РАЗВИТИЕ МАЛОГО БИЗНЕСА В РОССИИ: ПУТИ ФИНАНСИРОВАНИЯ

In Russia small-scale business originated in the end of 1980s duringRestructuring. It has been developing as fast as Russian economics.Unlike large industrial companies, which just continued to run businessas they used to, small-scale businessmen had to start from scratch ordisaffiliate with large organizations. Basically, in 1990-s small-scale business as a financial institute was self-regulated due to its highcriminalization and nonpayment of tax.For a period of only 25 years small-scale business has improved muchand now provides well-being to the country. The improvement happeneddue to the following factors:- propitious economic and political climate of the country against thebackground of global economy and the years of restricting- important and useful measures for economic development were taken - important and useful measures for development of small-scale enterprises were takenThe development of this new financial institute is quite fast, but historyhas other examples of such phenomenon. In the 21st century RussianFederation adopted experience of advanced countries and imposed it onits historic experience. However, we can’t say that small-scale business is on its top of development in our country. Nowadays development of small-scale business is one of the priorities of the Russian government.Малый бизнес в России - явление, зародившееся в конце 1980-х годов во время Перестройки и развивающееся параллельно и так же стремительно, как и сама российская экономика. В отличие от крупных промышленных и других компаний, которые продолжили деятельностьсоветскихнационализированныхпредприятий, малое предпринимательствостартовалоснуля, либопосредствомвыхода из крупного бизнеса. В 1990-е годы, по своей сути, малое предпринимательство как институт было саморегулирующимся, ввиду высокойкриминализациибизнеса, неуплатыналоговипрочихобязательных выплат. На сегодняшний моментмалый бизнеспрошел относительнокороткийповременныммеркампуть- двадцатьпять лет. Однакосделалбольшойшагнапутиквысшейточкеразвитияи благоприятствованиядляэкономикистраны. Этообуславливается следующими факторами: - благоприятныйэкономическийиполитическийклиматстранына фоне мировой экономики и годов перестройки; - принятыважныеиполезныезаконодательныеиисполнительные меры для развития экономики; - принятыважныеиполезныезаконодательныеиисполнительные меры для развития малого предпринимательства. Висторическихрамкахданноеразвитиепроисходиточеньбыстро, однаковусловияхсовременногомира, этонепервыйпример. РоссийскаяФедерациявдвадцатьпервомвекеперенялаопытсильных иразвивающихсяэкономик, наложиланасвой историческийопыт. Однако нельзя говорить о том, что малый бизнес в стране достиг вершины развития. Мы только на пути к нему, и развитие малого бизнесасейчасявляетсяоднойизприоритетныхзадачроссийского руководства

Space-Time Discretizations Using Constrained First-Order System Least Squares (CFOSLS)

This paper studies finite element discretizations for three types of time-dependent PDEs, namely heat equation, scalar conservation law and wave equation, which we reformulate as first order systems in a least-squares setting subject to a space-time conservation constraint (coming from the original PDE). Available piece- wise polynomial finite element spaces in (n + 1)-dimensions for functional spaces from the (n + 1)-dimensional de Rham sequence for n = 3, 4 are used for the implementation of the method. Computational results illustrating the error behavior, iteration counts and performance of block-diagonal and monolithic geometric multi- grid preconditioners are presented for the discrete CFOSLS system. The results are obtained from a parallel implementation of the methods for which we report reasonable scalability

Enabling propagation of anisotropic polaritons along forbidden directions via a topological transition

Recent discoveries of polaritons in van der Waals (vdW) crystals with directional in-plane propagation, ultra-low losses, and broad spectral tunability have opened the door for unprecedented manipulation of the flow of light at the nanoscale. However, despite their extraordinary potential for nano-optics, these unique polaritons also present an important limitation: their directional propagation is intrinsically determined by the crystal structure of the host material, which imposes forbidden directions of propagation and hinders its control. Here, we theoretically predict and experimentally demonstrate that directional polaritons (in-plane hyperbolic phonon polaritons) in a vdW biaxial slab (alpha-phase molybdenum trioxide) can be steered along previously forbidden directions by inducing an optical topological transition, which naturally emerges when placing the slab on a substrate with a given negative permittivity (4H-SiC). Importantly, due to the low-loss nature of this topological transition, we are able to visualize in real space exotic intermediate polaritonic states between mutually orthogonal hyperbolic regimes, which permit to unveil the unique topological origin of the transition. This work provides new insights into the emergence of low-loss optical topological transitions in vdW crystals, offering a novel route to efficiently steer the flow of energy at the nanoscale

