924 research outputs found
More Legumes for Green Manure = More Corn
Iowa State College experiments show that a lot of nitrogren can be cheaply produced by adding a legume seeding to the oats preceding corn. Research indicates every farmer could profitably make a legume seeding for green manure in every acre of oats in addition to meadow and rotation plantings
Evolution of level density step structures from 56,57-Fe to 96,97-Mo
Level densities have been extracted from primary gamma spectra for 56,57-Fe
and 96,97-Mo nuclei using (3-He,alpha gamma) and (3-He,3-He') reactions on
57-Fe and 97-Mo targets. The level density curves reveal step structures above
the pairing gap due to the breaking of nucleon Cooper pairs. The location of
the step structures in energy and their shapes arise from the interplay between
single-particle energies and seniority-conserving and seniority-non-conserving
interactions.Comment: 9 pages, including 5 figure
New features of the phase transition to superconducting state in thin films
The Halperin-Lubensky-Ma (HLM) effect of a fluctuation-induced change of the
order of phase transition in thin films of type I superconductors with
relatively small Ginzburg-Landau number is considered. Numerical data
for the free energy, the order parameter jump, the latent heat, and the
specific heat of W, Al and In are presented to reveal the influence of film
thickness and material parameters on the properties of the phase transition. We
demonstrate for the first time that in contrast to the usual notion the HLM
effect occurs in the most distinct way in superconducting films with high
critical magnetic field rather than in materials with small .
The possibility for an experimental observation of the fluctuation change of
the order of superconducting phase transition in superconducting films is
discussed.Comment: 11 pages, MikTexTeX, 3 fig, 2 Tables, corrected some typos, Submitted
J.Phys:Cond Ma
Chiral symmetry breaking in dimensionally regularized nonperturbative quenched QED
In this paper we study dynamical chiral symmetry breaking in dimensionally
regularized quenched QED within the context of Dyson-Schwinger equations. In D
< 4 dimensions the theory has solutions which exhibit chiral symmetry breaking
for all values of the coupling. To begin with, we study this phenomenon both
numerically and, with some approximations, analytically within the rainbow
approximation in the Landau gauge. In particular, we discuss how to extract the
critical coupling alpha_c = pi/3 relevant in four dimensions from the D
dimensional theory. We further present analytic results for the chirally
symmetric solution obtained with the Curtis-Pennington vertex as well as
numerical results for solutions exhibiting chiral symmetry breaking. For these
we demonstrate that, using dimensional regularization, the extraction of the
critical coupling relevant for this vertex is feasible. Initial results for
this critical coupling are in agreement with cut-off based work within the
currently achievable numerical precision.Comment: 24 pages, including 5 figures; submitted to Phys. Rev.
Staggered fermions and chiral symmetry breaking in transverse lattice regulated QED
Staggered fermions are constructed for the transverse lattice regularization
scheme. The weak perturbation theory of transverse lattice non-compact QED is
developed in light-cone gauge, and we argue that for fixed lattice spacing this
theory is ultraviolet finite, order by order in perturbation theory. However,
by calculating the anomalous scaling dimension of the link fields, we find that
the interaction Hamiltonian becomes non-renormalizable for ,
where is the bare (lattice) QED coupling constant. We conjecture that
this is the critical point of the chiral symmetry breaking phase transition in
QED. Non-perturbative chiral symmetry breaking is then studied in the strong
coupling limit. The discrete remnant of chiral symmetry that remains on the
lattice is spontaneously broken, and the ground state to lowest order in the
strong coupling expansion corresponds to the classical ground state of the
two-dimensional spin one-half Heisenberg antiferromagnet.Comment: 30 pages, UFIFT-HEP-92-1
Charge Delocalization in Self-Assembled Mixed-Valence Aromatic Cation Radicals
The spontaneous assembly of aromatic cation radicals (D+•) with their neutral counterpart (D) affords dimer cation radicals (D2+•). The intermolecular dimeric cation radicals are readily characterized by the appearance of an intervalence charge-resonance transition in the NIR region of their electronic spectra and by ESR spectroscopy. The X-ray crystal structure analysis and DFT calculations of a representative dimer cation radical (i.e., the octamethylbiphenylene dimer cation radical) have established that a hole (or single positive charge) is completely delocalized over both aromatic moieties. The energetics and the geometrical considerations for the formation of dimer cation radicals is deliberated with the aid of a series of cyclophane-like bichromophoric donors with drastically varied interplanar angles between the cofacially arranged aryl moieties. X-ray crystallography of a number of mixed-valence cation radicals derived from monochromophoric benzenoid donors established that they generally assemble in 1D stacks in the solid state. However, the use of polychromophoric intervalence cation radicals, where a single charge is effectively delocalized among all of the chromophores, can lead to higher-order assemblies with potential applications in long-range charge transport. As a proof of concept, we show that a single charge in the cation radical of a triptycene derivative is evenly distributed on all three benzenoid rings and this triptycene cation radical forms a 2D electronically coupled assembly, as established by X-ray crystallography
Ethane steam reforming over a platinum/alumina catalyst: effect of sulphur poisoning
In this study we have examined the adsorption of hydrogen sulfide and methanethiol over platinum catalysts and examined the effect of these poisons on the steam reforming of ethane. Adsorption of hydrogen sulfide was measured at 293 and 873 K. At 873 K the adsorbed state of hydrogen sulfide in the presence of hydrogen was SH rather than S, even though the Pt:S ratio was unity. The effect of 11.2 ppm hydrogen sulfide or methanethiol on the steam reforming of ethane was studied at 873 K and 20 barg. Both poisons deactivated the catalyst over a number of hours, but methanethiol was found to be more deleterious, reducing the conversion by almost an order of magnitude, possibly due to the co-deposition of sulfur and carbon. Changes in the selectivity revealed that the effect of sulfur was not uniform on the reactions occurring, with the production of methane reduced proportionally more than the other products, due to the surface sensitivity of the hydrogenolysis and methanation reactions. The water-gas shift reaction was affected to a lesser extent. No regeneration was observed when hydrogen sulfide was removed from the feedstream in agreement with adsorption studies. A slight regeneration was observed when methanethiol was removed from the feed, but this was believed to be due to the removal of carbon rather than sulfur. The overall effect of sulfur poisoning was to reduce activity and enhance hydrogen selectivity
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Quartz crystal microbalance (QCM) arrays for solution analysis
Quartz crystal microbalances (QCMs) are piezoelectric thickness-shear-mode resonators where the resonant frequency has long been known to vary linearly with the mass of rigid layers on the surface when the device is in contact with air. This reports summarizes the results from a Laboratory Directed Research and Development effort to use an array of QCMs to measure and identify volatile organic compounds (VOCs) in water solutions. A total of nine polymer-coated QCMs were tested with varying concentrations of twelve VOCs while frequency and damping voltage were measured. Results from these experiments were analyzed using a Sandia-developed pattern recognition technique called visually empirical region of influence (VERI) developed at Sandia. The VERI analyses of data with up to 16% and 50% sensitivity drifts were carried out on an array with six signals obtained from five sensors. The results indicate that better than 98% and 88% correct chemical recognition is maintained for the 16% and 50% drifts, respectively. These results indicate a good degree of robustness for these sensor films
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