1,797 research outputs found

    MANGANESE MINERALISATIONS AT THE BASE OF MIOCENE SEDIMENTS IN NORTHERN SARDINIA (ITALY)

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    During the eastward drift of the Palaeozoic-Mesozoic block formed by Sardinia and Corsica in the Oligocene-Miocene, calc-alkaline volcanism developed mostly in the western part of the island. Most Tertiary metallogenic phoenomena are related to hydrothermal activity associated with this volcanism. Following volcanic and related hydrothermal activity, sediments were deposited during the Oligocene-Miocene as a consequence of a marine transgression. The basal part of this series is clastic and includes elements derived from erosion of unaltered volcanics as well as hydrothermally altered rocks and hydrothermal vein quartz. Inside the Tertiary volcanics manganese ore-minerals occur as nodules, veinlets, and stockworks and mainly include Mn and Fe oxides; quartz in different forms is the most common gangue mineral. The mineralisations at the contact between volcanics and Miocene sediments are the most homogeneous, the ore-minerals occur in the cement, but also as fairly continuous thin beds, nodules and veinlets containing pyrolusite, frequent ramsdellite, less frequent manganite, psilomelane, cryptomelane-manjiroite, rare ranciéite, and todorokite. The nature of the ore-bearing beds indicate a near-shore clastic environment along the ancient coastal lines of the Miocene sea. Genetic considerations point to a supergenic transport and redeposition after erosion of primary dispersion and residual concentrations of Mn in the volcanics

    3D simulation of ammonia combustion in a lean premixed swirl burner

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    To date, a number of mechanical, electrical, thermal, and chemical approaches have been developed for storing electrical energy for utility-scale services. The only sufficiently flexible mechanism allowing large quantities of energy to be stored over long time periods is chemical energy storage in the form of carbon or hydrogen. One chemical considered for hydrogen carriage that can potentially be employed for storage is ammonia. Ammonia can substitute pure hydrogen for storage and be employed for power generation at large industrial scale if the molecule is efficiently burned through mature equipment such as gas turbines, thus providing not only a carbon free fuel, but also a chemical capable of being stored at low energy requirements. Thus, progress on the use of ammonia in gas turbines is a main priority for groups working on the area. Studies need to be conducted in experimental rigs with strong CFD analyses for further industrial implementation. In this paper, modelling of ammonia combustion in a generic gas turbine combustor is explored in order to provide an effective tool for future application. Large Eddy Simulation approach was used to develop a model for ammonia/hydrogen combustion in gas turbine combustors. To capture more details of the turbulent reacting flow, a detailed chemical mechanism was selected for a deep insight. A Partially Stirred Reactor framework was utilized to deal with the turbulence/chemistry interaction. The developed model was then applied to the simulation of lean premixed ammonia/hydrogen flames in a generic swirl burner. A preliminary validation for the model is performed by correlation of NOx emission with experimental data. Results show the model can provide detailed information of flow field, flame structure, emissions, etc. It can be used to optimize the procedure of utilizing ammonia as a fuel in future equipment design

    Data-driven prediction of laminar burning velocity for ternary ammonia/hydrogen/methane/air premixed flames

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    Zero-carbon fuels such as hydrogen and ammonia play a pivotal role in the energy transition by offering cleaner alternatives to natural gas (methane), especially in industrial combustion systems. Binary and ternary blends of these fuels offer a transitionary, low-carbon solution in the near future. Laminar burning velocity (LBV), as a fundamental combustion property, is significantly different for ammonia, hydrogen, and methane. Although the LBV of binary blends of these fuels is well-studied, ternary blends have not been...

    The preburning condition of Chalcolithic cremated human remains from the Perdigoes enclosures (Portugal)

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    The Iberian Chalcolithic displayed a remarkable variety of funerary practices, which has been related to interpopulation differences, intrapopulation social-cultural differences, and complex multistage funerary rituals. Perdigoes, a Chalcolithic set of ditched enclosures, reflects such diversity including a wide array of funerary practices. Among those practices is cremation, which, despite relatively rare, is represented in different structures in Perdigoes. One of these structures (Pit 40) presents an unparalleled high minimum number of individuals (n = 240), contrasting with nearby and coeval structures. In this study, we analyse heat-induced bone changes and other archaeothanatological variables to tentatively assess the preburning condition of the human remains. The results of Pit 40 are also compared with other comparable contexts to assess if this unique context presents further funerary differences relative to those other contexts in, for example, body processing. Our results suggest preferential cremation of fleshed human remains, but burning of at least a minority of skeletonised remains and deposition of possibly unburned remains also likely occurred. Body processing appears to be comparable with that of the cremation contexts of Perdigoes but contrasts with that of another nearby context (Dolmen of Olival da Pega 2b) in which burned bones were also found.Portuguese Foundation for Science and TechnologyPortuguese Foundation for Science and Technology [PEst-OE/SADG/UI0283/2013, POCI-01-0145-FEDER-016766, PTDC/EPH-ARQ/0798/2014, PTDC/IVC-ANT/1201/2014, SFRH/BPD/84268/2012]info:eu-repo/semantics/publishedVersio
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