635 research outputs found
Multiple-scattering effects on incoherent neutron scattering in glasses and viscous liquids
Incoherent neutron scattering experiments are simulated for simple dynamic
models: a glass (with a smooth distribution of harmonic vibrations) and a
viscous liquid (described by schematic mode-coupling equations). In most
situations multiple scattering has little influence upon spectral
distributions, but it completely distorts the wavenumber-dependent amplitudes.
This explains an anomaly observed in recent experiments
Vibrational States of Glassy and Crystalline Orthotherphenyl
Low-frequency vibrations of glassy and crystalline orthoterphenyl are studied
by means of neutron scattering. Phonon dispersions are measured along the main
axes of a single crystal, and the corresponding longitudinal and transversal
sound velocities are obtained. For glassy and polycrystalline samples, a
density of vibrational states is determined and cross-checked against other
dynamic observables. In the crystal, low-lying zone-boundary modes lead to an
excess over the Debye density of states. In the glass, the boson peak is
located at even lower frequencies. With increasing temperature, both glass and
crystal show anharmonicity.Comment: 7 pages of LaTeX (svjour), 2 tables, 10 figures accepted in Eur.
Phys. J.
The Dynamic Transition of Protein Hydration Water
Thin layers of water on biomolecular and other nanostructured surfaces can be
supercooled to temperatures not accessible with bulk water. Chen et al. [PNAS
103, 9012 (2006)] suggested that anomalies near 220 K observed by quasi-elastic
neutron scattering can be explained by a hidden critical point of bulk water.
Based on more sensitive measurements of water on perdeuterated phycocyanin,
using the new neutron backscattering spectrometer SPHERES, and an improved data
analysis, we present results that show no sign of such a fragile-to-strong
transition. The inflection of the elastic intensity at 220 K has a dynamic
origin that is compatible with a calorimetric glass transition at 170 K. The
temperature dependence of the relaxation times is highly sensitive to data
evaluation; it can be brought into perfect agreement with the results of other
techniques, without any anomaly.Comment: 4 pages, 3 figures. Phys. Rev. Lett. (in press
Atomic Transport in Dense, Multi-Component Metallic Liquids
Pd43Ni10Cu27P0 has been investigated in its equilibrium liquid state with
incoherent, inelastic neutron scattering. As compared to simple liquids, liquid
PdNiCuP is characterized by a dense packing with a packing fraction above 0.5.
The intermediate scattering function exhibits a fast relaxation process that
precedes structural relaxation. Structural relaxation obeys a time-temperature
superposition that extends over a temperature range of 540K. The mode-coupling
theory of the liquid to glass transition (MCT) gives a consistent description
of the dynamics which governs the mass transport in liquid PdNiCuP alloys. MCT
scaling laws extrapolate to a critical temperature Tc at about 20% below the
liquidus temperature. Diffusivities derived from the mean relaxation times
compare well with Co diffusivities from recent tracer diffusion measurements
and diffsuivities calculated from viscosity via the Stokes-Einstein relation.
In contrast to simple metallic liquids, the atomic transport in dense, liquid
PdNiCuP is characterized by a drastical slowing down of dynamics on cooling, a
q^{-2} dependence of the mean relaxation times at intermediate q and a
vanishing isotope effect as a result of a highly collective transport
mechanism. At temperatures as high as 2Tc diffusion in liquid PdNiCuP is as
fast as in simple liquids at the melting point. However, the difference in the
underlying atomic transport mechanism indicates that the diffusion mechanism in
liquids is not controlled by the value of the diffusivity but rather by that of
the packing fraction
Thermalization via Heat Radiation of an Individual Object Thinner than the Thermal Wavelength
Modeling and investigating the thermalization of microscopic objects with
arbitrary shape from first principles is of fundamental interest and may lead
to technical applications. Here, we study, over a large temperature range, the
thermalization dynamics due to far-field heat radiation of an individual,
deterministically produced silica fiber with a predetermined shape and a
diameter smaller than the thermal wavelength. The temperature change of the
subwavelength-diameter fiber is determined through a measurement of its optical
path length in conjunction with an ab initio thermodynamic model of the fiber
structure. Our results show excellent agreement with a theoretical model that
considers heat radiation as a volumetric effect and takes the emitter shape and
size relative to the emission wavelength into account
Propylene Carbonate Reexamined: Mode-Coupling Scaling without Factorisation ?
