Electron transport through rectifying self-assembled monolayer diodes on silicon: Fermi level pinning at the molecule-metal interface

We report the synthesis and characterization of molecular rectifying diodes on silicon using sequential grafting of self-assembled monolayers of alkyl chains bearing a pi group at their outer end (Si/sigma-pi/metal junctions). We investigate the structure-performance relationships of these molecular devices and we examine to what extent the nature of the pi end-group (change in the energy position of their molecular orbitals) drives the properties of these molecular diodes. For all the pi-groups investigated here, we observe rectification behavior. These results extend our preliminary work using phenyl and thiophene groups (S. Lenfant et al., Nano Letters 3, 741 (2003)).The experimental current-voltage curves are analyzed with a simple analytical model, from which we extract the energy position of the molecular orbital of the pi-group in resonance with the Fermi energy of the electrodes. We report the experimental studies of the band lineup in these silicon/alkyl-pi conjugated molecule/metal junctions. We conclude that Fermi level pinning at the pi-group/metal interface is mainly responsible for the observed absence of dependence of the rectification effect on the nature of the pi-groups, even though they were chosen to have significant variations in their electronic molecular orbitalsComment: To be published in J. Phys. Chem.

Ownership Characteristics of Heir Property in a Black Belt County: A Quantitative Approach

The existing literature identifies heir property, land held communally by heirs of someone who has died without a will, as a primary cause of land loss among African Americans and a major factor contributing to persistent poverty in the South’s demographically-defined Black Belt. Despite the importance of this form of property, little systematic research has been done to quantify the extent of heir property or the potential wealth tied up in clouded titles. This study documents the presence of more than 1,500 heir property parcels in one Alabama Black Belt county (Macon) and describes the methodological challenges involved in such research. Our analysis identified distinctive characteristics of and significant relationships between a set of key ownership variables (taxpayer location, size and value of land, structural improvements, and municipal incorporation). We argue the need to document the extent and consequences of heir property to spur action by legislators, Extension Systems across the region, and pro-bono attorneys, among others, to address the personal and economic costs associated with this form of insecure ownership

Sticky Flavors

The Fr\'echet mean, a generalization to a metric space of the expectation of a random variable in a vector space, can exhibit unexpected behavior for a wide class of random variables. For instance, it can stick to a point (more generally to a closed set) under resampling: sample stickiness. It can stick to a point for topologically nearby distributions: topological stickiness, such as total variation or Wasserstein stickiness. It can stick to a point for slight but arbitrary perturbations: perturbation stickiness. Here, we explore these and various other flavors of stickiness and their relationship in varying scenarios, for instance on CAT($\kappa$) spaces, $\kappa\in \mathbb{R}$. Interestingly, modulation stickiness (faster asymptotic rate than $\sqrt{n}$) and directional stickiness (a generalization of moment stickiness from the literature) allow for the development of new statistical methods building on an asymptotic fluctuation, where, due to stickiness, the mean itself features no asymptotic fluctuation. Also, we rule out sticky flavors on manifolds in scenarios with curvature bounds

Hybridization gap and anisotropic far-infrared optical conductivity of URu2Si2

We performed far-infrared optical spectroscopy measurements on the heavy fermion compound URu 2 Si 2 as a function of temperature. The light's electric-field was applied along the a-axis or the c-axis of the tetragonal structure. We show that in addition to a pronounced anisotropy, the optical conductivity exhibits for both axis a partial suppression of spectral weight around 12 meV and below 30 K. We attribute these observations to a change in the bandstructure below 30 K. However, since these changes have no noticeable impact on the entropy nor on the DC transport properties, we suggest that this is a crossover phenomenon rather than a thermodynamic phase transition.Comment: To be published in Physical Review

