Electrochemical Society. [DOI: 10.1149/1.3504196] All rights reserved.ope
Flatband voltage control in p-metal gate metal-oxide-semiconductor field effect transistor by insertion of TiO2 layer
Titanium oxide (TiO2) layer was used to control the flatband voltage (V-FB) of p-type metal-oxide-semiconductor field effect transistors. TiO2 was deposited by plasma enhanced atomic layer deposition (PE-ALD) on hafnium oxide (HfO2) gate dielectrics. Comparative studies between TiO2 and Al2O3 as capping layer have shown that improved device properties with lower capacitance equivalent thickness (CET), interface state density (D-it), and flatband voltage (V-FB) shift were achieved by PE-ALD TiO2 capping layer.open111210sciescopu
A study on fire design accidental loads for aluminum safety helidecks
The helideck structure must satisfy the safety requirements associated with various environmental and accidental loads. Especially, there have been a number of fire accidents offshore due to helicopter collision (take-off and/or landing) in recent decades. To prevent further accidents, a substantial amount of effort has been directed toward the management of fire in the safety design of offshore helidecks. The aims of this study are to introduce and apply a procedure for quantitative risk assessment and management of fires by defining the fire loads with an applied example. The frequency of helicopter accidents are considered, and design accidental levels are applied. The proposed procedures for determining design fire loads can be efficiently applied in offshore helideck development projects
Synchronized Optical and Electronic Detection of Biomolecules Using a Low Noise Nanopore Platform
In the past two decades there has been a tremendous amount of research into the use of nanopores as single molecule sensors, which has been inspired by the Coulter counter and molecular transport across biological pores. Recently, the desire to increase structural resolution and analytical throughput has led to the integration of additional detection methods such as fluorescence spectroscopy. For structural information to be probed electronically high bandwidth measurements are crucial due to the high translocation velocity of molecules. The most commonly used solid-state nanopore sensors consist of a silicon nitride membrane and bulk silicon substrate. Unfortunately, the photoinduced noise associated with illumination of these platforms limits their applicability to high-bandwidth, high-laser-power synchronized optical and electronic measurements. Here we present a unique low-noise nanopore platform, composed of a predominately Pyrex substrate and silicon nitride membrane, for synchronized optical and electronic detection of biomolecules. Proof of principle experiments are conducted showing that the Pyrex substrates have substantially lowers ionic current noise arising from both laser illumination and platform capacitance. Furthermore, using confocal microscopy and a partially metallic pore we demonstrate high signal-to-noise synchronized optical and electronic detection of dsDNA
- …