РАЗРАБОТКА МЕСТОРОЖДЕНИЙ ГАЗОВЫХ ГИДРАТОВ ЧЕРНОМОРСКОЙ ВПАДИНЫ – АКТУАЛЬНАЯ ЗАДАЧА В СОВРЕМЕННОМ ПОИСКЕ АЛЬТЕРНАТИВНыХ ИСТОЧНИКОВ ЭНЕРГИИ НА ТЕРРИТОРИИ УКРАИНЫ

Дана коротка оцінка стану проблеми з пошуку та розвідки родовищ газових гідратів. Розглянута актуальність освоєння газових гідратів як нового джере-ла енергії на території України. Запропоновано розробляти екологічно безпе-чні схеми освоєння альтернативних джерел. Дана краткая оценка состояния вопроса по поиску и разведке месторождений газовых гидратов. Рассмотрена актуальность освоения газовых гидратов как нового источника энергии на территории Украины. Предлагается разра-батывать экологически безопасные схемы освоения альтернативных источ-ников. Short evaluation of the problem state concerning search and prospecting of gas hydrates deposits is given. Currency of gas hydrates development as new source of energy on territory of Ukraine is considered. It is proposed to develop ecologically safe schemes of alternative sources extraction

Poynting's theorem and energy conservation in the propagation of light in bounded media

Starting from the Maxwell-Lorentz equations, Poynting's theorem is reconsidered. The energy flux vector is introduced as S_e=(E x B)/mu_0 instead of E x H, because only by this choice the energy dissipation can be related to the balance of the kinetic energy of the matter subsystem. Conservation of the total energy as the sum of kinetic and electromagnetic energy follows. In our discussion, media and their microscopic nature are represented exactly by their susceptibility functions, which do not necessarily have to be known. On this footing, it can be shown that energy conservation in the propagation of light through bounded media is ensured by Maxwell's boundary conditions alone, even for some frequently used approximations. This is demonstrated for approaches using additional boundary conditions and the dielectric approximation in detail, the latter of which suspected to violate energy conservation for decades.Comment: 5 pages, RevTeX4, changes: complete rewrit

Persistent Current of Free Electrons in the Plane

Predictions of Akkermans et al. are essentially changed when the Krein spectral displacement operator is regularized by means of zeta function. Instead of piecewise constant persistent current of free electrons on the plane one has a current which varies linearly with the flux and is antisymmetric with regard to all time preserving values of $\alpha$ including $1/2$. Different self-adjoint extensions of the problem and role of the resonance are discussed.Comment: (Comment on "Relation between Persistent Currents and the Scattering Matrix", Phys. Rev. Lett. {\bf 66}, 76 (1991)) plain latex, 4pp., IPNO/TH 94-2

Coherently tunable third-order nonlinearity in a nanojunction

A possibility of tuning the phase of the third-order Kerr-type nonlinear susceptibility in a system consisting of two interacting metal nanospheres and a nonlinearly polarizable molecule is investigated theoretically and numerically. It is shown that by varying the relative inter-sphere separation, it is possible to tune the phase of the effective nonlinear susceptibility \chi^{(3)}(\omega;\omega,\omega,-\omega)$in the whole range from 0 to$2\pi$.Comment: 10 pages 5 figure

Propagation of Nonclassical Radiation through a Semiconductor Slab

Based on a microscopic derivation of the emission spectra of a bulk semiconductor we arrive at a clear physical interpretation of the noise current operators in macroscopic quantum electrodynamics. This opens the possibility to study medium effects on nonclassical radiation propagating through an absorbing or amplifying semiconductor. As an example, the propagation of an incident squeezed vacuum is analyzed.Comment: 4 pages, 2 figure

A quantum measure of coherence and incompatibility

The well-known two-slit interference is understood as a special relation between observable (localization at the slits) and state (being on both slits). Relation between an observable and a quantum state is investigated in the general case. It is assumed that the amount of ceherence equals that of incompatibility between observable and state. On ground of this, an argument is peresented that leads to a natural quantum measure of coherence, called "coherence or incompatibility information". Its properties are studied in detail making use of 'the mixing property of relative entropy' derived in this article. A precise relation between the measure of coherence of an observable and that of its coarsening is obtained and discussed from the intutitive point of view. Convexity of the measure is proved, and thus the fact that it is an information entity is established. A few more detailed properties of coherence information are derived with a view to investigate final-state entanglement in general repeatable measurement, and, more importantly, general bipartite entanglement in follow ups of this study.Comment: 19 GS pages; supercedes quant-ph/030921

Mixed-state twin observables

Twin observables, i.e. opposite subsystem observables A+ and A- that are indistinguishable in measurement in a given mixed or pure state W, are investigated in detail algebraicly and geometrically. It is shown that there is a far-reaching correspondence between the detectable (in W) spectral entities of the two operators. Twin observables are state-dependently quantum-logically equivalent, and direct subsystem measurement of one of them ipso facto gives rise to the indirect (i.e. distant) measurement of the other. Existence of nontrivial twins requires singularity of W. Systems in thermodynamic equilibrium do not admit subsystem twins. These observables may enable one to simplify the matrix representing W.Comment: 13 page

