802 research outputs found
Harmonic analysis of iterated function systems with overlap
In this paper we extend previous work on IFSs without overlap. Our method
involves systems of operators generalizing the more familiar Cuntz relations
from operator algebra theory, and from subband filter operators in signal
processing.Comment: 37 page
Assessing climate change impacts on live fuel moisture and wildfire risk using a hydrodynamic vegetation model
Live fuel moisture content (LFMC) plays a critical role in wildfire dynamics, but little is known about responses of LFMC to multivariate climate change, e.g., warming temperature, CO2 fertilization, and altered precipitation patterns, leading to a limited prediction ability of future wildfire risks. Here, we use a hydrodynamic demographic vegetation model to estimate LFMC dynamics of chaparral shrubs, a dominant vegetation type in fire-prone southern California. We parameterize the model based on observed shrub allometry and hydraulic traits and evaluate the model\u27s accuracy through comparisons between observed and simulated LFMC of three plant functional types (PFTs) under current climate conditions. Moreover, we estimate the number of days per year of LFMC below 79 % (which is a critical threshold for wildfire danger rating of southern California chaparral shrubs) from 1960 to 2099 for each PFT and compare the number of days below the threshold for medium and high greenhouse gas emission scenarios (RCP4.5 and 8.5). We find that climate change could lead to more days per year (5.2 %–14.8 % increase) with LFMC below 79 % between the historical (1960–1999) and future (2080–2099) periods, implying an increase in wildfire danger for chaparral shrubs in southern California. Under the high greenhouse gas emission scenario during the dry season, we find that the future LFMC reductions mainly result from a warming temperature, which leads to 9.1 %–18.6 % reduction in LFMC. Lower precipitation in the spring leads to a 6.3 %–8.1 % reduction in LFMC. The combined impacts of warming and precipitation change on fire season length are equal to the additive impacts of warming and precipitation change individually. Our results show that the CO2 fertilization will mitigate fire risk by causing a 3.5 %–4.8 % increase in LFMC. Our results suggest that multivariate climate change could cause a significant net reduction in LFMC and thus exacerbate future wildfire danger in chaparral shrub systems
A Halomethane thermochemical network from iPEPICO experiments and quantum chemical calculations
Internal energy selected halomethane cations CH3Cl+, CH2Cl2+, CHCl3+, CH3F+, CH2F2+, CHClF2+ and CBrClF2+ were prepared by vacuum ultraviolet photoionization, and their lowest energy dissociation channel studied using imaging photoelectron photoion coincidence spectroscopy (iPEPICO). This channel involves hydrogen atom loss for CH3F+, CH2F2+ and CH3Cl+, chlorine atom loss for CH2Cl2+, CHCl3+ and CHClF2+, and bromine atom loss for CBrClF2+. Accurate 0 K appearance energies, in conjunction with ab initio isodesmic and halogen exchange reaction energies, establish a thermochemical network, which is optimized to update and confirm the enthalpies of formation of the sample molecules and their dissociative photoionization products. The ground electronic states of CHCl3+, CHClF2+ and CBrClF2+ do not confirm to the deep well assumption, and the experimental breakdown curve deviates from the deep well model at low energies. Breakdown curve analysis of such shallow well systems supplies a satisfactorily succinct route to the adiabatic ionization energy of the parent molecule, particularly if the threshold photoelectron spectrum is not resolved and a purely computational route is unfeasible. The ionization energies have been found to be 11.47 ± 0.01 eV, 12.30 ± 0.02 eV and 11.23 ± 0.03 eV for CHCl3, CHClF2 and CBrClF2, respectively. The updated 0 K enthalpies of formation, ∆fHo0K(g) for the ions CH2F+, CHF2+, CHCl2+, CCl3+, CCl2F+ and CClF2+ have been derived to be 844.4 ± 2.1, 601.6 ± 2.7, 890.3 ± 2.2, 849.8 ± 3.2, 701.2 ± 3.3 and 552.2 ± 3.4 kJ mol–1, respectively. The ∆fHo0K(g) values for the neutrals CCl4, CBrClF2, CClF3, CCl2F2 and CCl3F and have been determined to be –94.0 ± 3.2, –446.6 ± 2.7, –702.1 ± 3.5, –487.8 ± 3.4 and –285.2 ± 3.2 kJ mol–1, respectively
Investigating goal conflict as a source of mixed emotions
This research investigated whether (1) the experience of mixed emotions is a consequence of activating conflicting goals and (2) mixed emotions are distinct from emotional conflict. A preliminary experiment (Study 1, N = 35) showed that an elicited goal conflict predicted more mixed emotions than a condition where the same goals were not in conflict. The second experiment was based on naturally occurring goal activation (Study 2, N = 57). This illustrated that mixed emotions were experienced more following conflicting goals compared with a facilitating goals condition—on both a direct self-report measure of mixed emotions and a minimum index measure. The results also showed that mixed emotions were different to emotional conflict. Overall, goal conflict was found to be a source of mixed emotions, and it is feasible that such states have a role in resolving personal dilemmas
