68 research outputs found
Garnet pyroxenite in the Biskupice peridotite, Bohemian Massif: anatomy of a Variscan high-pressure cumulate
An alkaline spring system within the Del Puerto Ophiolite (California, USA): A Mars analog site
Developing atom probe tomography of phyllosilicates in preparation for extra-terrestrial sample return
Hydrous phyllosilicate minerals, including the serpentine subgroup, are likely to be major constituents of material that will be bought back to Earth by missions to Mars and to primitive asteroids Ryugu and Bennu. Small quantities (< 60 g) of micrometre sized, internally heterogeneous material will be available for study, requiring minimally destructive techniques. Many conventional methods are unsuitable for phyllosilicates as they are typically finely crystalline and electron beam sensitive resulting in amorphisation and dehydration. New tools will be required for nanoscale characterisation of these precious extra‐terrestrial samples. Here we test the effectiveness of atom probe tomography (APT) for this purpose. Using lizardite from the Ronda peridotite, Spain, as a terrestrial analogue, we outline an effective analytical protocol to extract nanoscale chemical and structural measurements of phyllosilicates. The potential of APT is demonstrated by the unexpected finding that the Ronda lizardite contains SiO‐rich nanophases, consistent with opaline silica that formed as a by‐product of the serpentinisation of olivine. Our new APT approach unlocks previously unobservable nanominerals and nanostructures within phyllosilicates owing to resolution limitations of more established imaging techniques. APT will provide unique insights into the processes and products of water/rock interaction on Earth, Mars and primitive asteroids
Oxygen and Carbon Isotopic Composition of Precambrian Carbonates from Karnataka and Tamilnadu, India
Oxygen and carbon isotopic compositions for carbonate rocks from the Sargur Group in Karnataka and carbonates from the Madukkarai area in Tamil Nadu am reported. Carbonate rocks from both areas show preservation of sedimentary isotopic compositions. Bettadabidu carbonates have lower isotopic ratios (delta O-18 = 15.8 SMOW ; delta C-13 = - 0.7 PDB) when compared to Madukkarai carbonates (delta O-18 = 20 SMOW; delta C-13 = 2.0 PDB). Oxygen and carbon isotopic values exhibit positive correlation indicating a progressive devolatilization process during regional metamorphism. The range in delta O-18 values demonstrates that large quantities of a homogeneous metamorphic fluid have not pervasively infiltrated either terrane
Stable Isotope Evidence of heterogeneous Fluid Infiltration at the Ubehebe Peak Contact Aureole, Death Valley National Park, California.
Evidence from polymict ureilite meteorites for a disrupted and re-accreted single ureilite parent asteroid gardened by several distinct impactors
Ureilites are ultramafic achondrites that exhibit heterogeneity in mg# and oxygen isotope ratios between different meteorites. Polymict ureilites represent near-surface material of the ureilite parent asteroid(s). Electron microprobe analyses of >500 olivine and pyroxene clasts in several polymict ureilites reveal a statistically identical range of compositions to that shown by unbrecciated ureilites, suggesting derivation from a single parent asteroid. Many ureilitic clasts have identical compositions to the anomalously high Mn/Mg olivines and pyroxenes from the Hughes 009 unbrecciated ureilite (here termed the “Hughes cluster”). Some polymict samples also contain lithic clasts derived from oxidized impactors. The presence of several common distinctive lithologies within polymict ureilites is additional evidence that ureilites were derived from a single parent asteroid.
In situ oxygen three isotope analyses were made on individual ureilite minerals and lithic clasts, using a secondary ion mass spectrometer (SIMS) with precision typically better than 0.2–0.4‰ (2SD) for δ18O and δ17O. Oxygen isotope ratios of ureilitic clasts fall on a narrow trend along the CCAM line, covering the range for unbrecciated ureilites, and show a good anti-correlation with mineral mg#. SIMS analysis identifies one ferroan lithic clast as an R-chondrite, while a second ferroan clast is unlike any known meteorite. An exotic enstatite grain is derived from an enstatite chondrite or aubrite, and another pyroxene grain with Δ17O of −0.4 ± 0.2‰ is unrelated to any known meteorite type.
Ureilitic olivine clasts with mg#s 85 which include the melt-inclusion-bearing “Hughes cluster” ureilites. Thus melt was present in regions of the parent ureilite asteroid with a bulk mg# > 85 when the asteroid was disrupted by impact, giving rise to two types of ureilites: common ferroan ones that were residual after melting and less common magnesian ones that were still partially molten when disruption occurred. One or more daughter asteroids re-accreted from the remnants of the mantle of the proto-ureilite asteroid. Polymict ureilite meteorites represent regolith that subsequently formed on the surface of a daughter asteroid, including impact-derived material from at least six different meteoritic sources
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