Novel Topologies in Vanadium-bis-ß-Diketone Chemistry: A [V4] and a [V6] Metallacyclophane

Exploring the chemistry of vanadyl ions (VO2+) with bis-ß-diketone ligands, in pyridine reactions of vanadyl sulfate with 1, 3-bis-(3-oxo-3-(2-hydroxyphenyl)-propionyl)-benzene (H4L1) and 1, 3-bis-(3-oxo-3-(2-hydroxyphenyl)-propionyl)-pyridine (H4L2), two novel clusters, (VIVO)4(H2L1)4(py)4] (1) and (VVO)4(VIVO)2 (O)4(L2)2(py)6] (2) were prepared and characterized. Due to the conformational flexibility of the ligands, both entities exhibit very peculiar metal topologies and composition, differing significantly from structural patterns established in the related chemistry of divalent 3d metals. Structural analysis also unveils the existence of the most complex metallamacrocycles from this family to date. Studies of the magnetic properties via bulk magnetization measurements and EPR spectroscopy confirmed the existence of uncoupled long-distant S = 1/2 metal centers and the spin ground states S = 2 and S = 1 of the clusters

Constraint on teleportation over multipartite pure states

We first define a quantity exhibiting the usefulness of bipartite quantum states for teleportation, called the quantum teleportation capability, and then investigate its restricted shareability in multi-party quantum systems. In this work, we verify that the quantum teleportation capability has a monogamous property in its shareability for arbitrary three-qutrit pure states by employing the monogamy inequality in terms of the negativity.Comment: 4 pages, 1 figur

On the behavior of CO oxidation on shape-controlled Pt nanoparticles in alkaline medium

In this work, the behavior of the CO electro-oxidation reaction on shape-controlled Pt nanoparticles in alkaline medium was examined in order to understand the effect of the surface structure on this reaction. A series of experiments using Pt nanoparticles of different surface structures/shapes was used and the results obtained were compared with the previous knowledge gained from stepped platinum single crystal electrodes. Independently of the preferential orientation of the nanoparticles, the CO oxidation voltammetry exhibits two main peaks: one at ca. 0.56–0.59 V and the second one at 0.66–0.67 V, being the intensity of the peaks dependent on the shape of the nanoparticle. These two peaks have been assigned to the oxidation of CO on the (1 1 1) terraces and on the rest of the sites, respectively. The appearance of two differentiated peaks reveals that these (1 1 1) terraces and the rest of the sites on the nanoparticle surface behave independently of the presence of the other type of sites, that is, they are not connected. The results are discussed considering the effects of the surface mobility of CO and of the OH adsorption properties on the different sites in the oxidation peaks.Farias, M.J.S. would like to thanks CNPq, Brazil, for financial support for his postdoctoral stay at Universidad de Alicante. This work has been financially supported by the MICINN (Spain) (project CTQ2010-16271) and Generalitat Valenciana (project PROMETEO/2009/045, FEDER)

The epidemiology of dry eye disease in the UK: The Aston dry eye study

Purpose: Cross-sectional studies on dry eye disease (DED) have relied on different diagnoses hindering conclusions about the disease epidemiology. This study offers an insight into DED epidemiology in the UK using prior and recent diagnostic recommendations. Methods: Study participants comprised 282 volunteers from Birmingham, UK (median 40 years, range 18–88 years, 56% females). DED was defined by the Tear Film Ocular Surface Dry Eye Workshop II (TFOS DEWS II) criteria, based on a positive symptom score with the Dry Eye Questionnaire (DEQ-5) and Ocular Surface Disease Index (OSDI), and one of the following homeostasis markers: non-invasive tear break-up time of 8 mOsm/L (TearLab Osmolarity System); or > 5 corneal spots, >9 conjunctival spots or lower/upper lid-wiper-epitheliopathy staining of ≥ 2 mm length and ≥ 25% width (Oculus Keratograph 5 M). In addition, the Women's Health Study (WHS) criteria, based on symptoms or a prior dry eye diagnosis, was assessed. DED risk factors were gathered using a self-administered questionnaire. Results: DED prevalence by the TFOS DEWS II criteria was 32.1% (95% confidence interval 25.5–37.7% and 29.5% (95% confidence interval 24.4–35.1% by the WHS criteria. Female sex, systemic and/or ocular health conditions, short sleep duration and prolonged outdoor leisure time spent were significant DED risk factors (p ≤ 0.05). Conclusions: Approximately one-third of the adult UK population have DED, aligning with the prevalence reported in multiple counties globally. Female sex, systemic/ocular health conditions, short sleep duration and prolonged outdoor leisure time are positive predictors of DED

On the geometric distance between quantum states with positive partial transposition and private states

We prove an analytic positive lower bound for the geometric distance between entangled positive partial transpose (PPT) states of a broad class and any private state that delivers one secure key bit. Our proof holds for any Hilbert space of finite dimension. Although our result is proven for a specific class of PPT states, we show that our bound nonetheless holds for all known entangled PPT states with non-zero distillable key rates whether or not they are in our special class.Comment: 16 page