Biochemical characterization of a novel monospecific endo-β-1,4-glucanase belonging to GH Family 5 from a rhizosphere metagenomic library

Cellulases have a broad range of different industrial applications, ranging from food and beverages to pulp and paper and the biofuels area. Here a metagenomics based strategy was used to identify the cellulolytic enzyme CelRH5 from the rhizosphere. CelRH5 is a novel monospecific endo-β-1,4-glucanase belonging to the glycosyl hydrolase family 5 (GH5). Structural based modelling analysis indicated that CelRH5 is related to endo-β-1,4-glucanases derived from thermophilic microorganisms such as Thermotoga maritima, Fervidobacterium nodosum and Ruminiclostridium thermocellum sharing 30-40% amino acid sequence identity. The molecular weight of the enzyme was determined as 40.5 kDa. Biochemical analyses revealed that the enzyme displayed good activity with soluble forms of cellulose as a substrate such as ostazin brilliant red hydroxyethyl cellulose (OBR-HEC), carboxymethylcellulose (CMC), hydroxyethyl cellulose (HEC) and insoluble azurine cross-linked hydroxyethylcellulose (AZCL-HEC). The enzyme shows highest enzymatic activity at pH 6.5 with high pH tolerance, remaining stable in the pH range 4.5 – 8.5. Highest activity was observed at 40 ˚C, but CelRH5 is psychrotolerant being active and stable at temperatures below 30 ˚C. The presence of final products of cellulose hydrolysis (glucose and cellobiose) or metal ions such as Na+, K+, Li+ and Mg2+, as well as ethylenediaminetetraacetic acid (EDTA), urea, dithiothreitol (DTT), dimethyl sulfoxide (DMSO), 2-mercaptoethanol (2-ME) or glycerol, did not have a marked effect on CelRH5 activity. However, the enzyme is quite sensitive in presence of 10 mM ions Zn2+, Ni2+, Co2+, Fe3+ and reagents such as 1 M guanidine HCl, 0.1% sodium dodecyl sulphate (SDS) and 20% ethanol. Given that it is psychrotolerant and retains activity in the presence of final cellulose degradation products, metal ions and various reagents, which are common in many technological processes; CelRH5 may be potential suitability for a variety of different biotechnological applications

Population bottlenecks and the risk of parasitic and microbiological infections in the endangered saddleback (Philesturnus carunculatus) and South Island robin (Petroica a. australis)

Severe population bottlenecks and the small size of many remnant habitats may render many bird populations prone to extinction from disease outbreaks. Bottlenecks may increase inbreeding which in turn may result in a low diversity of resistance and an immune system that is impaired or defective. Thus, bottlenecked populations may be less immunocompetent and more vulnerable to microbiological and parasitic perturbations. Few studies have assessed the effect of bottlenecks on the immunocompetence of birds. In this study, I used twelve saddleback (Philesturnus carunculatus) and two New Zealand robin (Petroica a. australis) populations, to determine if the severe bottlenecks reduce the immunocompetence of birds. When I experimentally challenged the immune system of two robin populations I found that despite the two populations having similar parasite loads, robins from the severely bottlenecked Motuara Island population exhibited a significantly lower T-cell mediated immune response than the source population (Nukuwaiata Island) suggesting that birds passing through severe population bottlenecks have a compromised immunocompetence. In the saddleback, severe bottlenecks, as well as high population densities and small island size, lead to individuals exhibiting higher stress levels and feather mite loads and lower immune function, as was evident by lower lymphocyte counts. I did not find levels of fluctuating asymmetry of saddlebacks to be directly influenced by bottleneck size. However, I did find that individuals with higher levels of fluctuating asymmetry had higher loads of hippoboscid flies and lower loads of coccidia suggesting a possible trade-off between growth and immune function. In contrast to previous studies looking at behavioural secondary sexual traits, I found no effect of founder number on the size of wattles in saddleback. I did however demonstrate that wattle size reflected the level of immune function in females as well as males, suggesting that females play a far greater role in offspring fitness than has been appreciated in traditional theories of sexual selection. Overall, my results indicate that severe bottlenecks can lead to reductions in immunocompetence in the resulting populations, especially in those populations that pass through the most severe bottlenecks. Based on the evidence from my thesis, I recommend conservation managers should aim to use at least 90 individuals to found new populations in order to reduce the deleterious effects of bottlenecks on immune function. If the costs of population bottlenecks and inbreeding are to be avoided, conservationists must adequately address the role of genetic factors in susceptibility to disease, and work towards minimising the risk of severe population bottlenecks in the management of endangered bird

Generalized gradient expansions in quantum transport equations

Gradient expansions in quantum transport equations of a Kadanoff-Baym form have been reexamined. We have realized that in a consistent approach the expansion should be performed also inside of the self-energy in the scattering integrals of these equations. In the first perturbation order this internal expansion gives new correction terms to the generalized Boltzman equation. These correction terms are found here for several typical systems. Possible corrections to the theory of a linear response to weak electric fields are also discussed.Comment: 20 pages, latex, to appear in Journal of Statistical Physics, March (1997