3,916 research outputs found
Recommended Thermal Rate Coefficients for the C + H Reaction and Some Astrochemical Implications
We have incorporated our experimentally derived thermal rate coefficients for
C + H forming CH and CH into a commonly used astrochemical
model. We find that the Arrhenius-Kooij equation typically used in chemical
models does not accurately fit our data and use instead a more versatile
fitting formula. At a temperature of 10 K and a density of 10 cm, we
find no significant differences in the predicted chemical abundances, but at
higher temperatures of 50, 100, and 300 K we find up to factor of 2 changes.
Additionally, we find that the relatively small error on our thermal rate
coefficients, , significantly reduces the uncertainties on the
predicted abundances compared to those obtained using the currently implemented
Langevin rate coefficient with its estimated factor of 2 uncertainty.Comment: 19 pages, 5 figures. Accepted for publication in Ap
Merged-beams Reaction Studies of O + H_3^+
We have measured the reaction of O + H3+ forming OH+ and H2O+. This is one of
the key gas-phase astrochemical processes initiating the formation of water
molecules in dense molecular clouds. For this work, we have used a novel merged
fast-beams apparatus which overlaps a beam of H3+ onto a beam of ground-term
neutral O. Here, we present cross section data for forming OH+ and H2O+ at
relative energies from \approx 3.5 meV to \approx 15.5 and 0.13 eV,
respectively. Measurements were performed for statistically populated O(3PJ) in
the ground term reacting with hot H3+ (with an internal temperature of \approx
2500-3000 K). From these data, we have derived rate coefficients for
translational temperatures from \approx 25 K to \approx 10^5 and 10^3 K,
respectively. Using state-of-the-art theoretical methods as a guide, we have
converted these results to a thermal rate coefficient for forming either OH+ or
H2O+, thereby accounting for the temperature dependence of the O fine-structure
levels. Our results are in good agreement with two independent flowing
afterglow measurements at a temperature of \approx 300 K, and with a
corresponding level of H3+ internal excitation. This good agreement strongly
suggests that the internal excitation of the H3+ does not play a significant
role in this reaction. The Langevin rate coefficient is in reasonable agreement
with the experimental results at 10 K but a factor of \approx 2 larger at 300
K. The two published classical trajectory studies using quantum mechanical
potential energy surfaces lie a factor of \approx 1.5 above our experimental
results over this 10-300 K range.Comment: 43 pages, 11 figures. Submitted to the Astrophysical Journa
Modular Invariance of Finite Size Corrections and a Vortex Critical Phase
We analyze a continuous spin Gaussian model on a toroidal triangular lattice
with periods and where the spins carry a representation of the
fundamental group of the torus labeled by phases and . We find the
{\it exact finite size and lattice corrections}, to the partition function ,
for arbitrary mass and phases . Summing over phases gives
the corresponding result for the Ising model. The limits and
do not commute. With the model exhibits a {\it vortex
critical phase} when at least one of the is non-zero. In the continuum or
scaling limit, for arbitrary , the finite size corrections to are
{\it modular invariant} and for the critical phase are given by elliptic theta
functions. In the cylinder limit the ``cylinder charge''
is a non-monotonic function of that ranges from
for to zero for .Comment: 12 pages of Plain TeX with two postscript figure insertions called
torusfg1.ps and torusfg2.ps which can be obtained upon request from
[email protected]
Multiparticle entanglement and its experimental detection
We discuss several aspects of multiparticle mixed state entanglement and its
experimental detection. First we consider entanglement between two particles
which is robust against disposals of other particles. To completely detect
these kinds of entanglement, full knowledge of the multiparticle density matrix
(or of all reduced density matrixes) is required. Then we review the relation
of the separability properties of l-partite splittings of a state to its
multipartite entanglement properties. We show that it suffices to determine the
diagonal matrix elements of in a certain basis in order to detect
multiparticle entanglement properties of . We apply these observations to
analyze two recent experiments, where multiparticle entangled states of 3 (4)
particles were produced. Finally, we focus on bound entangled states
(non-separable, non-distillable states) and show that they can be activated by
joint actions of the parties. We also provide several examples which show the
activation of bound entanglement with bound entanglement.Comment: 9 pages, no figures; submitted to The Journal of Physics A:
Mathematical and General, special issue in Quantum Information and
Computatio
Relaxation and Localization in Interacting Quantum Maps
We quantise and study several versions of finite multibaker maps. Classically
these are exactly solvable K-systems with known exponential decay to global
