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Phase equilibria and thermodynamic properties of oxide systems on the basis of rare earth, alkaline earth and 3d-transition (Mn, Fe, Co) metals. A short overview of
Review is dedicated studies of phase equilibria in the systems based on rare earth elements and 3d transition metals. It’s highlighted several structural families of these compounds and is shown that many were found interesting properties for practical application, such as high conductivity up to the superconducting state, magnetic properties, catalytic activity of the processes of afterburning of exhaust gases, the high mobility in the oxygen sublattice and more
Highly mobile carriers in orthorhombic phases of iron-based superconductors FeSeS
The field and temperature dependencies of the longitudinal and Hall
resistivity have been measured for FeSeS (x=0.04, 0.09 and
0.19) single crystals. The sample FeSeS does not show a
transition to an orthorhombic phase and exhibits at low temperatures the
transport properties quite different from those of orthorhombic samples. The
behavior of FeSeS is well described by the simple two
band model with comparable values of hole and electron mobility. In particular,
at low temperatures the transverse resistance shows a linear field dependence,
the magnetoresistance follow a quadratic field dependence and obeys to Kohler's
rule. In contrast, Kohler's rule is strongly violated for samples having an
orthorhombic low temperature structure. However, the transport properties of
the orthorhombic samples can be satisfactory described by the three band model
with the pair of almost equivalent to the tetragonal sample hole and electron
bands, supplemented with the highly mobile electron band which has two order
smaller carrier number. Therefore, the peculiarity of the low temperature
transport properties of the orthorhombic Fe(SeS) samples, as probably of many
other orthorhombic iron superconductors, is due to the presence of a small
number of highly mobile carriers which originate from the local regions of the
Fermi surface, presumably, nearby the Van Hove singularity points
Magnetotransport properties of FeSe in fields up to 50T
Magnetotransport properties of the high-quality FeSe crystal, measured in a
wide temperature range and in magnetic fields up to 50 T, show the symmetry of
the main holelike and electronlike bands in this compound. In addition to the
main two bands, there is also a tiny, highly mobile, electronlike band which is
responsible for the non-linear behavior of (B) at low temperatures
and some other peculiarities of FeSe. We observe the inversion of the
temperature coeficient at a magnetic field higher than about 20 T
which is an implicit conformation of the electron-hole symmetry in the main
bands.Comment: MISM 201
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