Municipal Solid Waste Fly Ash-Derived Zeolites as Adsorbents for the Recovery of Nutrients and Heavy Metals—A Review

Though fly ash from the incineration of municipal solid waste (MSW-FA) is considered hazardous waste, its huge and increasing volumes and potential value due to high concentrations of salts and heavy metals such as copper and zinc have attracted commercial interest in mining it for resources. The associated treatments used for extracting these resources may make it economically feasible to extract other constituents from the residuals, adding another potential pathway towards a zero-waste society. This review assesses the feasibility of using zeolites, synthesized from precursors extracted from MSW-FA, as sorbents for the recovery of nutrients (ammonium, nitrate, and phosphate) and heavy metals. It is possible to tailor the properties of the zeolites; however, the large variability in reported adsorption capacities and specificities, as well as the inherent heterogenic nature and variable composition and concentrations of most nutrient- or heavy metal-rich waste streams, make such tailoring challenging. A remaining important issue is the transfer of unwanted micropollutants from the MSW-FA or waste stream to the final products and the loss of surfactants from surfactant-modified zeolites during adsorption and/or desorption of nitrate and/or phosphate. Nonetheless, the recovery process is benefited by high concentrations of the target compounds and low concentrations of competing ions.publishedVersio

Coexisting graphical and structured textual representations of requirements : insights and suggestions

[Context & motivation] Many requirements documents contain graphical and textual representations of requirements side-byside. These representations may be complementary but oftentimes they are strongly related or even express the same content. [Question/problem] Since both representation may be used on their own, we want to nd out why and how a combination of them is used in practice. In consequence, we want to know what advantages such an approach provides and whether challenges arise from the coexistence. [Principal ideas/results] To get more insights into how graphical and textual representations are used in requirements documents, we conducted eight interviews with stakeholders at Daimler. These stakeholders work on a system that is speci ed by tabular textual descriptions and UML activity diagrams. The results indicate that the di erent representations are associated with di erent activities. [Contribution] Our study provides insights into a possible implementation of a speci cation approach using mixed representations of requirements. We use these insights to make suggestions on how to apply the approach in a way that pro ts from its advantages and mitigates potential weaknesses. While we draw our conclusions from a single use case, some aspects might be applicable in general

A case study on a specification approach using activity diagrams in requirements documents

Rising complexity of systems has long been a major challenge in requirements engineering. This manifests in more extensive and harder to understand requirements documents. At the Daimler AG, an approach is applied that combines the use of activity diagrams with natural language specifications to specify system functions. The approach starts with an activity diagram that is created to get an early overview. The contained information is then transferred to a textual requirements document, where details are added and the behavior is refined. While the approach aims to reduce efforts needed to understand a system’s behavior, the application of the approach itself causes new challenges on its own. By examining existing specifications at Daimler, we identified nine categories of inconsistencies and deviations between activity diagrams and their textual representations. In a case study, we examined one system in detail to assess how often these occur. In a follow-up survey, we presented instances of the categories to different stakeholders of the system and let them asses the categories regarding their severity. Our analysis indicates that a coexistence of textual and graphical representations of models without proper tool support results in inconsistencies and deviations that may cause severe maintenance costs or even provoke faults in subsequent development steps

Mechanisms and advancement of antifading agents for fluorescence microscopy and single-molecule spectroscopy

Modern fluorescence microscopy applications go along with increasing demands for the employed fluorescent dyes. In this work, we compared antifading formulae utilizing a recently developed reducing and oxidizing system (ROXS) with commercial antifading agents. To systematically test fluorophore performance in fluorescence imaging of biological samples, we carried out photobleaching experiments using fixed cells labeled with various commonly used organic dyes, such as Alexa 488, Alexa 594, Alexa 647, Cy3B, ATTO 550, and ATTO 647N. Quantitative evaluation of (i) photostability, (ii) brightness, and (iii) storage stability of fluorophores in samples mounted in different antifades (AFs) reveal optimal combinations of dyes and AFs. Based on these results we provide guidance on which AF should preferably be used with a specific dye. Finally, we studied the antifading mechanisms of the commercial AFs using single-molecule spectroscopy and reveal that these empirically selected AFs exhibit similar properties to ROXS AFs