equilibrium. This is an attempt to construct simple models of relaxation in
quantum systems. The effect of symmetries and localization on quantum transport
is discussed.Comment: 32 pages. LaTex file. 9 figures, not included. For figures send mail
to first author at '[email protected]
Generation of neutral atomic beams utilizing photodetachment by high power diode laser stacks
We demonstrate the use of high power diode laser stacks to photodetach fast
hydrogen and carbon anions and produce ground term neutral atomic beams. We
achieve photodetachment efficiencies of 7.4\% for H at a beam energy
of 10\,keV and 3.7\% for C at 28\,keV. The diode laser systems used
here operate at 975\,nm and 808\,nm, respectively, and provide high continuous
power levels of up to 2\,kW, without the need of additional enhancements like
optical cavities. The alignment of the beams is straightforward and operation
at constant power levels is very stable, while maintenance is minimal. We
present a dedicated photodetachment setup that is suitable to efficiently
neutralize the majority of stable negative ions in the periodic table
Higher Order Correlations in Quantum Chaotic Spectra
The statistical properties of the quantum chaotic spectra have been studied,
so far, only up to the second order correlation effects. The numerical as well
as the analytical evidence that random matrix theory can successfully model the
spectral fluctuatations of these systems is available only up to this order.
For a complete understanding of spectral properties it is highly desirable to
study the higher order spectral correlations. This will also inform us about
the limitations of random matrix theory in modelling the properties of quantum
chaotic systems. Our main purpose in this paper is to carry out this study by a
semiclassical calculation for the quantum maps; however results are also valid
for time-independent systems.Comment: Revtex, Four figures (Postscript files), Phys. Rev E (in press
Virtual Texture Generated using Elastomeric Conductive Block Copolymer in Wireless Multimodal Haptic Glove.
Haptic devices are in general more adept at mimicking the bulk properties of materials than they are at mimicking the surface properties. This paper describes a haptic glove capable of producing sensations reminiscent of three types of near-surface properties: hardness, temperature, and roughness. To accomplish this mixed mode of stimulation, three types of haptic actuators were combined: vibrotactile motors, thermoelectric devices, and electrotactile electrodes made from a stretchable conductive polymer synthesized in our laboratory. This polymer consisted of a stretchable polyanion which served as a scaffold for the polymerization of poly(3,4-ethylenedioxythiophene) (PEDOT). The scaffold was synthesized using controlled radical polymerization to afford material of low dispersity, relatively high conductivity (0.1 S cm-1), and low impedance relative to metals. The glove was equipped with flex sensors to make it possible to control a robotic hand and a hand in virtual reality (VR). In psychophysical experiments, human participants were able to discern combinations of electrotactile, vibrotactile, and thermal stimulation in VR. Participants trained to associate these sensations with roughness, hardness, and temperature had an overall accuracy of 98%, while untrained participants had an accuracy of 85%. Sensations could similarly be conveyed using a robotic hand equipped with sensors for pressure and temperature
Regional and oyster microenvironmental scale heterogeneity in the Pacific oyster bacterial community.
Different organs of a host represent distinct microenvironments resulting in the establishment of multiple discrete bacterial communities within a host. These discrete bacterial communities can also vary according to geographical location. For the Pacific oyster, Crassostrea gigas, the factors governing bacterial diversity and abundance of different oyster microenvironments are poorly understood. In this study, the factors shaping bacterial abundance, diversity and composition associated with the C. gigas mantle, gill, adductor muscle, and digestive gland were characterised using 16S (V3-V4) rRNA amplicon sequencing across six discrete estuaries. Both location and tissue-type, with tissue-type being the stronger determinant, were factors driving bacterial community composition. Bacterial communities from wave-dominated estuaries had similar compositions and higher bacterial abundance despite being geographically distant from one another, possibly indicating that functional estuarine morphology characteristics are a factor shaping the oyster bacterial community. Despite the bacterial community heterogeneity, examinations of the core bacterial community identified Spirochaetaceae bacteria as conserved across all sites and samples. Whereas members of the Vulcaniibacterium, Spirochaetaceae and Margulisbacteria, and Polynucleobacter were regionally conserved members of the digestive gland, gill, and mantle bacterial communities respectively. This indicates that baseline bacterial community profiles for specific locations are necessary when investigating bacterial communities in oyster health
- …