22 research outputs found

    Cooperative thermal and optical switching of spin states in a new two-dimensional coordination polymer

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    {Fe(pmd)2[Cu(CN)2]2} (pmd = pyrimidine) displays a rigid two-dimensional structure and undergoes thermal- and optical-driven spin crossover behaviour; cooperative elastic coupling between iron(II) ions in the framework induces thermal hysteresis in the HS↔LS conversion and sigmoidal HS→LS relaxation of the photo-induced HS state at low temperatures.Niel, Virginie, [email protected] ; Galet Domingo, Ana Guadalupe, [email protected] ; Gaspar Pedros, Ana Belen, [email protected] ; Real Cabezos, Jose Antonio, [email protected]

    Spin crossover in 1D, 2D and 3D polymeric Fe(II) networks

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    In this chapter, structural and spin transition aspects of the most important families of polymeric Fe(II) compounds are reviewed. These coordination compounds contain N-donor heterocyclic 1,2,4-triazole, 1-R-tetrazole and bis monodentate pyridine-like bridging ligands. Recent results involving new series of polymeric compounds formed by the combination of organic and inorganic tetra- and dicyanometallate complex bridging ligands are also discussed

    CCDC 228041: Experimental Crystal Structure Determination

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    An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures

    CCDC 228044: Experimental Crystal Structure Determination

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    An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures

    CCDC 228043: Experimental Crystal Structure Determination

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    An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures

    CCDC 228045: Experimental Crystal Structure Determination

    No full text
    An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures
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