Corrosion protection of carbon steel by an epoxy resin containing organically modified clay

This study focusses on the use of montmorillonite clay (MMT) treated with an organic compound (aminotrimethylphosphonic acid (ATMP)) and dispersed in an epoxy resin to improve corrosion protection of carbon steel. X-ray diffraction was performed to verify that the individual silicate layers were separated and dispersed in the epoxy resin. Corrosion resistance of the coated steel was evaluated by electrochemical impedance spectroscopy (EIS) and local electrochemical impedance spectroscopy (LEIS). Three systems were tested: the epoxy clear-coat, the epoxy resin containing 2 wt.% clay and the epoxy resin containing 2 wt.% clay modified byATMP (ATMP-modified clay). From conventional EIS, it was shown that the incorporation of clay or ATMP-modified clay in the epoxy matrix significantly improved the barrier properties of the coating. The corrosion resistance of the carbon steel coated by the epoxy resin containing ATMP-modified clay was higher than that obtained for the system containing non-treated clay. Local electrochemical measurements performed on scratched samples revealed the inhibitive role of ATMP at the carbon steel/coating interface

Incorporation of an indole-3 butyric acid modified clay in epoxy resin for corrosion protection of carbon steel

In the present work, indole-3 butyric acid (IBA) was inserted between montmorillonite clay platelets by cation exchange. The clay treated with the organic compound (IBA-modified clay) was then dispersed in an epoxy resin at a low concentration (2 wt.%). IBA was chosen to act both as an inhibitor and an adherence promoter. The effect of the IBA-modified clay on the microstructure and on the protective properties of the epoxy coating deposited on carbon steel was evaluated by a thermostimulated-current (TSC) method and by electrochemical impedance spectroscopy (EIS). The TSC measurements showed the specific action of IBA-modified clay which decreased the molecular mobility of the polymer chain by comparison with the pure epoxy. Impedance measurements corroborated the role of the modified clay on the barrier properties of the coating which remained high as a function of exposure time in a 0.5 M NaCl solution. The corrosion resistance of the carbon steel coated with the epoxy resin containing IBA-modified clay was significantly higher than that obtained with the clear coat. Polarization curves plotted in the presence of an artificial defect demonstrated the inhibitive role of IBA at the carbon steel/coating interface. The good adherence of the coating was seen during salt spray test

Effect of cast iron microstructure on adherence of an epoxy protection

To study the influence of the microstructure of cast iron on the adhesion of an epoxy coating, ferritic, pearlitic and austempered samples were prepared in as-received, polished and oxidised states. A pull-off test (dry adhesion) was performed before immersing in water while the crosscut test was made after 24 days of exposition in distilled water (wet adhesion). X-rays were combined with optical microscopy (LOM) and scanning electron microscopy (SEM) for surface analysis. The adhesion of the epoxy coating on the cast iron surface firstly depends on the roughness of the surface; polished samples showed high adherence by comparison with asreceived samples. On the oxidised samples, the surface oxide significantly improves the adhesion of the coating in both dry and wet states for all three sample microstructure. The presence of carbide in the structure was observed to decrease adherenc

HIGH PROTECTION PERFORMANCE OF COATING SYSTEMS BASED ON ZINC RICH PRIMER AND FLUOROPOLYMER COATING

Coating systems based on zinc rich primer and fluoropolymer top coat were exposed for 8 years at different atmospheric stations in Vietnam: Hanoi, Ha Long and Nha Trang. For comparison the coating system with zinc rich primer and polyurethane topcoat was also tested. The degradations of coating systems were evaluated by gloss measurement and electrochemical impedance spectroscopy. The obtained results show that coating systems with zinc rich primer and top coatings based on fluoropolymer  and polyurethane topcoats show very high weather resistance and corrosion protection performance, but the systems with fluoropolymer are better than coating system with polyurethane topcoat

MODIFICATION OF GRAPHENE OXIDE BY CURCUMIN AND APPLICATION IN POLYURETHANE COATING

Curcumin modified graphene oxide (GO-CR) was prepared using adsorption method and polyurethane (PU) coating containing 0.3 wt% GO-CR was prepared on carbon steel. Synthesized GO-CR was characterized by fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and zeta potential measurement. Corrosion protection property of polyurethane coating containing GO-CR was evaluated and compared with blank polyurethane coating and coating containing GO by electrochemical impedance spectroscopy. The results showed that GO-CR has layer structure like GO with lower crystallinity. In GO-CR structure curcumin was attached on GO surface. The presence of curcumin on GO-CR surface provided corrosion inhibition action for PU coating and also improved the dispersion of GO in PU coating

8-hydroxyquinoline-modified clay incorporated in an epoxy coating for the corrosion protection of carbon steel

In the present work, a well-known corrosion inhibitor (8-hydroxyquinoline (8HQ)) was inserted within the montmorillonite platelets (8HQ-MMT) and the modified clay was incorporated (3 wt.%) into a solvent-free epoxy coating which was afterwards deposited on carbon steel substrates. First, the inhibitive action of 8HQ was investigated by electrochemical methods carried out on a bare carbon steel rotating disk electrode in a 0.1 M NaCl solution. Then, electrochemical impedance measurements were performed to assess the effect of the 8HQ-MMT in the epoxy coating for the corrosion protection. The results were compared with a reference sample constituted by the epoxy coating containing an ammonium quaternary salt-modified clay. It was shown that the two coatings presented good barrier properties. Dry and wet adherence measurements revealed an improvement of the adherence when the 8HQ-MMT was incorporated into the coating by comparison with the reference sample. It was concluded that the 8HQ mainly had an effect at the metal/coating interface but its concentration was too low to afford significant corrosion protection of the carbon steel

Защита стальных поверхностей покрытиями на основе полиуретана и кремнийорганических соединений

Coatings of oligomethylsiloxane resin (OMES) and hydrolyzed heptadecafluorotetrahydrodecyltrimethoxysi-lane (HFS) oligomers were obtained by the spin-coating method on polyurethane (PU) - modified steel substrates. Their wettability and tribological properties were studied. It was found that the modification of the PU layer with silicon organic compounds increases its hydrophobicity and wear resistance. The water contact angles are 63.1° for a PU coating, 81.2° for PU/OMES and 115.8° for PU/HFS.Методом центрифугирования на стальных подложках, модифицированных полиуретаном (ПУ) сформированы покрытия олигометилсилоксановой смолы (ОМЕС) и олигомеров гидролизованного гептадекафтор-тетрагидродецилтриметоксисилана (ГФС), изучена их смачиваемость и трибологические свойства. Установлено, что модификация слоя ПУ кремнийорганическими соединениями увеличивает его гидрофобность и износоустойчивость. Краевые углы смачивания водой составляют для покрытий из ПУ - 63,1°, ПУ/ОМЕС - 81,2° и ПУ/ГФС - 115,8°

Effect of cast iron microstructure on adherence of an epoxy protection

International audienceTo study the influence of the microstructure of cast iron on the adhesion of an epoxy coating, ferritic, pearlitic and austempered samples were prepared in as-received, polished and oxidized states. A pull-off test (dry adhesion) was performed before immersing in water while the cross-cut test was made after 24 days of exposition in distilled water (wet adhesion). X-rays were combined with optical microscopy (LOM) and scanning electron microscopy (SEM) for surface analysis. The adhesion of the epoxy coating on the cast iron surface firstly depends on the roughness of the surface; polished samples showed high adherence by comparison with as-received samples. On the oxidized samples, the surface oxide significantly improves the adhesion of the coating in both dry and wet states for all three sample microstructure. The presence of carbide in the structure was observed to decrease adherence