Organic acids and selected nitrogen species for ABLE-3

The NASA Global Tropospheric Experiment (GTE) executed airborne science missions aboard the NASA Wallops Electra (NA429) in the North American high latitude (greater than 45 deg North) atmosphere during Jul. to Aug. 1988 and Jul. to Aug. 1990. These missions were part of GTE's Atmospheric Boundary Layer Experiment (ABLE). The 1988 mission , ABLE-3A, examined the ecosystems of Alaska as a source and/or sink for important tropospheric gases and particles, and gained new information on the chemical composition of the Arctic atmosphere during the summertime. During 1990 the second high latitude mission, ABLE-3B, focused on the Hudson Bay Lowland and Labrador regions of Canada. Both of these missions provided benchmark data sets on atmosphere biosphere exchange and atmospheric chemistry over largely uninhabited regions of North America. In support of the GTE/ABLE-3A and -3B field missions, the University of New Hampshire flew instrumentation aboard the Wallops Electra research aircraft to provide measurements of the trace gases nitric (HNO3), formic (HCOOH), and acetic (CH3COOH) acid. In addition, measurements were conducted to determine the major water soluble ionic composition of the atmospheric aerosol. For ABLE-3B, groundbased measurements of the acidic trace gases were also performed from the NASA micrometerological tower situated at Schefferville, Laborador. These measurements were aimed at assessing dry deposition of acidic gases to the taiga ecosystem in the Laborador region of Canada

Evolution Of Galaxies .4. Highly Flattened Disks

NSF GP-18335, GP-32051Astronom

Evolution Of Galaxies .2. Chemical Evolution Coefficients

NSF GP-18355, GP-32051Astronom

Research opportunities on immunocompetence in space

The most significant of the available data on the effects of space flight on immunocompetences and the potential operational and clinical significance of reported changes are as follows: (1) reduced postflight blastogenic response of peripheral lymphocytes from space crew members; (2) postflight neutrophilia persisting up to 7 days; (3) gingival inflammation of the Skylab astronauts; (4) postflight lymphocytopenia, eosinopenia, and monocytopenia; (5) modifications and shifts in the microflora of space crews and spacecraft; and (6) microbial contamination of cabin air and drinking water. These responses and data disclose numerous gaps in the knowledge that is essential for an adequate understanding of space-related changes in immunocompetence

Measurements of nitric acid, carboxylic acids, and selected aerosol species for the NASA/GTE Pacific Mission - West (PEM-WEST)

The research investigation funded through this grant to the University of New Hampshire was performed during a major field expedition conducted by the NASA Tropospheric Chemistry Program. The NASA Global Tropospheric Experiment (GTE) executed an airborne science mission (PEM-WEST A) aboard the NASA Ames DC-8 over the Pacific Ocean during Sep./Oct. 1981. The atmosphere over the central Pacific Ocean is the only major region in the Northern Hemisphere that is relatively free from direct anthropogenic influence. Thus, this environment is ideally suited to study the natural biogeochemical cycles of carbon, nitrogen, ozone, sulfur, and aerosols without serious confounding problems related to anthropogenic emissions. Asian sources account for about 17 percent of the global budgets of nitrogen oxides (NO(x)) and sulfur dioxide (SO2). The Pacific Rim region therefore provides the opportunity to study the anthropogenic impact on natural atmospheric chemical cycles. The PEM-WEST A flights were focused on contrasting the chemistry of 'clean' air over the central Pacific with anthropogenically impacted air advected off the Asian continent. The principal objectives of PEM-WEST A were to investigate the atmospheric chemistry of ozone (O3) and its precursors, and to study important aspects of the atmospheric sulfur cycle over the western Pacific Ocean. Measurements conducted by the University of New Hampshire contributed directly to both of these objectives. Subsequent PEM-WEST field missions are planned by GTE in the mid-1990's to contrast atmospheric chemistry documented during PEM-WEST A with other time periods. This report presents preliminary findings from the PEM-WEST A field mission. Data interpretation is currently ongoing with the goal of manuscript submission of scientific results to a special issue of the Journal of Geophysical Research-Atmospheres in Feb. 1994. The reader is strongly encouraged to review this suite of profession articles to appreciate the overall scientific findings and benefits of the PEM-WEST A field mission

Landing approach evaluation of an integrated CRT display for general aviation aircraft

A flight director adaptable to general aviation aircraft was evaluated for the landing approach task in a twin turbojet business aircraft. The flight director combined aircraft heading, pitch and roll atitude, and ILS (Instrument Landing System) signals into a single picture on a small cathode ray tube (CRT) to give the pilot an integrated picture of the aircraft situation. The display is unique in that it presents the information on a CRT and gives quasi-command signals to the pilot. The particular display investigated was a preproduction version of the Kaiser Model FP-50 flight director. Approaches made with visual references only, with a conventional ILS displacement instrument, and with the CRT display were compared in terms of tracking performance and pilot workload. Tracking performance of three research pilots using the CRT display was superior to that using the conventional ILS instrument and comparable to that under VFR conditions. Pilot workload (based on pilot comments) was not clearly decreased

