743 research outputs found
Glyoxal 4-nitrophenylhydrazone : triple helices linked into a three-dimensional channel structure
Peer reviewedPublisher PD
The Technologizing of inhumane practices
Australia's aggressive foreign policy stance, particularly on the refugee / illegal immigrant issue has been politically successful. This paper attributes this success to a two-part strategy. The first, using the theories of Said and Barthes, is to create a "ubiquitous semiotic" that plugs into Australia’s invasion myth. Founded on fear and ignorance it demonizes a recognisable "other", the "oriental" refugee demonised as a queue jumper. The second part of the strategy responds to the daily news and public affairs programs, which scrutinize government actions, but also provide the locus of contesting political discourses. The paper deals cursorily with the first part, the ubiquitous semiotic. The tactic of technologizing the inhumane is examined using sociolinguistic analysis of a television interview involving the Australian Immigration Minister. From this, it becomes evident how the process of classification into "other" allow the logic of technocratic processes to treat people inhumanely
Hydrogen bonding in C-methylated nitroanilines : the three-dimensional framework structure of 2-methyl-4-nitroaniline
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Expected and unexpected products of reactions of 2-hydrazinylbenzothiazole with 3-nitrobenzenesulfonyl chloride in different solvents
Acknowledgements We thank the EPSRC National Crystallography Service (University of Southampton) for the X-ray data collections. Funding information MVNdS and JLW thank CNPq (Brazil) for financial support.Peer reviewedPublisher PD
A triclinic polymorph of benzanilide : disordered molecules form hydrogen-bonded chains
Peer reviewedPublisher PD
tert-Butyl 2-{[2,8-bis(trifluoromethyl)quinolin-4-yl](hydroxy)methyl}piperidine-1-carboxylate
The title molecule, C22H24F6N2O3, adopts a folded conformation whereby the carboxylate residue lies over the quinolinyl residue, with the dihedral angle between the carbamate and quinoline planes being 41.64 (7)°. Helical supramolecular C(7) chains sustained by O—H⋯O hydrogen bonds propagating along the a-axis direction feature in the crystal packing. The F atoms of one of the CF3 groups are disordered over two orientations; the major component has a site occupancy of 0.824 (7)
Benzyl 2-{[2,8-bis(trifluoromethyl)quinolin-4-yl](hydroxy)methyl}piperidine-1-carboxylate
The title molecule, C25H22F6N2O3, adopts an open conformation whereby the quinoline and carboxylate ester groups are orientated in opposite directions but to the same side of the piperidine ring so that the molecule has an approximate U-shape. The piperidine ring adopts a distorted boat conformation. In the crystal, inversion dimers linked by pairs of O—H⋯O hydrogen bonds generate R
2
2(14) loops
Hydrogen bonding in substituted nitroanilines : isolated nets in 1,3-diamino-4-nitrobenzene and continuously interwoven nets in 3,5-dinitroaniline
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Crystal Structure of the Chiral Azomethine Imine, (Z)-(S)-4-(tert-Butylcarbonylamino)-2-(2-methoxybenzylidene)-5-oxopyrazolidin-2-ium-1-ide, Obtained by the Cyclization of tert-Butyl (S)-2-[2-(methoxybenzylidene)hydrazine]-1-(hydroxymethyl)-2-oxocarbamate
Open Access via Springer Compact Agreement. The use of the NCS crystallographic service at Southampton and the valuable assistance of the staff there are gratefully acknowledged. JLW thanks FAPERJ and CNPq, Brazil for support.Peer reviewedPublisher PD
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