495 research outputs found
Analysis of a turbine rotor containing a transverse crack at Oak Creek Unit 17
Transient increases in one, two and three per revolution vibration characteristics of a low pressure steam turbine were observed during steam temperature reduction operations. Vibration and fracture mechanics analyses suggested the presence of a transverse shaft crack which was eventually identified by ultrasonic inspection and confirmed by destructive sectioning. Signature analyses of vibration data recorded over a two-year period prior to crack identification are correlated with fatigue crack growth, which occurred intermittently during transient temperature decreases. The apparent increased response of the rotor to vibration is due to asymmetric stiffness changes introduced by the growing transverse crack. The vibration response is predicted to increase with increasing crack depths in excess of 10% of the shaft diameter. Fracture mechanics analyses predict that fatigue crack growth occurred during periods of steam temperature decrease, when high surface tensile stresses are present. These same transient thermal stresses are shown to have retarded and prevented subsequent fatigue crack growth during steady operation
Second Order Correlation Function of a Phase Fluctuating Bose-Einstein Condensate
The coherence properties of phase fluctuating Bose-Einstein condensates are
studied both theoretically and experimentally. We derive a general expression
for the N-particle correlation function of a condensed Bose gas in a highly
elongated trapping potential. The second order correlation function is analyzed
in detail and an interferometric method to directly measure it is discussed and
experimentally implemented. Using a Bragg diffraction interferometer, we
measure intensity correlations in the interference pattern generated by two
spatially displaced copies of a parent condensate. Our experiment demonstrates
how to characterize the second order correlation function of a highly elongated
condensate and to measure its phase coherence length.Comment: 22 pages, 5 figure
Characterization and control of phase fluctuations in elongated Bose-Einstein condensates
Quasi one dimensional Bose-Einstein condensates (BECs) in elongated traps
exhibit significant phase fluctuations even at very low temperatures. We
present recent experimental results on the dynamic transformation of phase
fluctuations into density modulations during time-of-flight and show the
excellent quantitative agreement with the theoretical prediction. In addition
we confirm that under our experimental conditions, in the magnetic trap density
modulations are strongly suppressed even when the phase fluctuates. The paper
also discusses our theoretical results on control of the condensate phase by
employing a time-dependent perturbation. Our results set important limitations
on future applications of BEC in precision atom interferometry and atom optics,
but at the same time suggest pathways to overcome these limitations.Comment: 9 pages, 7 figure
Introduction of a pyramid guiding process for general musculoskeletal physical rehabilitation
Successful instruction of a complicated subject as Physical Rehabilitation demands organization. To understand principles and processes of such a field demands a hierarchy of steps to achieve the intended outcome. This paper is intended to be an introduction to a proposed pyramid scheme of general physical rehabilitation principles. The purpose of the pyramid scheme is to allow for a greater understanding for the student and patient. As the respected Food Guide Pyramid accomplishes, the student will further appreciate and apply supported physical rehabilitation principles and the patient will understand that there is a progressive method to their functional healing process
Perturbation theory for anisotropic dielectric interfaces, and application to sub-pixel smoothing of discretized numerical methods
We derive a correct first-order perturbation theory in electromagnetism for
cases where an interface between two anisotropic dielectric materials is
slightly shifted. Most previous perturbative methods give incorrect results for
this case, even to lowest order, because of the complicated discontinuous
boundary conditions on the electric field at such an interface. Our final
expression is simply a surface integral, over the material interface, of the
continuous field components from the unperturbed structure. The derivation is
based on a "localized" coordinate-transformation technique, which avoids both
the problem of field discontinuities and the challenge of constructing an
explicit coordinate transformation by taking a limit in which a coordinate
perturbation is infinitesimally localized around the boundary. Not only is our
