Provenance and recycling of Sahara Desert sand

We here present the first comprehensive provenance study of the Sahara Desert using a combination of multiple provenance proxies and state-of-the-art statistical analysis. Our dataset comprises 44 aeolian-dune samples, collected across the region from 12°N (Nigeria) to 34°N (Tunisia) and from 33°E (Egypt) to 16°W (Mauritania) and characterized by bulk-petrography, heavy-mineral, and detrital-zircon Usingle bondPb geochronology analyses. A set of statistical tools including Multidimensional Scaling, Correspondence Analysis, Individual Difference Scaling, and General Procrustes Analysis was applied to discriminate among sample groups with the purpose to reveal meaningful compositional patterns and infer sediment transport pathways on a geological scale. The overall homogenity across sand samples, however, precluded a detailed narrative. Saharan dune fields are, with a few local exceptions, composed of pure quartzose sand with very poor heavy-mineral suites dominated by durable zircon, tourmaline, and rutile. Some feldspars, amphibole, epidote, garnet, or staurolite occur closer to basement exposures, and carbonate grains, clinopyroxene and olivine near a basaltic field in Libya. Relatively varied compositions also characterize sand along the Nile Valley and the southern front of the Anti-Atlas fold belt in Morocco. Otherwise, from the Sahel to the Mediterranean Sea and from the Nile River to the Atlantic Ocean, sand consists nearly exclusively of quartz and durable minerals. These have been concentrated through multiple cycles of erosion, deposition, and diagenesis of Phanerozoic siliciclastic rocks during the long period of relative tectonic quiescence that followed the Neoproterozoic Pan-African orogeny, the last episode of major crustal growth in the region. The principal ultimate source of recycled sand is held to be represented by the thick blanket of quartz-rich sandstones that were deposited in the Cambro-Ordovician from the newly formed Arabian-Nubian Shield in the east to Mauritania in the west. Durability of zircon grains and their likelihood to be recycled from older sedimentary rocks argues against the assumption, too often implicitly taken for granted in provenance studies based on detrital-zircon ages, that their age distribution reflects transport pathways existing at the time of deposition rather than inheritance from multiple and remote landscapes of the past

Provenance of Kalahari Sand: Paleoweathering and recycling in a linked fluvial-aeolian system

We here review what is known about the dunefields and fluvial systems of the Kalahari Basin in terms of geological setting and Quaternary dynamics and set out what has been hypothesized about the provenance of Kalahari sand so far. Previous work has tackled this problem by applying a limited number of techniques (mostly sediment textures and heavy minerals) to parts of the large dryland. The generally highly quartzose mineralogy of aeolian dunes and their compositional variability have been only broadly evaluated and several sedimentological issues have thus remained controversial, including the relative role played by fluvial processes versus aeolian reworking of older sediments and weathering controls. This reveals a need for a systematic provenance study that considers the entire basin. For this reason, here we combine original petrographic, heavy-mineral, and detrital-zircon geochronology data with previously published clay-mineral, geochemical, and geochronological information to present the first comprehensive provenance study of the vast Kalahari sand sea. Our multi-proxy dataset comprises 100 samples, collected across the Kalahari Basin from 11°S (NW Zambia) to 28°S (NW South Africa) and from 15°E (Angola) to 28°30′W (Zimbabwe). Kalahari aeolian-dune sand mostly consists of monocrystalline quartz associated with durable heavy minerals and thus drastically differs from coastal dunefields of Namibia and Angola, which are notably richer in feldspar, lithic grains, and chemically labile clinopyroxene. The western Kalahari dunefield of southeastern Namibia is distinguished by its quartz-rich feldspatho-quartzose sand, indicating partly first-cycle provenance from the Damara Belt and Mesoproterozoic terranes. Within the basin, supply from Proterozoic outcrops is documented locally. Composition varies notably at the western and eastern edges of the sand sea, reflecting partly first-cycle fluvial supply from crystalline basements of Cambrian to Archean age in central Namibia and western Zimbabwe. Basaltic detritus from Jurassic Karoo lavas is dominant in aeolian dunes near Victoria Falls. Bulk-sediment petrography and geochemistry of northern and central Kalahari pure quartzose sand, together with heavy-mineral and clay-mineral assemblages, indicate extensive recycling via aeolian and ephemeral-fluvial processes in arid climate of sediment strongly weathered during previous humid climatic stages in subequatorial Africa. Distilled homogenized composition of aeolian-dune sand thus reverberates the echo of paleo-weathering passed on to the present landscape through multiple episodes of fluvial and aeolian recycling. Intracratonic sag basins such as the Kalahari contain vast amounts of quartz-rich polycyclic sand that may be tapped by rivers eroding backwards during rejuvenation stages associated with rift propagation. Such an event may considerably increase the sediment flux to the ocean, fostering the progradation of river-fed continental-embankments, as documented by augmented accumulation rates coupled with upward increasing mineralogical durability in the post-Tortonian subsurface succession of the Zambezi Delta. The Central Kalahari is not a true desert. It has none of the naked, shifting sand dunes that typify the Sahara and other great deserts of the world. In some years the rains may exceed twenty — once even forty — inches, awakening a magic green paradise.” Mark Owens, Cry of the Kalahari