The dynamic susceptibility of propylene carbonate in the moderately viscous
regime above is reinvestigated by incoherent neutron and
depolarised light scattering, and compared to dielectric loss and solvation
response. Depending on the strength of relaxation, a more or less
extended scaling regime is found. Mode-coupling fits yield consistently
and K, although different positions of the
susceptibility minimum indicate that not all observables have reached the
universal asymptotics
Harmonic behavior of metallic glasses up to the metastable melt
In two amorphous alloys ZrTiCuNiBe and ZrAlNiCu coherent neutron scattering has been measured over five decades in energy, including measurements in the metastable melt of a metallic alloy more than 80 K above Tg. In the vibrational spectra a pronounced "boson" peak is found: Even in crystallized samples the density of states exceeds the Debye ω2 model, and in the amorphous state low-frequency vibrations are further enhanced. The peak position shows no dispersion in q, while intensities are strongly correlated with the static structure factor. Over the full energy range the temperature dependence is strictly harmonic. From high-energy resolution measurements we establish lower bounds for the temperatures at which structural α and fast β relaxation become observable
Molecular mode-coupling theory applied to a liquid of diatomic molecules
We study the molecular mode coupling theory for a liquid of diatomic
molecules. The equations for the critical tensorial nonergodicity parameters
and the critical amplitudes of the - relaxation
are solved up to a cut off = 2 without any
further approximations.
Here are indices of spherical harmonics. Contrary to previous studies,
where additional approximations were applied, we find in agreement with
simulations, that all molecular degrees of freedom vitrify at a single
temperature . The theoretical results for the non ergodicity parameters
and the critical amplitudes are compared with those from simulations. The
qualitative agreement is good for all molecular degrees of freedom. To study
the influence of the cut off on the non ergodicity parameter, we also calculate
the non ergodicity parameters for an upper cut off . In addition we
also propose a new method for the calculation of the critical nonergodicity
parameterComment: 27 pages, 17 figure
Reorientational relaxation of a linear probe molecule in a simple glassy liquid
Within the mode-coupling theory (MCT) for the evolution of structural
relaxation in glass-forming liquids, correlation functions and susceptibility
spectra are calculated characterizing the rotational dynamics of a top-down
symmetric dumbbell molecule, consisting of two fused hard spheres immersed in a
hard-sphere system. It is found that for sufficiently large dumbbell
elongations, the dynamics of the probe molecule follows the same universal
glass-transition scenario as known from the MCT results of simple liquids. The
-relaxation process of the angular-index-j=1 response is stronger,
slower and less stretched than the one for j=2, in qualitative agreement with
results found by dielectric-loss and depolarized-light-scattering spectroscopy
for some supercooled liquids. For sufficiently small elongations, the
reorientational relaxation occurs via large-angle flips, and the standard
scenario for the glass-transition dynamics is modified for odd-j responses due
to precursor phenomena of a nearby type-A MCT transition. In this case, a major
part of the relaxation outside the transient regime is described qualitatively
by the -relaxation scaling laws, while the -relaxation scaling
law is strongly disturbed.Comment: 40 pages. 10 figures as GIF-files, to be published in Phys. Rev.
Fast relaxation in a fragile liquid under pressure
The incoherent dynamic structure factor of ortho-terphenyl has been measured
by neutron time-of-flight and backscattering technique in the pressure range
from 0.1 MPa to 240 MPa for temperatures between 301 K and 335 K.
Tagged-particle correlations in the compressed liquid decay in two steps. The
alpha-relaxation lineshape is independent of pressure, and the relaxation time
proportional to viscosity. A kink in the amplitude f_Q(P) reveals the onset of
beta relaxation. The beta-relaxation regime can be described by the
mode-coupling scaling function; amplitudes and time scales allow a consistent
determination of the critical pressure P_c(T). alpha and beta relaxation depend
in the same way on the thermodynamic state; close to the mode-coupling
cross-over, this dependence can be parametrised by an effective coupling Gamma
~ n*T**{-1/4}.Comment: 4 Pages of RevTeX, 4 figures (submitted to Physical Review Letters
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