406 research outputs found
The effect of crystallization conditions on tantalum distribution in molybdenum and tungsten during electron beam zone melting
The distribution of tantalum in molybdenum and tungsten single crystals during electron beam floating zone melting under different crystallization conditions was investigated. The performed line chemical analysis of specimens proved creation of tantalum micro segregation, so-called growth striations, which showed themselves on concentration profiles as periodically alternating areas with increased and decreased concentrations of tantalum. The existence of these chemical inhomogeneities suggests that stationary conditions of the crystal growth were disturbed during the zone melting, i.e. fluctuations of microscopic rate of growth occurred due to convection in the melt. The determined effective distribution coefficients of tantalum in molybdenum and tungsten approach to calculated theoretical values of the equilibrium distribution coefficient
A theoretical study of the structural phases of Group 5B - 6B metals and their transport properties
In order to predict the stable and metastable phases of the bcc metals in the
block of the Periodic Table defined by groups 5B to 6B and periods 4 to 6, as
well as the structure dependence of their transport properties, we have
performed full potential computations of the total energies per unit cell as a
function of the c/a ratio at constant experimental volume. In all cases, a
metastable body centered tetragonal (bct) phase was predicted from the
calculations. The total energy differences between the calculated stable and
metastable phases ranged from 0.09 eV/cell (vanadium) to 0.39 eV/cell
(tungsten). The trends in resistivity as a function of structure and atomic
number are discussed in terms of a model of electron transport in metals.
Theoretical calculations of the electrical resistivity and other transport
properties show that bct phases derived from group 5B elements are more
conductive than the corresponding bcc phases, while bct phases formed from
group 6B elements are less conductive than the corresponding bcc phases.
Special attention is paid to the phases of tantalum where we show that the
frequently observed beta phase is not a simple tetragonal distortion of bcc
tantalum
The soft and the hard pomerons in hadron elastic scattering at small t
We consider simple-pole descriptions of soft elastic scattering for pp, pbar
p, pi+ p, pi- p, K+ p and K- p. We work at t and s small enough for
rescatterings to be neglected, and allow for the presence of a hard pomeron.
After building and discussing an exhaustive dataset, we show that simple poles
provide an excellent description of the data in the region - 0.5 GeV^2 < t <
-0.1 GeV^2, 6 GeV<sqrt(s)< 63 GeV. We show that new form factors have to be
used, and get information on the trajectories of the soft and hard pomerons.Comment: 27 pages, 9 figures, LaTeX. A few typos fixed, and references
correcte
Application of multivariate statistical analysis for delineation of prospective geochemical anomalies in Providenskaya Area (Chukotka, Russia)
The secondary geochemical field structure was modelled on the basis of the lithogeochemical dispersion trains of the Providenskaya Area of the Chukotka Peninsula. The factor and cluster analysis were applied to interpret the nature of geochemical anomalies. It was proved that a range of anomalies were prospective for gold-silver, polymetallic, tin, and tungsten deposit allocation
A Hexanuclear Mixed-Valence Oxovanadium(IV,V) Complex as a Highly Efficient Alkane Oxidation Catalyst
The new hexanuclear mixed-valence vanadium complex [V3O3(OEt)(ashz)(2)(mu-OEt)](2) (1) with an N,O-donor ligand is reported. It acts as a highly efficient catalyst toward alkane oxidations by aqueous H2O2. Remarkably, high turnover numbers up to 25000 with product yields of up to 27% (based on alkane) stand for one of the most active systems for such reactions
Structural and magnetic properties of the (001) and (111) surfaces of the half-metal NiMnSb
Using the full potential linearised augmented planewave method we study the
electronic and magnetic properties of the (001) and (111) surfaces of the
half-metallic Heusler alloy NiMnSb from first-principles. We take into account
all possible surface terminations including relaxations of these surfaces.
Special attention is paid to the spin-polarization at the Fermi level which
governs the spin-injection from such a metal into a semiconductor. In general,
these surfaces lose the half-metallic character of the bulk NiMnSb, but for the
(111) surfaces this loss is more pronounced. Although structural optimization
does not change these features qualitatively, specifically for the (111)
surfaces relaxations can compensate much of the spin-polarization at the Fermi
surface that has been lost upon formation of the surface.Comment: 18 pages, 8 figure
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