The Segmented Zambezi Sedimentary System from Source to Sink: 1. Sand Petrology and Heavy Minerals

The Zambezi River rises at the center of southern Africa, flows across the low-relief Kalahari Plateau, meets Karoo basalt, plunges into Victoria Falls, follows along Karoo rifts, and pierces through Precambrian basement to eventually deliver its load onto the Mozambican passive margin. Reflecting its polyphase evolution, the river is subdivided into segments with different geological and geomorphological character, a subdivision finally fixed by man’s construction of large reservoirs and faithfully testified by sharp changes in sediment composition. Pure quartzose sand recycled from Kalahari desert dunes in the uppermost tract is next progressively enriched in basaltic rock fragments and clinopyroxene. Sediment load is renewed first downstream of Lake Kariba and next downstream of Lake Cahora Bassa, documenting a stepwise decrease in quartz and durable heavy minerals. Composition becomes quartzo-feldspathic in the lower tract, where most sediment is supplied by high-grade basements rejuvenated by the southward propagation of the East African rift. Feldspar abundance in Lower Zambezi sand has no equivalent among big rivers on Earth and far exceeds that in sediments of the northern delta, shelf, and slope, revealing that provenance signals from the upper reaches have ceased to be transmitted across the routing system after closure of the big dams. This high-resolution petrologic study of Zambezi sand allows us to critically reconsider several dogmas, such as the supposed increase of mineralogical “maturity” during long-distance fluvial transport, and forges a key to unlock the rich information stored in sedimentary archives, with the ultimate goal to accurately reconstruct the evolution of this mighty river flowing across changing African landscapes since the late Mesozoic

Tectono-metallogenetic evolution of the Fe–Cu deposit of Dominga, northern Chile

The Dominga district in northern Chile (2082 Mt at 23.3 % Fe, 0.07 % Cu) shows a spatial and genetic affinity among distinctive structural elements and Fe–Cu-rich paragenetic mineral assemblages. Deep seated, NE-to-E striking structural elements form a right-lateral duplex-like structural system (early structural system, ESS) that cuts a regionally extensive alteration (stage I) zone. The EES system served as a locus and as path for the emplacement of biotite–magnetite alteration/mineralization (stage IIa) as veins and Fe-bearing layers following altered volcano sedimentary strata. NW-striking actinolite–magnetite hydrothermal breccias, coeval with and part of the ESS, include apatite (stage IIb) crystallized at 127 ± 15 Ma (U–Pb, 2σ). The ESS was also the locus of subsequent alteration/mineralization represented by K-feldspar, epidote, and albite (stage IIIa) and Fe–Cu-rich (vermiculite–anhydrite–chalcopyrite, stage IIIb) mineral associations. Shallowly developed, NNE-striking, left-lateral structural elements defining the El Tofo Structural System (ETSS)—probably part of the Atacama Fault System—clearly crosscut the ESS. Minerals associated with alteration/mineralization stage IIIb also occur as veins and as part of hydrothermal breccias of the ETSS, marking the transition from the ESS to ETSS. Molybdenite associated with alteration/mineralization stage IIIb yielded a Re–Os age of 127.1 ± 0.7 Ma (2σ). Both the ESS and ETSS were cut by left-lateral, NW- to E-striking shallowly developed structural elements (Intermediate Structural System, ISS) on which a hematite–calcite assemblage (stage IV) occurs mostly as infill material of veins and fault veins. The ISS is cut by N-striking, left-lateral, and shallowly developed structural elements (Late Structural System, LSS) showing no evidence of alteration/mineralization. Estimated strain and stress fields indicate an overall NW-trending shortening/compression and NE-trending stretching/tension strike-slip regime probably due to oblique subduction during the Mesozoic. However, the orientations of the stress and strain fields calculated for each structural system suggest a back-and-forth rotation pattern during transition from one structural system to the other—as they change between transtension and transpression—and between alteration/mineralization stages

Zircon as a provenance tracer: Coupling Raman spectroscopy and Usingle bondPb geochronology in source-to-sink studies