Microservice Architectures for Advanced Driver Assistance Systems: A Case-Study

The technological advancements of recent years have steadily increased the complexity of vehicle-internal software systems, and the ongoing development towards autonomous driving will further aggravate this situation. This is leading to a level of complexity that is pushing the limits of existing vehicle software architectures and system designs. By changing the software structure to a service-based architecture, companies in other domains successfully managed the rising complexity and created a more agile and future-oriented development process. This paper presents a case-study investigating the feasibility and possible effects of changing the software architecture for a complex driver assistance function to a microservice architecture. The complete procedure is described, starting with the description of the software-environment and the corresponding requirements, followed by the implementation, and the final testing. In addition, this paper provides a high-level evaluation of the microservice architecture for the automotive use-case. The results show that microservice architectures can reduce complexity and time-consuming process steps and makes the automotive software systems prepared for upcoming challenges as long as the principles of microservice architectures are carefully followed

Bruk av ozon i akvakultur og fiskeforedling

Ozon er en sterk oksidant som har et stort potensiale som desinfeksjonsmiddel innen akvakultur og fiskeforedling. Målsettingen med prosjektet som er rapportert her var å komme fram til betingelser for bruk av ozon i disse bransjene. Det er gjennomført forsøk med ozonering av Listeria monocytogenes i biofilm, ozonering av overflater i et lakseslakteri, forsøk med felling av blodprotein med naturlige organiske koagulanter før ozonering av blodvann fra et lakseslakteri, samt forsøk med ulike metoder for deozonering av ferskvann og sjøvann.NIVA og Norges forskningsrå

Removal of a cyanotoxins mixture by loose nanofiltration membranes applied in drinking water production

Cyanobacterial toxins may threaten human health if their levels in drinking water exceed certain thresholds. Therefore, it is important for water works that use raw water sources prone to cyanobacterial blooms to have efficient barriers against such toxins. Nanofiltration (NF) is one potential barrier. The efficacy and mechanism of removing four cyanotoxins, namely microcystins (MCs), cylindrospermopsin (CYN), saxitoxins (STXs), and anatoxin (ATX), were studied at bench-scale using NF membranes commonly applied in Norwegian drinking water facilities. The average removal of the different cyanotoxins under the tested operating conditions ranged from 15 % to 96 %. The membrane with the lowest molecular weight cut-off (MWCO) of 0.3 kDa made of polyamide (PA) was deemed the most suitable for the removal of all studied cyanotoxins. A gradual improvement of rejection observed with the 2 kDa cellulose acetate (CA) membrane was linked to the formation of fouling on the membrane surface. Sulfonated polyethersulfone (SPES) membranes with MWCO of 1 and 3 kDa could not efficiently and consistently remove cyanotoxins, except for MCs. The rejection of MCs over time was over 80 % by the SPES membranes during two days of filtration. The influence of pressure and pH as relevant operating parameters was evaluated. However, the analysis of the cyanotoxin concentrations in the permeate indicated that the investigated NF membranes alone would generally not be able to meet the WHO guidelines for drinking water during a severe cyanobacterial bloom. Thus, incorporating other water treatment technologies should be considered to effectively remove cyanotoxins.publishedVersio

Untangling the role of biotic and abiotic ageing of various environmental plastics toward the sorption of metals