Performance analysis of wireless LANs: an integrated packet/flow level approach

In this paper we present an integrated packet/flow level modelling approach for analysing flow throughputs and transfer times in IEEE 802.11 WLANs. The packet level model captures the statistical characteristics of the transmission of individual packets at the MAC layer, while the flow level model takes into account the system dynamics due to the initiation and completion of data flow transfers. The latter model is a processor sharing type of queueing model reflecting the IEEE 802.11 MAC design principle of distributing the transmission capacity fairly among the active flows. The resulting integrated packet/flow level model is analytically tractable and yields a simple approximation for the throughput and flow transfer time. Extensive simulations show that the approximation is very accurate for a wide range of parameter settings. In addition, the simulation study confirms the attractive property following from our approximation that the expected flow transfer delay is insensitive to the flow size distribution (apart from its mean)

Number Fluctuation in an interacting trapped gas in one and two dimensions

It is well-known that the number fluctuation in the grand canonical ensemble, which is directly proportional to the compressibility, diverges for an ideal bose gas as T -> 0. We show that this divergence is removed when the atoms interact in one dimension through an inverse square two-body interaction. In two dimensions, similar results are obtained using a self-consistent Thomas-Fermi (TF) model for a repulsive zero-range interaction. Both models may be mapped on to a system of non-interacting particles obeying the Haldane-Wu exclusion statistics. We also calculate the number fluctuation from the ground state of the gas in these interacting models, and compare the grand canonical results with those obtained from the canonical ensemble.Comment: 11 pages, 1 appendix, 3 figures. Submitted to J. Phys. B: Atomic, Molecular & Optica

Types of Stickiness in BHV Phylogenetic Tree Spaces and Their Degree

It has been observed that the sample mean of certain probability distributions in Billera-Holmes-Vogtmann (BHV) phylogenetic spaces is confined to a lower-dimensional subspace for large enough sample size. This non-standard behavior has been called stickiness and poses difficulties in statistical applications when comparing samples of sticky distributions. We extend previous results on stickiness to show the equivalence of this sampling behavior to topological conditions in the special case of BHV spaces. Furthermore, we propose to alleviate statistical comparision of sticky distributions by including the directional derivatives of the Fr\'echet function: the degree of stickiness.Comment: 8 Pages, 1 Figure, conference submission to GSI 202

Geographical distribution of selected and putatively neutral SNPs in Southeast Asian malaria parasites.

Loci targeted by directional selection are expected to show elevated geographical population structure relative to neutral loci, and a flurry of recent papers have used this rationale to search for genome regions involved in adaptation. Studies of functional mutations that are known to be under selection are particularly useful for assessing the utility of this approach. Antimalarial drug treatment regimes vary considerably between countries in Southeast Asia selecting for local adaptation at parasite loci underlying resistance. We compared the population structure revealed by 10 nonsynonymous mutations (nonsynonymous single-nucleotide polymorphisms [nsSNPs]) in four loci that are known to be involved in antimalarial drug resistance, with patterns revealed by 10 synonymous mutations (synonymous single-nucleotide polymorphisms [sSNPs]) in housekeeping genes or genes of unknown function in 755 Plasmodium falciparum infections collected from 13 populations in six Southeast Asian countries. Allele frequencies at known nsSNPs underlying resistance varied markedly between locations (F(ST) = 0.18-0.66), with the highest frequencies on the Thailand-Burma border and the lowest frequencies in neighboring Lao PDR. In contrast, we found weak but significant geographic structure (F(ST) = 0-0.14) for 8 of 10 sSNPs. Importantly, all 10 nsSNPs showed significantly higher F(ST) (P < 8 x 10(-5)) than simulated neutral expectations based on observed F(ST) values in the putatively neutral sSNPs. This result was unaffected by the methods used to estimate allele frequencies or the number of populations used in the simulations. Given that dense single-nucleotide polymorphism (SNP) maps and rapid SNP assay methods are now available for P. falciparum, comparing genetic differentiation across the genome may provide a valuable aid to identifying parasite loci underlying local adaptation to drug treatment regimes or other selective forces. However, the high proportion of polymorphic sites that appear to be under balancing selection (or linked to selected sites) in the P. falciparum genome violates the central assumption that selected sites are rare, which complicates identification of outlier loci, and suggests that caution is needed when using this approach