Impact of Friction Stir Processing Parameters on Forming the Structure and Properties in AISI 420 Steel Surface Layer

Research has been done into the influence of friction thermomechanical treatment parameters on forming the structure and properties in a surface layer of 20X13 steel. The paper presents a theoretical approach towards controlling the process variables. A hardened layer with a thickness of 1,7 mm was obtained after 20X13 steel had been subjected to the process. The thickness of the layer that had a microhardness of ≥600HV0,05 turned out to be about 0,75mm while the microstructure of the hardened layer was martensitic, martensitic and perlitic with dispersed inclusions of carbides. It was established that the feed has the biggest influence on the thickness of the hardened layer.     Keywords: friction stir processing, rotation speed, tool feed, normal force, microhardness, microstructure

Features of accumulation of sulfur and phosphorus by phytoremediants from technogenically polluted wastewater of mining enterprises

The article presents data on the accumulation of phosphorus and sulfur in the tissues of phytoremediant plants Phragmites australis (Cav.) Trin. ex Steud., Typha angustifolia L., Typha latifolia L., used for the treatment of technogenically polluted wastewater from mining enterprise

Bremsstrahlung in the gravitational field of a cosmic string

In the framework of QED we investigate the bremsstrahlung process for an electron passing by a straight static cosmic string. This process is precluded in empty Minkowski space-time by energy and momentum conservation laws. It happens in the presence of the cosmic string as a consequence of the conical structure of space, in spite of the flatness of the metric. The cross section and emitted electromagnetic energy are computed and analytic expressions are found for different energies of the incoming electron. The energy interval is divided in three parts depending on whether the energy is just above electron rest mass $M$, much larger than $M$, or exceeds $M/\delta$, with $\delta$ the string mass per unit length in Planck units. We compare our results with those of scalar QED and classical electrodynamics and also with conic pair production process computed earlier.Comment: 21 pages, to appear in Phys. Rev. D., KONS-RGKU-94-0

Renormalization of the vacuum angle in quantum mechanics, Berry phase and continuous measurements

The vacuum angle $\theta$ renormalization is studied for a toy model of a quantum particle moving around a ring, threaded by a magnetic flux $\theta$. Different renormalization group (RG) procedures lead to the same generic RG flow diagram, similar to that of the quantum Hall effect. We argue that the renormalized value of the vacuum angle may be observed if the particle's position is measured with finite accuracy or coupled to additional slow variable, which can be viewed as a coordinate of a second (heavy) particle on the ring. In this case the renormalized $\theta$ appears as a magnetic flux this heavy particle sees, or the Berry phase, associated with its slow rotation.Comment: 4 pages, 2 figure

The use of small volumes of test samples in subvisible particle testing by the light obscuration method

The light obscuration method described in the State Pharmacopoeia of the Russian Federation for subvisible particle testing, provides for preparation of a pooled sample with a minimum volume of 25 mL to be used in four measurements, each with 5.0 mL of the test sample. In the case of, for example, ready-to-use 0.2–0.3 mL pre-filled syringes, the method requires pooling the contents of a large number of products, which is economically costly. The use of small volumes of test samples in measurements by the light obscuration method is especially relevant for expensive medicines. Current particle counters allow for testing of 0.1 mL samples, but this requires assessment of the procedure’s accuracy. The aim of the study was to assess the accuracy of subvisible particle testing by the light obscuration method for small volumes of test samples. Materials and methods: we used an HIAC 9703+ liquid particle counter; particle count reference standards containing 0.998×106 particles/mL and 3.800 particles/mL; suspensions of standard latex particles with a known size (20 μm). Results: the study assessed the accuracy of subvisible particle determination by the light obscuration method for small test samples of 0.1‒0.5 mL: trueness was 96–100%; repeatability was 0.8–1.8%; linear correlation coefficients for the calculated versus theoretical number of particles were more than 0.999. The use of 0.1 mL test samples is impractical because of insufficient accuracy of the test results. The relative standard deviation of subvisible particle measurements obtained with 0.2–5.0 mL test samples did not exceed the measurement error of the instrument. The use of small test samples (0.2–1.0 mL) requires the use of a 1 mL sampling syringe. The study demonstrated the need for determination of the pre-run volume (not less than 0.1 mL). Comparative testing of standard (5.0 mL) and small (0.5 mL) samples of protein-based biological products showed comparable results. Conclusions: the study demonstrated that the light obscuration method could be used for small volumes of test samples

Lyophilisation of bacterial test strains in a manifold-type apparatus: Effects of freezing and drying parameters, ampoule fill volume, and cotton filter density

