1,882 research outputs found
Past, present and futureāsample environments for materials research studies in scattering and spectroscopy; a UK perspective
Small angle x-ray scattering and x-ray absorption fine structure are two techniques that have been employed at synchrotron sources ever since their inception. Over the course of the development of the techniques, the introduction of sample environments for added value experiments has grown dramatically. This article reviews past successes, current developments and an exploration of future possibilities for these two x-ray techniques with an emphasis on the developments in the United Kingdom between 1980ā2020
Elucidating the Significance of Copper and Nitrate Speciation in Cu-SSZ-13 for NāO Formation during NHā-SCR
Unwanted N2O formation is a problem that has been noted in selective catalytic reduction (SCR) where copper zeolite catalysts are utilized. With its immense global warming potential and long-term stability, elevated atmospheric N2O has already been identified as a future challenge in the war on climate change. This paper explores the phenomenon of N2O formation during NH3-SCR over Cu-SSZ-13 catalysts, which are currently commercialized in automotive emissions control systems, and proposes a link between N2O production and the local copper environment found within the zeolite. To achieve this, a comparison is made between two Cu-SSZ-13 samples with different copper co-ordinations produced via different synthesis methods. A combination of synchrotron X-ray absorption near-edge spectroscopy, UVāvis, Raman, and density functional theory (DFT) is used to characterize the nature of copper species present within each sample. Synchrotron IR microspectroscopy is then used to compare their behavior during SCR under operando conditions and monitor the evolution of nitrate intermediates, which, along with further DFT, informs a mechanistic model for nitrate decomposition pathways. Increased N2O production is seen in the Cu-SSZ-13 sample postulated to contain a linear Cu species, providing an important correlation between the catalytic behavior of Cu-zeolites and the nature of their metal ion loading and speciation
Probability-Changing Cluster Algorithm: Study of Three-Dimensional Ising Model and Percolation Problem
We present a detailed description of the idea and procedure for the newly
proposed Monte Carlo algorithm of tuning the critical point automatically,
which is called the probability-changing cluster (PCC) algorithm [Y. Tomita and
Y. Okabe, Phys. Rev. Lett. {\bf 86} (2001) 572]. Using the PCC algorithm, we
investigate the three-dimensional Ising model and the bond percolation problem.
We employ a refined finite-size scaling analysis to make estimates of critical
point and exponents. With much less efforts, we obtain the results which are
consistent with the previous calculations. We argue several directions for the
application of the PCC algorithm.Comment: 6 pages including 8 eps figures, to appear in J. Phys. Soc. Jp
Controlling magnetic order and quantum disorder in molecule-based magnets.
We investigate the structural and magnetic properties of two molecule-based magnets synthesized from the same starting components. Their different structural motifs promote contrasting exchange pathways and consequently lead to markedly different magnetic ground states. Through examination of their structural and magnetic properties we show that [Cu(pyz)(H 2 O)(gly) 2 ](ClO 4 ) 2 may be considered a quasi-one-dimensional quantum Heisenberg antiferromagnet whereas the related compound [Cu(pyz)(gly)](ClO 4 ) , which is formed from dimers of antiferromagnetically interacting Cu 2+ spins, remains disordered down to at least 0.03 K in zero field but shows a field-temperature phase diagram reminiscent of that seen in materials showing a Bose-Einstein condensation of magnons
Controlling magnetic order and quantum disorder in molecule-based magnets
We investigate the structural and magnetic properties of two molecule-based magnets synthesized from the same starting components. Their different structural motifs promote contrasting exchange pathways and consequently lead to markedly different magnetic ground states. Through examination of their structural and magnetic properties we show that [Cu(pyz)(H2O)(gly)2](ClO4)2 may be considered a quasi-one-dimensional quantum Heisenberg antiferromagnet whereas the related compound [Cu(pyz)(gly)](ClO4), which is formed from dimers of antiferromagnetically interacting Cu2+ spins, remains disordered down to at least 0.03 K in zero field but shows a field-temperature phase diagram reminiscent of that seen in materials showing a Bose-Einstein condensation of magnons
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Combined transcriptomic-(1)H NMR metabonomic study reveals yhat monoethylhexyl phthalate stimulates adipogenesis and glyceroneogenesis in human adipocytes
