44 research outputs found
Gradients of vibrational coordinates from the variation of coordinates along the path of a particle
Kinematic Orbits and the Structure of the Internal Space for Systems of Five or More Bodies
The internal space for a molecule, atom, or other n-body system can be
conveniently parameterised by 3n-9 kinematic angles and three kinematic
invariants. For a fixed set of kinematic invariants, the kinematic angles
parameterise a subspace, called a kinematic orbit, of the n-body internal
space. Building on an earlier analysis of the three- and four-body problems, we
derive the form of these kinematic orbits (that is, their topology) for the
general n-body problem. The case n=5 is studied in detail, along with the
previously studied cases n=3,4.Comment: 38 pages, submitted to J. Phys.
PHYCOBILISOMES AND ISOLATED PHYCOBILIPROTEINS. EFFECT OF GLUTARDIALDEHYDE AND BENZOQUINONE ON FLUORESCENCE
The fluorescence of the biliproteins C-phycocyanin from Spirulina platensis, B-phycoerythrin
from Porphyridium cruentum and of isolated whole P. cruentum phycobilisomes is quenched in the
presence of glutardialdehyde (GA) or benzoquinone (BQ). The kinetics of fluorescence decrease thus
induced is biphasic. If GA is used as a quencher, the fluorescence can be recovered at 77 K. Contrary to
the GA-effect, only a minor recovery takes place with BQ at 77K, thus demonstrating a different
mechanism of action of GA and BQ on biliprotein
Invariant Manifolds and Collective Coordinates
We introduce suitable coordinate systems for interacting many-body systems
with invariant manifolds. These are Cartesian in coordinate and momentum space
and chosen such that several components are identically zero for motion on the
invariant manifold. In this sense these coordinates are collective. We make a
connection to Zickendraht's collective coordinates and present certain
configurations of few-body systems where rotations and vibrations decouple from
single-particle motion. These configurations do not depend on details of the
interaction.Comment: 15 pages, 2 EPS-figures, uses psfig.st
Site-selective spectroscopy and level ordering in C-phycocyanin
We present a combined fluorescence and hole-burning study of the biliprotein C-phycocyanin. Sharp zero-phonon holes compare with a broad structureless fluorescence. This finding is rationalized in terms of the special level structure in this pigment, the fast energy-transfer processes and a lack of correlation of the energies of the emissive states
THERMAL DENATURATION OF MONOMERIC AND TRIMERIC PHYCOCYANINS STUDIED BY STATIC AND SPECTROSCOPY POLARIZED TIME-RESOLVED FLUORESCENCE
C-Phycocyanin (PC) and allophycocyanin (APC). as well as the a-subunit of PC. have been
isolated from the blue-green alga (cyanobacterium). Spirulina platensis. The effects of partial thermal
denaturation of PC and of its state of aggregation have been studied by ps time-resolved, polarized
fluorescence spectroscopy. All measurements have been performed under low photon fluxes (< 10’ ’
photonsipulse x cm’) to minimize singlet-singlet annihilation processes. A complex decay is obtained
under most conditions, which can be fitted satisfactorily with a bi-exponential (7’ = 70400 ps. T? =
1000-3000 ps) for both the isotropic and the polarized part, but with different intensities and time
constants for the two decay curves. The data are interpreted in the frameworkof the model first developed
by Teak and Dale (Biochern. J. 116, 161 (1970)], which divides the spectroscopically different
chromophores in (predominantly) sensitizing (s) and fluorescing U, ones. If one assumes temperature
dependent losses in the energy transfer from the s to the f and between f chromophores. both the
biexponential nature of the isotropic fluorescence decay and the polarization data can be rationalized. In
the isotropic emission (corresponding to the population of excited states) the short lifetime is related to the
s-,f transfer. the longer one to the “free“ decay of the final acceptor(s) (= f). The polarized part is
dominated by an extremely short decay time. which is related to s+f transfer, as well as to resonance
transfer between the f-chromophores
Self-consistent anisotropic oscillator with cranked angular and vortex velocities
The Kelvin circulation is the kinematical Hermitian observable that measures
the true character of nuclear rotation. For the anisotropic oscillator, mean
field solutions with fixed angular momentum and Kelvin circulation are derived
in analytic form. The cranking Lagrange multipliers corresponding to the two
constraints are the angular and vortex velocities. Self-consistent solutions
are reported with a constraint to constant volume.Comment: 12 pages, LaTex/RevTex, Phys. Rev. C4