The oxalato complexes of titanium(IV)—I : Mononuclear Ti(OH)2(C2O4)22− in solution

Molecular weight, electrodialysis and anion exchange measurements between pH 1 and 4 showed that the titanyl oxalate anion is present in solution as mononuclear Ti(OH)2(C2O4)22 units. pH studies of solutions of (NH4)2TiO(C2O4)2·H2O in 0.5 M NaClO4 medium and computer evaluation and simulation by LETAGROP and HALTAFALL showed that the behaviour of such solutions can be simulated by applying stability constants of log β1 = 7.90 ± 0.02 and log β2 = 13.24 ± 0.07, when using hydrolysis constants given by Nazarenko et al.\ud \ud In an attempt to determine the stability constant β2 spectrophotometrically using an exchange method with pyrocatechol, a mixed ligand complex was found with a Ti:pyrocatechol:oxalate ratio of 1 : 1 : 1

Neural blackboard architectures of combinatorial structures in cognition

Human cognition is unique in the way in which it relies on combinatorial (or compositional) structures. Language provides ample evidence for the existence of combinatorial structures, but they can also be found in visual cognition. To understand the neural basis of human cognition, it is therefore essential to understand how combinatorial structures can be instantiated in neural terms. In his recent book on the foundations of language, Jackendoff described four fundamental problems for a neural instantiation of combinatorial structures: the massiveness of the binding problem, the problem of 2, the problem of variables and the transformation of combinatorial structures from working memory to long-term memory. This paper aims to show that these problems can be solved by means of neural ‘blackboard’ architectures. For this purpose, a neural blackboard architecture for sentence structure is presented. In this architecture, neural structures that encode for words are temporarily bound in a manner that preserves the structure of the sentence. It is shown that the architecture solves the four problems presented by Jackendoff. The ability of the architecture to instantiate sentence structures is illustrated with examples of sentence complexity observed in human language performance. Similarities exist between the architecture for sentence structure and blackboard architectures for combinatorial structures in visual cognition, derived from the structure of the visual cortex. These architectures are briefly discussed, together with an example of a combinatorial structure in which the blackboard architectures for language and vision are combined. In this way, the architecture for language is grounded in perception

Extended-Linking Services: towards a Quality Web

A URL takes requesters from a citation to a destination… provided, of course, the URL is still valid. The current chaotic web is wonderful in its way. However, within this chaotic web, we believe there is a need for a high-quality web of vetted information. The emerging OpenURL standard is the cornerstone of a worldwide web with high-quality links that feature properties such as: •Persistence: Increase the probable lifetime of citations. •Multiplicity: Produce a menu of targeted services for each citation. •Context-Sensitivity: Resolve a citation in a manner appropriate to the user and to the context. To encourage the development of extended-linking services, NISO formed a committee to develop a standard OpenURL syntax. Our immediate goal is to serve the scholarly-information community immediately. However, the OpenURL technique is widely applicable, and we expect to serve many other information communities

Connectivity between coastal habitats of two oceanic Caribbean islands as inferred from ontogenetic shifts by coral reef fishes

Mangroves and seagrass beds are considered important nursery habitats for juveniles of coral reef fishes. Studies have mostly focused on the fish community of just one habitat, so the connectivity between different coastal habitats is often unclear. In this study, density and size of reef fish were determined using a single sampling technique in four non-estuarine bay habitats and four reef zones in Curaçao and Bonaire (Netherlands Antilles). The data indicate that of the complete reef fish community at least 21 species show ontogenetic crossshelf shifts in habitat utilization. The 21 species mainly utilized shallow-water habitats (mangroves, seagrass beds, channel and shallow reef) as nursery habitats and the deeper coral reef zones (\u3e 5 m depth) as adult lifestage habitats. Fish species utilized 1–3 different nursery habitats simultaneously, but habitat utilization clearly differed between species. Previous studies showed that the dependence on these nursery habitats is very high, based on reduced density or absence of adults on coral reefs where these habitats were absent. The strong connectivity between several coastal habitats during the ontogeny of various commercially important reef fish species is evidence for the inclusion of bay habitats within boundaries of fishery reserves or marine protected areas

Transition UGent: a bottom-up initiative towards a more sustainable university

The vibrant think-tank ‘Transition UGent’ engaged over 250 academics, students and people from the university management in suggesting objectives and actions for the Sustainability Policy of Ghent University (Belgium). Founded in 2012, this bottom-up initiative succeeded to place sustainability high on the policy agenda of our university. Through discussions within 9 working groups and using the transition management method, Transition UGent developed system analyses, sustainability visions and transition paths on 9 fields of Ghent University: mobility, energy, food, waste, nature and green, water, art, education and research. At the moment, many visions and ideas find their way into concrete actions and policies. In our presentation we focused on the broad participative process, on the most remarkable structural results (e.g. a formal and ambitious Sustainability Vision and a student-led Sustainability Office) and on recent actions and experiments (e.g. a sustainability assessment on food supply in student restaurants, artistic COP21 activities, ambitious mobility plans, food leftovers projects, an education network on sustainability controversies, a transdisciplinary platform on Sustainable Cities). We concluded with some recommendations and reflections on this transition approach, on the important role of ‘policy entrepreneurs’ and student involvement, on lock-ins and bottlenecks, and on convincing skeptical leaders

Alternating-Direction Line-Relaxation Methods on Multicomputers

We study the multicom.puter performance of a three-dimensional Navier–Stokes solver based on alternating-direction line-relaxation methods. We compare several multicomputer implementations, each of which combines a particular line-relaxation method and a particular distributed block-tridiagonal solver. In our experiments, the problem size was determined by resolution requirements of the application. As a result, the granularity of the computations of our study is finer than is customary in the performance analysis of concurrent block-tridiagonal solvers. Our best results were obtained with a modified half-Gauss–Seidel line-relaxation method implemented by means of a new iterative block-tridiagonal solver that is developed here. Most computations were performed on the Intel Touchstone Delta, but we also used the Intel Paragon XP/S, the Parsytec SC-256, and the Fujitsu S-600 for comparison

Balanced dynamics in the Tropics

For the shallow-water equations on an equatorial beta plane, the properties of low-frequency Rossby waves and (mixed) Rossby-gravity waves are investigated. It is shown that in the low-frequency limit the horizontal divergence of these solutions is zero and their geopotential satisfies = f, where f = y is the Coriolis parameter and is the stream function of the non-divergent velocity field. This type of balance is rather different from the geostrophic balance satisfied by Kelvin waves. It can be used to formulate a balanced potential vorticity equation in the single variable that, while filtering out Kelvin waves and inertia-gravity waves, exactly reproduces Rossby waves and Rossby-gravity waves in the low-frequency limit