Law without law or "just" limit theorems?

About 35 years ago Wheeler introduced the motto `law without law' to highlight the possibility that (at least a part of) Physics may be understood only following {\em regularity principles} and few relevant facts, rather than relying on a treatment in terms of fundamental theories. Such a proposal can be seen as part of a more general attempt (including the maximum entropy approach) summarized by the slogan `it from bit', which privileges the information as the basic ingredient. Apparently it seems that it is possible to obtain, without the use of physical laws, some important results in an easy way, for instance, the probability distribution of the canonical ensemble. In this paper we will present a general discussion on those ideas of Wheeler's that originated the motto `law without law'. In particular we will show how the claimed simplicity is only apparent and it is rather easy to produce wrong results. We will show that it is possible to obtain some of the results treated by Wheeler in the realm of the statistical mechanics, using precise assumptions and nontrivial results of probability theory, mainly concerning ergodicity and limit theorems.Comment: 9 pages, 3 figure

Compressibility, laws of nature, initial conditions and complexity

We critically analyse the point of view for which laws of nature are just a mean to compress data. Discussing some basic notions of dynamical systems and information theory, we show that the idea that the analysis of large amount of data by means of an algorithm of compression is equivalent to the knowledge one can have from scientific laws, is rather naive. In particular we discuss the subtle conceptual topic of the initial conditions of phenomena which are generally incompressible. Starting from this point, we argue that laws of nature represent more than a pure compression of data, and that the availability of large amount of data, in general, is not particularly useful to understand the behaviour of complex phenomena.Comment: 19 Pages, No figures, published on Foundation of Physic

Temperature in and out of equilibrium: a review of concepts, tools and attempts

We review the general aspects of the concept of temperature in equilibrium and non-equilibrium statistical mechanics. Although temperature is an old and well-established notion, it still presents controversial facets. After a short historical survey of the key role of temperature in thermodynamics and statistical mechanics, we tackle a series of issues which have been recently reconsidered. In particular, we discuss different definitions and their relevance for energy fluctuations. The interest in such a topic has been triggered by the recent observation of negative temperatures in condensed matter experiments. Moreover, the ability to manipulate systems at the micro and nano-scale urges to understand and clarify some aspects related to the statistical properties of small systems (as the issue of temperature's "fluctuations"). We also discuss the notion of temperature in a dynamical context, within the theory of linear response for Hamiltonian systems at equilibrium and stochastic models with detailed balance, and the generalised fluctuation-response relations, which provide a hint for an extension of the definition of temperature in far-from-equilibrium systems. To conclude we consider non-Hamiltonian systems, such as granular materials, turbulence and active matter, where a general theoretical framework is still lacking.Comment: Review article, 137 pages, 12 figure

Efficiency of a stirred chemical reaction in a closed vessel

We perform a numerical study of the reaction efficiency in a closed vessel. Starting with a little spot of product, we compute the time needed to complete the reaction in the container following an advection-reaction-diffusion process. Inside the vessel it is present a cellular velocity field that transports the reactants. If the size of the container is not very large compared with the typical length of the velocity field one has a plateau of the reaction time as a function of the strength of the velocity field, $U$. This plateau appears both in the stationary and in the time-dependent flow. A comparison of the results for the finite system with the infinite case (for which the front speed, $v_f$, gives a simple estimate of the reacting time) shows the dramatic effect of the finite size.Comment: 4 pages, 4 figure

Multiple-scale analysis and renormalization for pre-asymptotic scalar transport

Pre-asymptotic transport of a scalar quantity passively advected by a velocity field formed by a large-scale component superimposed to a small-scale fluctuation is investigated both analytically and by means of numerical simulations. Exploiting the multiple-scale expansion one arrives at a Fokker--Planck equation which describes the pre-asymptotic scalar dynamics. Such equation is associated to a Langevin equation involving a multiplicative noise and an effective (compressible) drift. For the general case, no explicit expression for both the effective drift and the effective diffusivity (actually a tensorial field) can be obtained. We discuss an approximation under which an explicit expression for the diffusivity (and thus for the drift) can be obtained. Its expression permits to highlight the important fact that the diffusivity explicitly depends on the large-scale advecting velocity. Finally, the robustness of the aforementioned approximation is checked numerically by means of direct numerical simulations.Comment: revtex4, 12 twocolumn pages, 3 eps figure

Introduction to chaos and diffusion

This contribution is relative to the opening lectures of the ISSAOS 2001 summer school and it has the aim to provide the reader with some concepts and techniques concerning chaotic dynamics and transport processes in fluids. Our intention is twofold: to give a self-consistent introduction to chaos and diffusion, and to offer a guide for the reading of the rest of this volume.Comment: 39 page

About the role of chaos and coarse graining in Statistical Mechanics

We discuss the role of ergodicity and chaos for the validity of statistical laws. In particular we explore the basic aspects of chaotic systems (with emphasis on the finite-resolution) on systems composed of a huge number of particles.Comment: Summer school `Fundamental Problems in Statistical Physics' (Leuven, Belgium), June 16-29, 2013. To be published in Physica

Linear and anomalous front propagation in system with non Gaussian diffusion: the importance of tails

We investigate front propagation in systems with diffusive and sub-diffusive behavior. The scaling behavior of moments of the diffusive problem, both in the standard and in the anomalous cases, is not enough to determine the features of the reactive front. In fact, the shape of the bulk of the probability distribution of the transport process, which determines the diffusive properties, is important just for pre-asymptotic behavior of front propagation, while the precise shape of the tails of the probability distribution determines asymptotic behavior of front propagation.Comment: 7 pages, 3 figure

Linear and non-linear thermodynamics of a kinetic heat engine with fast transformations

We investigate a kinetic heat engine model constituted by particles enclosed in a box where one side acts as a thermostat and the opposite side is a piston exerting a given pressure. Pressure and temperature are varied in a cyclical protocol of period $\tau$ : their relative excursions, $\delta$ and $\epsilon$ respectively, constitute the thermodynamic forces dragging the system out-of-equilibrium. The analysis of the entropy production of the system allows to define the conjugated fluxes, which are proportional to the extracted work and the consumed heat. In the limit of small $\delta$ and $\epsilon$ the fluxes are linear in the forces through a $\tau$-dependent Onsager matrix whose off-diagonal elements satisfy a reciprocal relation. The dynamics of the piston can be approximated, through a coarse-graining procedure, by a Klein-Kramers equation which - in the linear regime - yields analytic expressions for the Onsager coefficients and the entropy production. A study of the efficiency at maximum power shows that the Curzon-Ahlborn formula is always an upper limit which is approached at increasing values of the thermodynamic forces, i.e. outside of the linear regime. In all our analysis the adiabatic limit $\tau \to \infty$ and the the small force limit $\delta,\epsilon \to 0$ are not directly related.Comment: 10 pages, 9 figure