On the role of the magnetic dipolar interaction in cold and ultracold collisions: Numerical and analytical results for NH() + NH()
We present a detailed analysis of the role of the magnetic dipole-dipole
interaction in cold and ultracold collisions. We focus on collisions between
magnetically trapped NH molecules, but the theory is general for any two
paramagnetic species for which the electronic spin and its space-fixed
projection are (approximately) good quantum numbers. It is shown that dipolar
spin relaxation is directly associated with magnetic-dipole induced avoided
crossings that occur between different adiabatic potential curves. For a given
collision energy and magnetic field strength, the cross-section contributions
from different scattering channels depend strongly on whether or not the
corresponding avoided crossings are energetically accessible. We find that the
crossings become lower in energy as the magnetic field decreases, so that
higher partial-wave scattering becomes increasingly important \textit{below} a
certain magnetic field strength. In addition, we derive analytical
cross-section expressions for dipolar spin relaxation based on the Born
approximation and distorted-wave Born approximation. The validity regions of
these analytical expressions are determined by comparison with the NH + NH
cross sections obtained from full coupled-channel calculations. We find that
the Born approximation is accurate over a wide range of energies and field
strengths, but breaks down at high energies and high magnetic fields. The
analytical distorted-wave Born approximation gives more accurate results in the
case of s-wave scattering, but shows some significant discrepancies for the
higher partial-wave channels. We thus conclude that the Born approximation
gives generally more meaningful results than the distorted-wave Born
approximation at the collision energies and fields considered in this work.Comment: Accepted by Eur. Phys. J. D for publication in Special Issue on Cold
Quantum Matter - Achievements and Prospects (2011
The ACE-CRIS Scintillating Optical Fiber Trajectory (SOFT) Detector: Calibrations at the NSCL and GSI
The Scintillating Optical Fiber Trajectory (SOFT) detector, the hodoscope for the Cosmic Ray Isotope Spectrometer (CRIS) on the NASA Advanced Composition Explorer, was calibrated using 155 MeV/n He, Li, C, N, 0, and Ar at the Michigan State University National Superconducting
Cyclotron Laboratory (NSCL), and 200 - 700 MeV/n C, Si, and Fe at the GSI facility in Darrnstadt. Germany. The flight instrument consists of three hodoscope fiber planes and one trigger plane. read out by an image intensified CCD camera system and by intensified photodiodes respectively. The
spatial and angular resolution of the hodoscope is described, along with the detection efficiency of both the hodoscope and trigger plane as a function of charge
The Buffer Gas Beam: An Intense, Cold, and Slow Source for Atoms and Molecules
Beams of atoms and molecules are stalwart tools for spectroscopy and studies
of collisional processes. The supersonic expansion technique can create cold
beams of many species of atoms and molecules. However, the resulting beam is
typically moving at a speed of 300-600 m/s in the lab frame, and for a large
class of species has insufficient flux (i.e. brightness) for important
applications. In contrast, buffer gas beams can be a superior method in many
cases, producing cold and relatively slow molecules in the lab frame with high
brightness and great versatility. There are basic differences between
supersonic and buffer gas cooled beams regarding particular technological
advantages and constraints. At present, it is clear that not all of the
possible variations on the buffer gas method have been studied. In this review,
we will present a survey of the current state of the art in buffer gas beams,
and explore some of the possible future directions that these new methods might
take
Successful Completion of the Top-off Upgrade of the Advanced Light Source
An upgrade of the Advanced Light Source to enable top-off operation has been completed during the last four years. The final work centered around radiation safety aspects, culminating in a systematic proof that top-off operation is equally safe as decaying beam operation. Commissioning and transition to full user operations happened in late 2008 and early 2009. Top-off operation at the ALS provides a very large increase in time-averaged brightness (by about a factor of 10) as well as improvements in beam stability. The following sections provide an overview of the radiation safety rationale, commissioning results, as well as experience in user operations
- …