P2-type Na2/3Ni1/3Mn2/3O2 Cathode Material with Excellent Rate and Cycling Performance for Sodium-Ion Batteries

P2-type Na2/3Ni1/3Mn2/3O2 is an air-stable cathode material for sodium-ion batteries. However, it suffers irreversible P2-O2 phase transition in 4.2-V plateau and shows poor cycling stability and rate capability within this plateau. To evaluate the practicability of this material in 2.3–4.1 V voltage range, single-crystal micro-sized P2-type Na2/3Ni1/3Mn2/3O2 with high rate capability and cycling stability is synthesized via polyvinylpyrrolidone (PVP)-combustion method. The electrochemical performance is evaluated by galvanostatic charge-discharge tests. The kinetics of Na+ intercalation/deintercalation is studied detailly with potential intermittent titration technique (PITT), galvanostatic intermittent titration technique (GITT) and cyclic voltammetry (CV). The discharge capacity at 0.1 C in 2.3–4.1 V is 87.6 mAh g−1. It can deliver 91.5% capacity at 40 C rate and keep 89% after 650 cycles at 5C. The calculated theoretical energy density of full cell with hard carbon anode is 210 Wh kg−1. The moderate energy density associated with high power density and long cycle life is acceptable for load adjustment of new-energy power, showing the prospect of practical application

Quantum Reciprocity Conjecture for the Non-Equilibrium Steady State

By considering the lack of history dependence in the non-equilibrium steady state of a quantum system we are led to conjecture that in such a system, there is a set of quantum mechanical observables whose retarded response functions are insensitive to the arrow of time, and which consequently satisfy a quantum analog of the Onsager reciprocity relations. Systems which satisfy this conjecture can be described by an effective Free energy functional. We demonstrate that the conjecture holds in a resonant level model of a multi-lead quantum dot.Comment: References revised to take account of related work on Onsager reciprocity in mesoscopics by Christen, and in hydrodynamics by Mclennan, Dufty and Rub

The Luminosity Function of high-redshift QSOs - A combined analysis of GOODS and SDSS

Aims: In this work the luminosity function of QSOs is measured in the redshift range 3.5<z<5.2 for the absolute magnitude interval -21<M_{145}<-28. The determination of the faint end of the luminosity function at these redshifts provides important constraints on models of joint evolution of galaxies and AGNs. Methods: We have defined suitable criteria to select faint QSOs in the GOODS fields, checking in detail their effectiveness and completeness. Spectroscopic follow-up of the resulting QSO candidates has been carried out. The confirmed sample of faint QSOs is compared with a brighter one derived from the SDSS. We have used a Monte-Carlo technique to estimate the properties of the luminosity function, checking various parameterizations for its shape and evolution. Results: Models based on Pure Density Evolution show better agreement with observation than models based on Pure Luminosity Evolution. However a different break magnitude with respect to z~2.1 is required at 3.5<z<5.2. Models with a steeper faint end score a higher probability. We do not find any evidence for a flattening of the bright end at redshift z>3.5. Conclusions: The estimated space density evolution of QSOs indicates a suppression of the formation and/or feeding of Supermassive Black Holes at these redshifts. The QSO contribution to the UV background is insufficient to ionize the IGM at 3.5<z<5.2.Comment: 17 pages, 13 ps figures, A&A accepted. Updated to journal versio