Autonomous marine hyperspectral radiometers for determining solar irradiances and aerosol optical properties

We have developed two hyperspectral radiometer systems which require no moving parts, shade rings or motorised tracking, making them ideally suited for autonomous use in the inhospitable remote marine environment. Both systems are able to measure direct and diffuse hyperspectral irradiance in the wavelength range 350–1050 nm at 6 nm (Spectrometer 1) or 3.5 nm (Spectrometer 2) resolution. Marine field trials along a 100� transect (between 50� N and 50� S) of the Atlantic Ocean resulted in close agreement with existing commercially available instruments in measuring (1) photosynthetically available radiation (PAR), with both spectrometers giving regression slopes close to unity (Spectrometer 1: 0.960; Spectrometer 2: 1.006) and R2 �0.96; (2) irradiant energy, with R2�0.98 and a regression slope of 0.75 which can be accounted for by the difference in wavelength integration range; and (3) hyperspectral irradiance where the agreement on average was between 2 and 5 %. Two long duration land-based field campaigns of up to 18 months allowed both spectrometers to be well calibrated. This was also invaluable for empirically correcting for the wider field of view (FOV) of the spectrometers in comparison with the current generation of sun photometers (�7.5� compared with �1�). The need for this correction was also confirmed and independently quantified by atmospheric radiative transfer modelling and found to be a function of aerosol optical depth (AOD) and solar zenith angle. Once Spectrometer 2 was well calibrated and the FOV effect corrected for, the RMSE in retrievals of AOD when compared with a CIMEL sun photometer were reduced to �0.02–0.03 with R2 > 0.95 at wavelengths 440, 500, 670 and 870 nm. Corrections for the FOV as well as ship motion were applied to the data from the marine field trials. This resulted in AOD500 nm ranging between 0.05 in the clear background marine aerosol regions and �0.5 within the Saharan dust plume. The RMSE between the handheld Microtops sun photometer and Spectrometer 2 was between 0.047 and 0.057 with R2 > 0.94

On Certain Kähler Quotients of Quaternionic Kähler Manifolds

We prove that, given a certain isometric action of a two-dimensional Abelian group A on a quaternionic Kähler manifold M which preserves a submanifold N ⊂ M, the quotient M′ =N/A has a natural Kähler structure. We verify that the assumptions on the group action and on the submanifold N ⊂ M are satisfied for a large class of examples obtained from the supergravity c-map. In particular, we find that all quaternionic Kähler manifolds M in the image of the c-map admit an integrable complex structure compatible with the quaternionic structure, such that N ⊂ M is a complex submanifold. Finally, we discuss how the existence of the Kähler structure on M′ is required by the consistency of spontaneous $${\mathcal{N} = 2}$$ to $${\mathcal{N} = 1}$$ supersymmetry breakin

Comment on ``Conduction states in oxide perovskites: Three manifestations of Ti3+^{3 +} Jahn-Teller polarons in barium titanate''

In this comment to [S. Lenjer, O. F. Schirmer, H. Hesse, and Th. W. Kool, Phys. Rev. B {\bf 66}, 165106 (2002)] we discuss the electronic structure of oxygen vacancies in perovskites. First principles computations are in favour of rather deep levels in these vacancies, and Lenjer et al suggest that the electrons' interaction energy is negative, but data on electroconductivity are against.Comment: 2 pages, no figure

Evaluation of the new ESR network software for the retrieval of direct sun products from CIMEL CE318 and PREDE POM01 sun-sky radiometers