Efficient quantum key distribution scheme with nonmaximally entangled states

We propose an efficient quantum key distribution scheme based on entanglement. The sender chooses pairs of photons in one of the two equivalent nonmaximally entangled states randomly, and sends a sequence of photons from each pair to the receiver. They choose from the various bases independently but with substantially different probabilities, thus reducing the fraction of discarded data, and a significant gain in efficiency is achieved. We then show that such a refined data analysis guarantees the security of our scheme against a biased eavesdropping strategy.Comment: 5 Pages, No Figur

Formic acid electrooxidation on thallium-decorated shape-controlled platinum nanoparticles: an improvement in electrocatalytic activity

Thallium modified shape-controlled Pt nanoparticles were prepared and their electrocatalytic activity towards formic acid electrooxidation was evaluated in 0.5 M sulfuric acid. The electrochemical and in situ FTIR spectroscopic results show a remarkable improvement in the electrocatalytic activity, especially in the low potential region (around 0.1–0.2 V vs. RHE). Cubic Pt nanoparticles modified with Tl were found to be more active than the octahedral Pt ones in the entire range of Tl coverages and potential windows. In situ FTIR spectra indicate that the promotional effect produced by Tl results in the inhibition of the poisoning step leading to COads, thus improving the onset potential for the complete formic acid oxidation to CO2. Chronoamperometric experiments were also performed at 0.2 V to evaluate the stability of the electrocatalysts at constant potential. Finally, experiments with different concentrations of formic acid (0.05–1 M) were also carried out. In all cases, Tl-modified cubic Pt nanoparticles result to be the most active. All these facts reinforce the importance of controlling the surface structure of the electrocatalysts to optimize their electrocatalytic properties.This work has been financially supported by the MICINN (Spain) (project CTQ2010-16271) and Generalitat Valenciana (project PROMETEO/2009/045 – FEDER)

Non-equilibrium entangled steady state of two independent two-level systems

We determine and study the steady state of two independent two-level systems weakly coupled to a stationary non-equilibrium environment. Whereas this bipartite state is necessarily uncorrelated if the splitting energies of the two-level systems are different from each other, it can be entangled if they are equal. For identical two-level systems interacting with two bosonic heat baths at different temperatures, we discuss the influence of the baths temperatures and coupling parameters on their entanglement. Geometric properties, such as the baths dimensionalities and the distance between the two-level systems, are relevant. A regime is found where the steady state is a statistical mixture of the product ground state and of the entangled singlet state with respective weights 2/3 and 1/3

Output state in multiple entanglement swapping

The technique of quantum repeaters is a promising candidate for sending quantum states over long distances through a lossy channel. The usual discussions of this technique deals with only a finite dimensional Hilbert space. However the qubits with which one implements this procedure will "ride" on continuous degrees of freedom of the carrier particles. Here we analyze the action of quantum repeaters using a model based on pulsed parametric down conversion entanglement swapping. Our model contains some basic traits of a real experiment. We show that the state created, after the use of any number of parametric down converters in a series of entanglement swappings, is always an entangled (actually distillable) state, although of a different form than the one that is usually assumed. Furthermore, the output state always violates a Bell inequality.Comment: 11 pages, 6 figures, RevTeX

Evidence for concerted and mosaic brain evolution in dragon lizards

The brain plays a critical role in a wide variety of functions including behaviour, perception, motor control, and homeostatic maintenance. Each function can undergo different selective pressures over the course of evolution, and as selection acts on the outputs of brain function, it necessarily alters the structure of the brain. Two models have been proposed to explain the evolutionary patterns observed in brain morphology. The concerted brain evolution model posits that the brain evolves as a single unit and the evolution of different brain regions are coordinated. The mosaic brain evolution model posits that brain regions evolve independently of each other. It is now understood that both models are responsible for driving changes in brain morphology; however, which factors favour concerted or mosaic brain evolution is unclear. Here, we examined the volumes of the 6 major neural subdivisions across 14 species of the agamid lizard genus Ctenophorus (dragons). These species have diverged multiple times in behaviour, ecology, and body morphology, affording a unique opportunity to test neuroevolutionary models across species. We assigned each species to an ecomorph based on habitat use and refuge type, then used MRI to measure total and regional brain volume. We found evidence for both mosaic and concerted brain evolution in dragons: concerted brain evolution with respect to body size, and mosaic brain evolution with respect to ecomorph. Specifically, all brain subdivisions increase in volume relative to body size, yet the tectum and rhombencephalon also show opposite patterns of evolution with respect to ecomorph. Therefore, we find that both models of evolution are occurring simultaneously in the same structures in dragons, but are only detectable when examining particular drivers of selection. We show that the answer to the question of whether concerted or mosaic brain evolution is detected in a system can depend more on the type of selection measured than on the clade of animals studied. (C) 2017 S. Karger AG, Base