Wetlands: A potentially significant source of atmospheric methyl bromide and methyl chloride

Tropospheric methyl bromide (CH3Br) and methyl chloride (CH3Cl) are significant sources of ozone (O3) destroying halogens to the stratosphere. Their O3 depletion potential (ODP) can be determined from atmospheric lifetimes and therefore their atmospheric budgets, both of which are out of balance with known sink terms larger than identified sources. We have discovered a new source of CH3Br and CH3Cl emissions to the atmosphere at two wetland sites in the Northeastern United States. We have reason to believe that these compounds are biologically produced in situ. Our measurements indicate that the global annual flux of CH3Br and CH3Cl from wetlands could be as high as 4.6 Gg yr−1 Of CH3Br and 48 Gg yr−1 of CH3Cl. These are preliminary estimates based on measurements made during the end of the 1998 growing season, a time period of decreased emissions of other trace gases such as methane (CH4)

Rethinking Civil Liberties under the Washington State Constitution

In 1986 the Washington Supreme Court set forth six criteria for courts to apply in determining whether the state constitution affords broader protection for civil liberties than the federal Constitution. While making progress toward an independent interpretation of the state constitution, Washington courts remain overly dependent on federal precedent. This Comment explores Washington\u27s approach to independent analysis of the state constitution by examining a recent Washington case extending a privacy interest to an individual\u27s garbage. Washington\u27s approach needs to be modified to emphasize independent analysis of the state constitution and thereby give effect to Washington\u27s unique and vital constitutional heritage

Optimization and Synthesis of Silver Nanoparticles Embedded Within a Porous Substrate for Raman Spectroscopy

Raman spectroscopy is a promising method for detection of a wide range of water contaminants. Raman spectroscopy’s growing list of applications relies upon signal enhancement achieved in recent years. A test strip or substrate designed to optimize Raman spectra, capable of withholding water and enhancing signal, would be a useful tool for applications including water quality tests. Signal enhancement may be achieved by the addition of silver nanoparticles (NPs) into a three-dimensional structure of cellulose nanofibers (CNF). The magnitude of signal enhancement may be related to nanoparticle size and morphology, and so control over the synthesis of silver nanoparticles could prove essential to this emerging technology. Particle diameter may be controlled by careful selection and concentration adjustment of the reducing agent in addition to varying the reaction’s duration. In addition to the resulting size, the reliability of the signal would rely upon its reproducibility, which would in turn be affected by the size distribution of nanoparticles produced, as well as their even dispersion within the test strip. To produce a nanoparticle engineered for use within a cellulose nanofiber substrate, a number of these parameters were investigated

Advanced Stochastic Collocation Methods for Polynomial Chaos in RAVEN

As experiment complexity in fields such as nuclear engineering continually increases, so does the demand for robust computational methods to simulate them. In many simulations, input design parameters and intrinsic experiment properties are sources of uncertainty. Often small perturbations in uncertain parameters have significant impact on the experiment outcome. For instance, in nuclear fuel performance, small changes in fuel thermal conductivity can greatly affect maximum stress on the surrounding cladding. The difficulty quantifying input uncertainty impact in such systems has grown with the complexity of numerical models. Traditionally, uncertainty quantification has been approached using random sampling methods like Monte Carlo. For some models, the input parametric space and corresponding response output space is sufficiently explored with few low-cost calculations. For other models, it is computationally costly to obtain good understanding of the output space. To combat the expense of random sampling, this research explores the possibilities of using advanced methods in Stochastic Collocation for generalized Polynomial Chaos (SCgPC) as an alternative to traditional uncertainty quantification techniques such as Monte Carlo (MC) and Latin Hypercube Sampling (LHS) methods for applications in nuclear engineering. We consider traditional SCgPC construction strategies as well as truncated polynomial spaces using Total Degree and Hyperbolic Cross constructions. We also consider applying anisotropy (unequal treatment of different dimensions) to the polynomial space, and offer methods whereby optimal levels of anisotropy can be approximated. We contribute development to existing adaptive polynomial construction strategies. Finally, we consider High-Dimensional Model Reduction (HDMR) expansions, using SCgPC representations for the subspace terms, and contribute new adaptive methods to construct them. We apply these methods on a series of models of increasing complexity. We use analytic models of various levels of complexity, then demonstrate performance on two engineering-scale problems: a single-physics nuclear reactor neutronics problem, and a multiphysics fuel cell problem coupling fuels performance and neutronics. Lastly, we demonstrate sensitivity analysis for a time-dependent fuels performance problem. We demonstrate the application of all the algorithms in RAVEN, a production-level uncertainty quantification framework