Usingle bondPb zircon geochronology is one of the most widely used techniques in sedimentary provenance analysis. Unfortunately, the ability of this method to identify sediment sources is often degraded by sediment recycling and mixing of detritus from different source rocks sharing similar age signatures. These processes create non-unique zircon Usingle bondPb age signatures and thereby obscure the provenance signal. We here address this problem by combining detrital zircon Usingle bondPb geochronology with Raman spectroscopy. The position and width of the Raman signal in zircon scales with its degree of metamictization, which in turn is sensitive to temperature. Thus, combined U-Pb + Raman datasets encode information about the crystallization history of detrital zircons as well as their thermal history. Using three borehole samples from Mozambique as part of a source-to-sink study of interest for hydrocarbon exploration, we show that zircon populations with similar Usingle bondPb age distributions can exhibit different Raman signatures. The joint U-Pb + Raman analysis allowed us to identify three different annealing trends, which were linked to specific thermal events. Thus we were able to differentiate a dominant Pan-African Usingle bondPb age peak into several sub-populations and highlight the major effect of Karoo tectono-magmatic events. In our case study, we used Raman also as a means to systematically identify all zircon grains in heavy-mineral mounts, resulting in considerable time savings. Raman spectroscopy is a non-destructive and cost-effective method that is easily integrated in the zircon Usingle bondPb dating workflow to augment the resolution power of detrital zircon Usingle bondPb geochronology

Molecular cytogenetic characterisation of a mosaic add(12)(p13.3) with an inv dup(3)(q26.31 --> qter) detected in an autistic boy

BACKGROUND: Inverted duplications (inv dup) of a terminal chromosome region are a particular subset of rearrangements that often results in partial tetrasomy or partial trisomy when accompanied by a deleted chromosome. Associated mosaicism could be the consequence of a post-zygotic event or could result from the correction of a trisomic conception. Tetrasomies of distal segments of the chromosome 3q are rare genetic events and their phenotypic manifestations are diverse. To our knowledge, there are only 12 cases reported with partial 3q tetrasomy. Generally, individuals with this genomic imbalance present mild to severe developmental delay, facial dysmorphisms and skin pigmentary disorders. RESULTS: We present the results of the molecular cytogenetic characterization of an unbalanced mosaic karyotype consisting of mos 46,XY,add(12)(p13.3) [56]/46,XY [44] in a previously described 11 years old autistic boy, re-evaluated at adult age. The employment of fluorescence in situ hybridization (FISH) and multicolor banding (MCB) techniques identified the extra material on 12p to be derived from chromosome 3, defining the additional material on 12p as an inv dup(3)(qter --> q26.3::q26.3 --> qter). Subsequently, array-based comparative genomic hybridization (aCGH) confirmed the breakpoint at 3q26.31, defining the extra material with a length of 24.92 Mb to be between 174.37 and 199.29 Mb. CONCLUSION: This is the thirteenth reported case of inversion-duplication 3q, being the first one described as an inv dup translocated onto a non-homologous chromosome. The mosaic terminal inv dup(3q) observed could be the result of two proposed alternative mechanisms. The most striking feature of this case is the autistic behavior of the proband, a characteristic not shared by any other patient with tetrasomy for 3q26.31 --> 3qter. The present work further illustrates the advantages of the use of an integrative cytogenetic strategy, composed both by conventional and molecular techniques, on providing powerful information for an accurate diagnosis. This report also highlights a chromosome region potentially involved in autistic disorders

Late Miocene hinterland crustal shortening in the Longmen Shan thrust belt, the eastern margin of the Tibetan Plateau

Long‐term (million‐year time scale) fault‐slip history is crucial for understanding the processes and mechanisms of mountain building in active orogens. Such information remains elusive in the Longmen Shan, the eastern Tibetan Plateau margin affected by the devastating 2008 Wenchuan earthquake. Whilst this event drew attention to fault deformation on the foreland side (the Yingxiu‐Beichuan fault), little is known about the deformation history of the hinterland Wenchuan‐Maoxian fault. To address this gap, thermochronological data were obtained from two vertical transects from the Xuelongbao massif, located in the hanging wall of the Wenchuan‐Maoxian fault. The data record late Miocene rapid cooling and rock exhumation at a rate of 0.9‐1.2 km/m.y. from ~13 Ma to present. The exhumation rate is significantly higher than that in the footwall (~0.3‐0.5 km/m.y.), indicating a differential exhumation of ~0.6 km/m.y. across the fault. This differential exhumation provides the first and minimum constraint on the long‐term throw rate (~0.6 km/m.y) of the Wenchuan‐Maoxian fault since the late Miocene. This new result implies continuous crustal shortening along the hinterland fault of Longmen Shan, even though it has not been ruptured by major historic earthquakes. Our study lends support to geodynamic models that highlight crustal shortening as dominating deformation along the eastern Tibetan Plateau