Scientific relevance. Lyophilisation is the preferred method at the National Collection of Pathogenic Microorganisms (NCPM) of the Scientific Centre for Expert Evaluation of Medicinal Products of the Ministry of Health of the Russian Federation. Lyophilisation is used to provide for high standards of test-strain deposition, storage, and transportation and to ensure that test strains maintain their properties. Successful lyophilisation requires conducting experiments to establish the key parameters and critical conditions of the process.Aim. The study aimed to evaluate the effects that the speed and time of freezing, the time of drying, the fill volume of ampoules, and the density of cotton filters have on the quality of NCPM indicator microorganisms lyophilised in a manifold-type apparatus.Materials and methods. Pseudomonas aeruginosa NCTC 12924, Staphylococcus aureus NCTC 10788, and Salmonella Abony NCTC 6017 were freeze-dried using a manifold-type apparatus (M. S. R. 18, Usifroid). The authors used a low-temperature freezer at –70±2 °C for slow freezing and a mixture of dry ice and alcohol for quick freezing. The statistical analysis was performed using Microsoft Excel and Statistica 10.Results. The minimum time needed for freezing the samples in a low-temperature freezer at –70±2 °C was 4 hours. Further storage at this temperature for up to 1 month was shown possible without compromising the quality of the final product. The time needed for freezing the samples in a mixture of dry ice and alcohol was under 1 minute. No differences in quality parameters were observed between the lyophilised samples frozen slowly or quickly, except for the cake appearance. Quick freezing resulted in cakes that were non-uniform, crumbled, and pulled away from the ampoule walls, which is considered undesirable. The primary drying stage for ampoules with a fill volume of 0.2 mL took 6–8 hours. The secondary drying stage of 11, 18, 35, and 59 hours resulted in comparable lyophilisate quality: the authors observed no statistically significant differences in viable cell counts (CFU/mL) at the end of lyophilisation and at the end of stress testing. The residual moisture content after 59-hour secondary drying was less than 2%. The cotton filter density had a critical influence on the lyophilisate quality. Therefore, the authors recommend using cotton filters weighing 50 mg or less.Conclusions. The authors analysed the main stages of the lyophilisation process used for NCPM test strains and considered the effects that the speed and time of freezing, the time of drying, the fill volume of ampoules, and the density of cotton filters have on the quality of the final lyophilised product. The NCPM has implemented the results of this study in its work

Influence of the material of weighing bottles on loss-on-drying reproducibility

One of the factors influencing the uncertainty of residual moisture measurements in biological medicinal products is the accumulation of electrostatic charge on the surfaces of weighing bottles and laboratory balances, which results in poor weighing reproducibility. The authors believe that the simplest and most economical solution to this problem is to use weighing bottles made of a conductive material, e.g. metal. The aim of the work was to evaluate the influence of the material of weighing bottles on the reproducibility of loss-on-drying (LOD) methods. Materials and methods: Model samples for the study were prepared from a sucrose-gelatin medium by lyophilisation and subsequent moisture sorption to achieve a certain residual moisture content. The authors assessed the samples’ mass uniformity using Shewhart’s X-charts, and analysed their residual moisture content using a loss-on-drying procedure with glass and metal weighing bottles. Statistical processing of the results was carried out by calculating the main statistical indicators: Student’s t-test and Fisher’s F-test. Results: Four batches of model samples were prepared and standardised in terms of average mass using Shewhart’s charts. The effect of weighing bottle materials was most pronounced at low residual moisture contents (less than 0.5%), with the relative standard deviation (RSD) values for the results obtained with glass and metal weighing bottles reaching 76% and 35%, respectively. For the samples with a higher residual moisture content (2–5%), the minimum RSDs with glass and metal weighing bottles were 15% and 6%, respectively. Conclusions: The study allowed for evaluating the influence of the material of weighing bottles on the results of LOD measurements and demonstrated a higher reproducibility with metal weighing bottles. This confirms the possibility of using metal weighing bottles in quality assessment of biological medicinal products for human use with LOD methods

Технология формирования высокопрочных износостойких фторкомпозитов

The article discusses the causes of the structural paradox at obtaining PTFE-based composites within traditional technological paradigm, which consists in reducing the parameters of deformation and strength characteristics of material while increasing the share of filler Methods for forming PTFE-based composites that overcome the negative impact of structural paradox are offered .Рассмотрены причины возникновения структурного парадокса при получении фторкомпозитов в рамках традиционной технологической парадигмы, состоящего в снижении параметров деформационно-прочностных характеристик при увеличении доли наполнителя. Предложены методы формирования фторкомпозитов, позволяющие преодолеть негативное влияние структурного парадокса

Recycling and disposal of gypsum-containing waste generated in the production of citric acid

The cycle of citric acid production with the formation of gypsum-containing waste was considered and options for processing and utilization of citrogypsum were proposed. The methods obtained include: the use of citrogypsum in the production of building materials, the extraction of rare earth metals, as well as the creation of a high-quality organic-mineral fertilizer, during the creation of which it is possible to reduce the negative effect not only from the accumulation of citrogypsum, but also from manure stored in the filtration field

A Precision Measurement of Nuclear Muon Capture on 3He

The muon capture rate in the reaction mu- 3He -> nu + 3H has been measured at PSI using a modular high pressure ionization chamber. The rate corresponding to statistical hyperfine population of the mu-3He atom is (1496.0 +- 4.0) s^-1. This result confirms the PCAC prediction for the pseudoscalar form factors of the 3He-3H system and the nucleon.Comment: 13 pages, 6 PostScript figure