On the parameterization of all admissible pairs in a class of CCF-ILC algorithms

This paper extends some recent results on the parameterization of all admissible pairs in a class of 2-parameter current-cycle-feedback ILC algorithms. In addition, a necessary and sufficient condition is given under which the associated set of equivalent controllers coincides with the set of all stabilizing controller

Rate and Mechanism of the Oxidative Addition of Benzoic Anhydride to Palladium(0) Complexes in DMF

The rate constant of the oxidative addition of the benzoic anhydride (PhCO)2O to [Pd0(PPh3)4] has been determined in DMF and compared to that of phenyl halides and phenyl triflate. The following reactivity order has been established: PhI >> (PhCO)2O > PhOTf > PhBr. The oxidative addition of (PhCO)2O proceeds by activation of one C−O bond. Two acyl-PdII complexes are formed: a neutral complex trans-[(PhCO)Pd(OCOPh)(PPh3)2] and a cationic complex trans-[(PhCO)PdS(PPh3)2]+ (S = DMF) showing that the decarbonylation process is highly endergonic. The exchange of PPh3 by the bidentate ligand dppp does not favor the decarbonylation process.

Massive galaxies with very young AGN

Gigahertz Peaked Spectrum (GPS) radio galaxies are generally thought to be the young counterparts of classical extended radio sources and live in massive ellipticals. GPS sources are vital for studying the early evolution of radio-loud AGN, the trigger of their nuclear activity, and the importance of feedback in galaxy evolution. We study the Parkes half-Jansky sample of GPS radio galaxies of which now all host galaxies have been identified and 80% has their redshifts determined (0.122 < z < 1.539). Analysis of the absolute magnitudes of the GPS host galaxies show that at z > 1 they are on average a magnitude fainter than classical 3C radio galaxies. This suggests that the AGN in young radio galaxies have not yet much influenced the overall properties of the host galaxy. However their restframe UV luminosities indicate that there is a low level of excess as compared to passive evolution models.Comment: To appear in the proceedings of "Formation and Evolution of Galaxy Bulges", IAUS 245; M. Bureau, E. Athanassoula & B. Barbuy, ed

Influence of Phosphoramidites in Copper-Catalyzed Conjugate Borylation Reaction

Copper(I) has become the preferred metal to catalyze the β-boration of α,β-unsaturated carbonyl compounds, and now we demonstrate that easily accessible monodentate chiral ligands, such as phosphoramidites and phosphites, can be convenient alternative ligands to induce asymmetry in the enantioselective version of this reaction, particularly in the β-boration of α,β-unsaturated imines.

Monte Carlo calculations of energy depositions and radiation transport. Volume 1 - Validation of COHORT codes

Monte Carlo codes for IBM 7090 digital computer to calculate radiation heating in propellant tanks, and radiation environment about nuclear rocket stag

Modeling and prediction of surgical procedure times

Accurate prediction of medical operation times is of crucial importance for cost efficient operation room planning in hospitals. This paper investigates the possible dependence of procedure times on surgeon factors like age, experience, gender, and team composition. The effect of these factors is estimated for over 30 different types of medical operations in two hospitals, by means of ANOVA models for logarithmic case durations. The estimation data set contains about 30,000 observations from 2005 till 2008. The relevance of surgeon factors depends on the type of operation. The factors found most often to be significant are team composition, experience, and daytime. Contrary to widespread opinions among surgeons, gender has nearly never a significant effect. By incorporating surgeon factors, the accuracy of out-of-sample prediction of case durations of about 1,250 surgical operations in 2009 is improved by up to more than 15 percent as compared to current planning procedures.planning;ANOVA model;European hospital;current procedure terminology (CPT);health care management;lognormal distribution;operation room;surgeon factors

Persistence of the valence bond glass state in the double perovskites Ba2-xSrxYMoO6

Peer reviewedPublisher PD

Banking System Stability: A Cross-Atlantic Perspective

This paper derives indicators of the severity and structure of banking system risk from asymptotic interdependencies between banks%u2019 equity prices. We use new tools available from multivariate extreme value theory to estimate individual banks%u2019 exposure to each other (%u201Ccontagion risk%u201D) and to systematic risk. Moreover, by applying structural break tests to those measures we study whether capital markets indicate changes in the importance of systemic risk over time. Using data for the United States and the euro area, we can also compare banking system stability between the two largest economies in the world. Finally, for Europe we assess the relative importance of cross-border bank spillovers as compared to domestic bank spillovers. The results suggest, inter alia, that systemic risk in the US is higher than in the euro area, mainly as cross-border risks are still relatively mild in Europe. On both sides of the Atlantic systemic risk has increased during the 1990s.

The Forward Premium Puzzle and Latent Factors Day by Day

We use futures instead of forward rates to study the complete maturity spectrum of the forward premium puzzle from two days to six months. At short maturities the slope coefficient is positive, but these turn negative as the maturity increases to the monthly level. Futures data allow us to control for the influence of an unobserved factor that can be decomposed into a contract-specific and a time- to-maturity effect. Once we do this, we find that the coefficients on the forward premium are much closer to one. The latent factor is shown to be related to conventional proxies of risk.forward premium puzzle, futures rates, latent factor