Adipose tissue is a major storage site for lipophilic environmental contaminants. The environmental metabolic disruptor hypothesis postulates that some pollutants can promote obesity or metabolic disorders by activating nuclear receptors involved in the control of energetic homeostasis. In this context, monoethylhexyl phthalate (MEHP) is of particular concern since it was shown to activate the peroxisome proliferator-activated receptor Ī³ (PPARĪ³) in 3T3-L1 murine preadipocytes. In the present work, we used an untargeted, combined transcriptomic-(1)H NMR-based metabonomic approach to describe the overall effect of MEHP on primary cultures of human subcutaneous adipocytes differentiated in vitro. MEHP stimulated rapidly and selectively the expression of genes involved in glyceroneogenesis, enhanced the expression of the cytosolic phosphoenolpyruvate carboxykinase, and reduced fatty acid release. These results demonstrate that MEHP increased glyceroneogenesis and fatty acid reesterification in human adipocytes. A longer treatment with MEHP induced the expression of genes involved in triglycerides uptake, synthesis, and storage; decreased intracellular lactate, glutamine, and other amino acids; increased aspartate and NAD, and resulted in a global increase in triglycerides. Altogether, these results indicate that MEHP promoted the differentiation of human preadipocytes to adipocytes. These mechanisms might contribute to the suspected obesogenic effect of MEHP
The geometry of nonlinear least squares with applications to sloppy models and optimization
Parameter estimation by nonlinear least squares minimization is a common
problem with an elegant geometric interpretation: the possible parameter values
of a model induce a manifold in the space of data predictions. The minimization
problem is then to find the point on the manifold closest to the data. We show
that the model manifolds of a large class of models, known as sloppy models,
have many universal features; they are characterized by a geometric series of
widths, extrinsic curvatures, and parameter-effects curvatures. A number of
common difficulties in optimizing least squares problems are due to this common
structure. First, algorithms tend to run into the boundaries of the model
manifold, causing parameters to diverge or become unphysical. We introduce the
model graph as an extension of the model manifold to remedy this problem. We
argue that appropriate priors can remove the boundaries and improve convergence
rates. We show that typical fits will have many evaporated parameters. Second,
bare model parameters are usually ill-suited to describing model behavior; cost
contours in parameter space tend to form hierarchies of plateaus and canyons.
Geometrically, we understand this inconvenient parametrization as an extremely
skewed coordinate basis and show that it induces a large parameter-effects
curvature on the manifold. Using coordinates based on geodesic motion, these
narrow canyons are transformed in many cases into a single quadratic, isotropic
basin. We interpret the modified Gauss-Newton and Levenberg-Marquardt fitting
algorithms as an Euler approximation to geodesic motion in these natural
coordinates on the model manifold and the model graph respectively. By adding a
geodesic acceleration adjustment to these algorithms, we alleviate the
difficulties from parameter-effects curvature, improving both efficiency and
success rates at finding good fits.Comment: 40 pages, 29 Figure
Random-cluster multi-histogram sampling for the q-state Potts model
Using the random-cluster representation of the -state Potts models we
consider the pooling of data from cluster-update Monte Carlo simulations for
different thermal couplings and number of states per spin . Proper
combination of histograms allows for the evaluation of thermal averages in a
broad range of and values, including non-integer values of . Due to
restrictions in the sampling process proper normalization of the combined
histogram data is non-trivial. We discuss the different possibilities and
analyze their respective ranges of applicability.Comment: 12 pages, 9 figures, RevTeX
Global well-posedness of the 3-D full water wave problem
We consider the problem of global in time existence and uniqueness of
solutions of the 3-D infinite depth full water wave problem. We show that the
nature of the nonlinearity of the water wave equation is essentially of cubic
and higher orders. For any initial interface that is sufficiently small in its
steepness and velocity, we show that there exists a unique smooth solution of
the full water wave problem for all time, and the solution decays at the rate
.Comment: 60 page
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