result potentially useful in evaluating boundary perturbations, e.g. from
fabrication imperfections, in highly anisotropic media such as many
metamaterials, but it also has a direct application in numerical
electromagnetism. In particular, we show how it leads to a sub-pixel smoothing
scheme to ameliorate staircasing effects in discretized simulations of
anisotropic media, in such a way as to greatly reduce the numerical errors
compared to other proposed smoothing schemes.Comment: 10 page
1015-72 Elevated Plasma Homocysteine: An Important Independent Risk Factor for Coronary Artery Disease in the Elderly
BackgroundHigh plasma homocysteine (HCY) concentration is an established risk factor for premature vascular disease which can be reduced using vitamin therapy. The role of increased homocysteine as a coronary risk factor in the elderly, however, remains uncertain.MethodsWe studied 228 patients with angiographically documented coronary disease (≥ 70% stenosis in at least one major epicardial vessel). These included 136 patients less than, and 92 greater than 65 years old. Patients were compared to 223 healthy controls 199 (<65) and 24 (> 65). The presence of traditional risk factors including hypertension, smoking, hypercholesterolemia and diabetes mellitus were noted. Total fasting plasma homocysteine was measured in all subjects. A gender-adjusted threshold for a high homocysteine level was defined as the 80th percentile for healthy controls (corresponding to a level of 11.7 μmol/L in women and 13.6 μmo1/L in men).ResultsAge<65Age>65PatientsControlsPatientsControlsHomocysteine12.2±4.0*11.0±3.414.2±4.6*11.9±3.6High HCY(%)33*2050†25Odds Ratios2.0*NA2.9*NAConfidence Interval1.2–3.2NA1.0–8.3NA*p<am vs controls†p<0.03ConclusionsHomocysteine concentrations are elevated in patients with coronary artery disease older than 65 years in age. A high value confers an independent three-fold risk for coronary disease in this patient group. Accordingly, intervention studies designed to reduce plasma homocysteine levels should not exclude the elderly
Bis(μ-2-tert-butylphenylimido-1:2κ2 N:N)chlorido-2κCl-(diethyl ether-1κO)(2η5-pentamethylcyclopentadienyl)lithiumtantalum(V)
In the title compound, [LiTa(C10H15)(C10H13N)2Cl(C4H10O)], the TaV atom is coordinated by a η5-pentamethylcyclopentadienyl (Cp*) ligand, a chloride ion and two N-bonded 2-tert-butylphenylimide dianions. With respect to the two N atoms, the chloride ion and the centroid of the Cp* ring, the tantalum coordination geometry is approximately tetrahedral. The lithium cation is bonded to both the 2-tert-butylphenylimide dianions and also a diethyl ether molecule, in an approximate trigonal planar arrangement. The Ta⋯Li separation is 2.681 (15) Å. In the crystal, a weak C—H⋯Cl interaction links the molecules. When compared to the 2,6-diisopropylphenylimide analogue (‘the Wigley derivative’) of the title compound, the two structures are conformationally matched with an overall r.m.s. difference of 0.461Å
BLUF Domain Function Does Not Require a Metastable Radical Intermediate State
BLUF
(blue light using flavin) domain proteins are an important
family of blue light-sensing proteins which control a wide variety
of functions in cells. The primary light-activated step in the BLUF
domain is not yet established. A number of experimental and theoretical
studies points to a role for photoinduced electron transfer (PET)
between a highly conserved tyrosine and the flavin chromophore to
form a radical intermediate state. Here we investigate the role of
PET in three different BLUF proteins, using ultrafast broadband transient
infrared spectroscopy. We characterize and identify infrared active
marker modes for excited and ground state species and use them to
record photochemical dynamics in the proteins. We also generate mutants
which unambiguously show PET and, through isotope labeling of the
protein and the chromophore, are able to assign modes characteristic
of both flavin and protein radical states. We find that these radical
intermediates are not observed in two of the three BLUF domains studied,
casting doubt on the importance of the formation of a population of
radical intermediates in the BLUF photocycle. Further, unnatural amino
acid mutagenesis is used to replace the conserved tyrosine with fluorotyrosines,
thus modifying the driving force for the proposed electron transfer
reaction; the rate changes observed are also not consistent with a
PET mechanism. Thus, while intermediates of PET reactions can be observed
in BLUF proteins they are not correlated with photoactivity, suggesting
that radical intermediates are not central to their operation. Alternative
nonradical pathways including a keto–enol tautomerization induced
by electronic excitation of the flavin ring are considered
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