Integration of renewable energy at coal mining enterprises: problems and prospects

This article addresses the issue of developing renewable energy in coal mining enterprises in the Russian Federation. The study presents a methodology for assessing the technical and economic efficiency of introducing renewable energy sources based on simulation modeling. An analysis of the potential of solar and wind energy for coal mining regions in Russia is conducted. The authors use a custom software developed by them to simulate the power supply system for various scenarios of renewable energy integration, including solar generation, wind generation, solar generation with energy storage, wind generation together with solar generation. Based on the example of the Rostov region, a feasibility study of the considered options is presented. Additionally, the research includes a sensitivity analysis of the investment project in the conditions of uncertainty in the development of Russian renewable energy. The research findings indicate that even in market conditions with CO2 emission quotas and prices at the level of the Sakhalin experiment, renewable energy in coal mining enterprises in Russia remains unattractive and requires additional support

Phase-Change Microcapsules with a Stable Polyurethane Shell through the Direct Crosslinking of Cellulose Nanocrystals with Polyisocyanate at the Oil/Water Interface of Pickering Emulsion

Phase-change materials (PCMs) attract much attention with regard to their capability of mitigating fossil fuel-based heating in in-building applications, due to the responsive accumulation and release of thermal energy as a latent heat of reversible phase transitions. Organic PCMs possess high latent heat storage capacity and thermal reliability. However, bare PCMs suffer from leakages in the liquid form. Here, we demonstrate a reliable approach to improve the shape stability of organic PCM n-octadecane by encapsulation via interfacial polymerization at an oil/water interface of Pickering emulsion. Cellulose nanocrystals are employed as emulsion stabilizers and branched oligo-polyol with high functionality to crosslink the polyurethane shell in reaction with polyisocyanate dissolved in the oil core. This gives rise to a rigid polyurethane structure with a high density of urethane groups. The formation of a polyurethane shell and successful encapsulation of n-octadecane is confirmed by FTIR spectroscopy, XRD analysis, and fluorescent confocal microscopy. Electron microscopy reveals the formation of non-aggregated capsules with an average size of 18.6 µm and a smooth uniform shell with the thickness of 450 nm. The capsules demonstrate a latent heat storage capacity of 79 J/g, while the encapsulation of n-octadecane greatly improves its shape and thermal stability compared with bulk paraffin

Focusing of in-plane hyperbolic polaritons in van der Waals crystals with tailored infrared nanoantennas

Phonon polaritons (PhPs),light coupled to lattice vibrations,with in-plane hyperbolic dispersion exhibit ray-like propagation with large wavevectors and enhanced density of optical states along certain directions on a surface. As such, they have raised a surge of interest as they promise unprecedented possibilities for the manipulation of infrared light with planar circuitry and at the nanoscale. Here, we demonstrate, for the first time, the focusing of in-plane hyperbolic PhPs propagating along thin slabs of MoO3. To that end, we developed metallic nanoantennas of convex geometries for both the efficient launching and focusing of the polaritons. Remarkably, the foci obtained exhibit enhanced near-field confinement and absorption compared to foci produced by in-plane isotropic PhPs. More intriguingly, foci sizes as small as lamdap/5 =lamda0/50 were achieved (lamdap is the polariton wavelength and lamda0 the photon wavelength). Focusing of in-plane hyperbolic polaritons introduces a first and most basic building block developing planar polariton optics utilizing in-plane anisotropic van der Waals materials and metasurfaces

Chiral photonic super-crystals based on helical van der Waals homostructures

Chirality is probably the most mysterious among all symmetry transformations. Very readily broken in biological systems, it is practically absent in naturally occurring inorganic materials and is very challenging to create artificially. Chiral optical wavefronts are often used for the identification, control and discrimination of left- and right-handed biological and other molecules. Thus, it is crucially important to create materials capable of chiral interaction with light, which would allow one to assign arbitrary chiral properties to a light field. In this paper, we utilized van der Waals technology to assemble helical homostructures with chiral properties (e. g. circular dichroism). Because of the large range of van der Waals materials available such helical homostructures can be assigned with very flexible optical properties. We demonstrate our approach by creating helical homostructures based on multilayer As$_2$S$_3$, which offers the most pronounced chiral properties even in thin structures due to its strong biaxial optically anisotropy. Our work showcases that the chirality of an electromagnetic system may emerge at an intermediate level between the molecular and the mesoscopic one due to the tailored arrangement of non-chiral layers of van der Waals crystals and without additional patterning