Statistics for Fission-Track Thermochronology

This chapter introduces statistical tools to extract geologically meaningful information from fission-track (FT) data using both the external detector and LA-ICP-MS methods. The spontaneous fission of 238U is a Poisson process resulting in large single-grain age uncertainties. To overcome this imprecision, it is nearly always necessary to analyse multiple grains per sample. The degree to which the analytical uncertainties can explain the observed scatter of the single-grain data can be visually assessed on a radial plot and objectively quantified by a chi-square test. For sufficiently low values of the chi-square statistic (or sufficiently high p values), the pooled age of all the grains gives a suitable description of the underlying ‘true’ age population. Samples may fail the chi-square test for several reasons. A first possibility is that the true age population does not consist of a single discrete age component, but is characterised by a continuous range of ages. In this case, a ‘random effects’ model can constrain the true age distribution using two parameters: the ‘central age’ and the ‘(over)dispersion’. A second reason why FT data sets might fail the chi-square test is if they are underlain by multimodal age distributions. Such distributions may consist of discrete age components, continuous age distributions, or a combination of the two. Formalised statistical tests such as chi-square can be useful in preventing overfitting of relatively small data sets. However, they should be used with caution when applied to large data sets (including length measurements) which generate sufficient statistical ‘power’ to reject any simple yet geologically plausible hypothesis

The Euphrates-Tigris-Karun river system: Provenance, recycling and dispersal of quartz-poor foreland-basin sediments in arid climate

We present a detailed sediment-provenance study on the modern Euphrates-Tigris-Karun fluvial system and Mesopotamian foreland basin, one of the cradles of humanity. Our rich petrographic and heavy-mineral dataset, integrated by sand geochemistry and U–Pb age spectra of detrital zircons, highlights the several peculiarities of this large source-to-sink sediment-routing system and widens the spectrum of compositions generally assumed as paradigmatic for orogenic settings. Comparison of classical static versus upgraded dynamic petrologic models enhances the power of provenance analysis, and allows us to derive a more refined conceptual model of reference and to verify the limitations of the approach. Sand derived from the Anatolia-Zagros orogen contains abundant lithic grains eroded from carbonates, cherts, mudrocks, arc volcanics, obducted ophiolites and ophiolitic mélanges representing the exposed shallow structural level of the orogen, with relative scarcity of quartz, K-feldspar and mica. This quartz-poor petrographic signature, characterizing the undissected composite tectonic domain of the entire Anatolia-Iranian plateau, is markedly distinct from that of sand shed by more elevated and faster-eroding collision orogens such as the Himalaya. Arid climate in the region allows preservation of chemically unstable grains including carbonate rock fragments and locally even gypsum, and reduces transport capacity of fluvial systems, which dump most of their load in Mesopotamian marshlands upstream of the Arabian/Persian Gulf allochemical carbonate factory. Quartz-poor sediment from the Anatolia-Zagros orogen mixes with quartz-rich recycled sands from Arabia along the western side of the foreland basin, and is traced all along the Gulf shores as far as the Rub' al-Khali sand sea up to 4000 km from Euphrates headwaters

Recurrent reciprocal deletions and duplications of 16p13.11: the deletion is a risk factor for MR/MCA while the duplication may be a rare benign variant

Background: Genomic disorders are often caused by non-allelic homologous recombination between segmental duplications. Chromosome 16 is especially rich in a chromosome-specific low copy repeat, termed LCR16. Methods and Results: A bacterial artificial chromosome (BAC) array comparative genome hybridisation (CGH) screen of 1027 patients with mental retardation and/or multiple congenital anomalies (MR/MCA) was performed. The BAC array CGH screen identified five patients with deletions and five with apparently reciprocal duplications of 16p13 covering 1.65 Mb, including 15 RefSeq genes. In addition, three atypical rearrangements overlapping or flanking this region were found. Fine mapping by high-resolution oligonucleotide arrays suggests that these deletions and duplications result from non-allelic homologous recombination (NAHR) between distinct LCR16 subunits with >99% sequence identity. Deletions and duplications were either de novo or inherited from unaffected parents. To determine whether these imbalances are associated with the MR/MCA phenotype or whether they might be benign variants, a population of 2014 normal controls was screened. The absence of deletions in the control population showed that 16p13.11 deletions are significantly associated with MR/MCA (p = 0.0048). Despite phenotypic variability, common features were identified: three patients with deletions presented with MR, microcephaly and epilepsy (two of these had also short stature), and two other deletion carriers ascertained prenatally presented with cleft lip and midline defects. In contrast to its previous association with autism, the duplication seems to be a common variant in the population (5/1682, 0.29%). Conclusion: These findings indicate that deletions inherited from clinically normal parents are likely to be causal for the patients' phenotype whereas the role of duplications (de novo or inherited) in the phenotype remains uncertain. This difference in knowledge regarding the clinical relevance of the deletion and the duplication causes a paradigm shift in (cyto) genetic counselling