Plastic particles can impact the environmental fate and bioavailability of essential inorganic micronutrients and non-essential (toxic) metals. The sorption of metals to environmental plastic has been demonstrated to be facilitated by plastic ageing, a phenomenon encompassing an array of physical, chemical, and biological processes. This study deploys a factorial experiment to untangle the role of different ageing processes in determining the sorption of metals. Plastics made of three different polymer types were aged both through abiotic (ultraviolet irradiation, UV) and biotic (through the incubation with a multispecies algal inoculum forming a biofilm) processes under controlled laboratory conditions. Pristine and aged plastic samples were characterized for their physiochemical properties through Fourier-transformed infrared spectroscopy, scanning electron microscopy and water contact angle measurements. Their sorption affinity toward aluminum (Al) and copper (Cu) in aqueous solutions was then assessed as a response variable. All ageing processes (alone or combined) influenced plastic surface properties resulting in reduced hydrophobicity, changes in surface functional groups (i.e., increase of oxygen containing functional groups after UV ageing and the appearance of marked bands as amides and polysaccharides after biofouling), as well as in nanomorphology. The sorption of Al and Cu was instead statistically dependent (p < 0.01) on the degree of biofouling covering the specimens. Biofouled plastic displayed in fact substantial affinity for metal sorption causing the depletion of up to tenfold Cu and Al compared to pristine polymers, regardless of the polymer type and presence or absence of other ageing treatments. These results confirm the hypothesis that the accumulation of metals on plastic is substantially driven by the biofilm present on environmental plastics. These findings also highlight the importance of investigating the implications of environmental plastic for metal and inorganic nutrients availability in environments impacted by this pollution

Opinion paper about organic trace pollutants in wastewater: Toxicity assessment in a European perspective

This opinion paper focuses on the role of eco-toxicological tools in the assessment of possible impacts of emerging contaminants on the aquatic ecosystem, hence, on human health. Indeed, organic trace pollutants present in raw and treated wastewater are the pivot targets: a multidisciplinary approach allows defining the basic principles for managing this issue, from setting a proper monitoring campaign up to evaluating the optimal process treatment. Giving hints on trace pollutants fate and behaviour, attention is focused on the choice of the bioassay(s), by analysing the meaning of possible biological answers. Data interpretation and exploitation are detailed with the final goal of providing criteria in order to be able to select the best targeted treatment options. The manuscript dealswith conventional and innovative analytical approaches for assessing toxicity, by reviewing laboratory and field assays; illustrative real scale and laboratory applications integrate and exemplify the proposed approach. (C) 2018 Elsevier B.V. All rights reserved.COST-European Cooperation in Science and TechnologyEuropean Cooperation in Science and Technology (COST) [ES1202]; Ministry of Education, Science and Technological Development of the Republic of Serbia [172050]The authors would like to acknowledge the financial support provided by COST-European Cooperation in Science and Technology, to the COST Action ES1202 Conceiving Wastewater Treatment in 2020-Energetic, Environmental and Economic Challenges (Water_2020). Biljana Skrbic would like to thanks the Ministry of Education, Science and Technological Development of the Republic of Serbia for financial support through project no. 172050

Untangling the role of biotic and abiotic ageing of various environmental plastics toward the sorption of metals

Plastic particles can impact the environmental fate and bioavailability of essential inorganic micronutrients and non-essential (toxic) metals. The sorption of metals to environmental plastic has been demonstrated to be facilitated by plastic ageing, a phenomenon encompassing an array of physical, chemical, and biological processes. This study deploys a factorial experiment to untangle the role of different ageing processes in determining the sorption of metals. Plastics made of three different polymer types were aged both through abiotic (ultraviolet irradiation, UV) and biotic (through the incubation with a multispecies algal inoculum forming a biofilm) processes under controlled laboratory conditions. Pristine and aged plastic samples were characterized for their physiochemical properties through Fourier-transformed infrared spectroscopy, scanning electron microscopy and water contact angle measurements. Their sorption affinity toward aluminum (Al) and copper (Cu) in aqueous solutions was then assessed as a response variable. All ageing processes (alone or combined) influenced plastic surface properties resulting in reduced hydrophobicity, changes in surface functional groups (i.e., increase of oxygen containing functional groups after UV ageing and the appearance of marked bands as amides and polysaccharides after biofouling), as well as in nanomorphology. The sorption of Al and Cu was instead statistically dependent (p < 0.01) on the degree of biofouling covering the specimens. Biofouled plastic displayed in fact substantial affinity for metal sorption causing the depletion of up to tenfold Cu and Al compared to pristine polymers, regardless of the polymer type and presence or absence of other ageing treatments. These results confirm the hypothesis that the accumulation of metals on plastic is substantially driven by the biofilm present on environmental plastics. These findings also highlight the importance of investigating the implications of environmental plastic for metal and inorganic nutrients availability in environments impacted by this pollution.publishedVersio