Planar refraction and lensing of highly confined polaritons in anisotropic media

Refraction between isotropic media is characterized by light bending towards the normal to the boundary when passing from a low- to a high-refractive-index medium. However, refraction between anisotropic media is a more exotic phenomenon which remains barely investigated, particularly at the nanoscale. Here, we visualize and comprehensively study the general case of refraction of electromagnetic waves between two strongly anisotropic (hyperbolic) media, and we do it with the use of nanoscale-confined polaritons in a natural medium: alpha-MoO3. The refracted polaritons exhibit non-intuitive directions of propagation as they traverse planar nanoprisms, enabling to unveil an exotic optical effect: bending-free refraction. Furthermore, we develop an in-plane refractive hyperlens, yielding foci as small as lambdap/6, being lambdap the polariton wavelength (lambda0/50 compared to the wavelength of free-space light). Our results set the grounds for planar nano-optics in strongly anisotropic media, with potential for effective control of the flow of energy at the nanoscale.G.Á.-P. and J.T.-G. acknowledge support through the Severo Ochoa Program from the Government of the Principality of Asturias (nos. PA-20-PF-BP19-053 and PA-18-PF-BP17-126, respectively). S.X. acknowledges the support from Independent Research Fund Denmark (Project No. 9041-00333B). B.C. acknowledges the support from VILLUM FONDEN (No. 00027987). The Center for Nanostructured Graphene is sponsored by the Danish National Research Foundation (Project No. DNRF103.) K.V.V. and V.S.V. gratefully acknowledge the financial support from the Ministry of Science and Higher Education of the Russian Federation (Agreement No. 075-15-2021-606). J.M.-S. acknowledges financial support through the Ramón y Cajal Program from the Government of Spain (RYC2018-026196-I). A.Y.N. and J.I.M. acknowledge the Spanish Ministry of Science, Innovation and Universities (national projects MAT201788358-C3-3-R and PID2019-104604RB/AEI/10.13039/501100011033). R.H. acknowledges financial support from the Spanish Ministry of Science, Innovation and Universities (national project RTI2018-094830-B-100 and the project MDM-2016-0618 of the Marie de Maeztu Units of Excellence Program) and the Basque Government (grant No. IT1164-19). A.Y.N. also acknowledges the Basque Department of Education (grant no. PIBA-2020-1-0014). P.A.-G. acknowledges support from the European Research Council under starting grant no. 715496, 2DNANOPTICA and the Spanish Ministry of Science and Innovation (State Plan for Scientific and Technical Research and Innovation grant number PID2019-111156GB-I00)

Polyurethane/<i>n</i>-Octadecane Phase-Change Microcapsules via Emulsion Interfacial Polymerization: The Effect of Paraffin Loading on Capsule Shell Formation and Latent Heat Storage Properties.

Organic phase-change materials (PCMs) hold promise in developing advanced thermoregulation and responsive energy systems owing to their high latent heat capacity and thermal reliability. However, organic PCMs are prone to leakages in the liquid state and, thus, are hardly applicable in their pristine form. Herein, we encapsulated organic PCM n-Octadecane into polyurethane capsules via polymerization of commercially available polymethylene polyphenylene isocyanate and polyethylene glycol at the interface oil-in-water emulsion and studied how various n-Octadecane feeding affected the shell formation, capsule structure, and latent heat storage properties. The successful shell polymerization and encapsulation of n-Octadecane dissolved in the oil core was verified by confocal microscopy and Fourier-transform infrared spectroscopy. The mean capsule size varied from 9.4 to 16.7 µm while the shell was found to reduce in thickness from 460 to 220 nm as the n-Octadecane feeding increased. Conversely, the latent heat storage capacity increased from 50 to 132 J/g corresponding to the growth in actual n-Octadecane content from 25% to 67% as revealed by differential scanning calorimetry. The actual n-Octadecane content increased non-linearly along with the n-Octadecane feeding and reached a plateau at 66-67% corresponded to 3.44-3.69 core-to-monomer ratio. Finally, the capsules with the reasonable combination of structural and thermal properties were evaluated as a thermoregulating additive to a commercially available paint