The European Skynet Radiometers network (EuroSkyRad or ESR) has been recently established as a research network of European PREDE sun-sky radiometers. Moreover, ESR is federated with SKYNET, an international network of PREDE sun-sky radiometers mostly present in East Asia. In contrast to SKYNET, the European network also integrates users of the CIMEL CE318 sky–sun photometer. Keeping instrumental duality in mind, a set of open source algorithms has been developed consisting of two modules for (1) the retrieval of direct sun products (aerosol optical depth, wavelength exponent and water vapor) from the sun extinction measurements; and (2) the inversion of the sky radiance to derive other aerosol optical properties such as size distribution, single scattering albedo or refractive index. In this study we evaluate the ESR direct sun products in comparison with the AERosol RObotic NETwork (AERONET) products. Specifically, we have applied the ESR algorithm to a CIMEL CE318 and PREDE POM simultaneously for a 4-yr database measured at the Burjassot site (Valencia, Spain), and compared the resultant products with the AERONET direct sun measurements obtained with the same CIMEL CE318 sky–sun photometer. The comparison shows that aerosol optical depth differences are mostly within the nominal uncertainty of 0.003 for a standard calibration instrument, and fall within the nominal AERONET uncertainty of 0.01–0.02 for a field instrument in the spectral range 340 to 1020 nm. In the cases of the Ångström exponent and the columnar water vapor, the differences are lower than 0.02 and 0.15 cm, respectively. Therefore, we present an open source code program that can be used with both CIMEL and PREDE sky radiometers and whose results are equivalent to AERONET and SKYNET retrievals

Unsteady undular bores in fully nonlinear shallow-water theory

We consider unsteady undular bores for a pair of coupled equations of Boussinesq-type which contain the familiar fully nonlinear dissipationless shallow-water dynamics and the leading-order fully nonlinear dispersive terms. This system contains one horizontal space dimension and time and can be systematically derived from the full Euler equations for irrotational flows with a free surface using a standard long-wave asymptotic expansion. In this context the system was first derived by Su and Gardner. It coincides with the one-dimensional flat-bottom reduction of the Green-Naghdi system and, additionally, has recently found a number of fluid dynamics applications other than the present context of shallow-water gravity waves. We then use the Whitham modulation theory for a one-phase periodic travelling wave to obtain an asymptotic analytical description of an undular bore in the Su-Gardner system for a full range of "depth" ratios across the bore. The positions of the leading and trailing edges of the undular bore and the amplitude of the leading solitary wave of the bore are found as functions of this "depth ratio". The formation of a partial undular bore with a rapidly-varying finite-amplitude trailing wave front is predicted for ``depth ratios'' across the bore exceeding 1.43. The analytical results from the modulation theory are shown to be in excellent agreement with full numerical solutions for the development of an undular bore in the Su-Gardner system.Comment: Revised version accepted for publication in Phys. Fluids, 51 pages, 9 figure

Surface potential at a ferroelectric grain due to asymmetric screening of depolarization fields

Nonlinear screening of electric depolarization fields, generated by a stripe domain structure in a ferroelectric grain of a polycrystalline material, is studied within a semiconductor model of ferroelectrics. It is shown that the maximum strength of local depolarization fields is rather determined by the electronic band gap than by the spontaneous polarization magnitude. Furthermore, field screening due to electronic band bending and due to presence of intrinsic defects leads to asymmetric space charge regions near the grain boundary, which produce an effective dipole layer at the surface of the grain. This results in the formation of a potential difference between the grain surface and its interior of the order of 1 V, which can be of either sign depending on defect transition levels and concentrations. Exemplary acceptor doping of BaTiO3 is shown to allow tuning of the said surface potential in the region between 0.1 and 1.3 V.Comment: 14 pages, 11 figures, submitted to J. Appl. Phy

Magnetic properties of submicron Co islands and their use as artificial pinning centers

We report on the magnetic properties of elongated submicron magnetic islands and their influence on a superconducting film. The magnetic properties were studied by magnetization hysteresis loop measurements and scanning-force microscopy. In the as-grown state, the islands have a magnetic structure consisting of two antiparallel domains. This stable domain configuration has been directly visualized as a 2x2-checkerboard pattern by magnetic-force microscopy. In the remanent state, after magnetic saturation along the easy axis, all islands have a single-domain structure with the magnetic moment oriented along the magnetizing field direction. Periodic lattices of these Co islands act as efficient artificial pinning arrays for the flux lines in a superconducting Pb film deposited on top of the Co islands. The influence of the magnetic state of the dots on their pinning efficiency is investigated in these films, before and after the Co dots are magnetized.Comment: 6 pages including figure

Sustaining the Visitor Economy and Environment in the Isles of Scilly

This is the final version.This report summarises the key findings of a short project that took place from January to March 2021. The project examined ways to foster positive synergies between the visitor economy and the natural environment, and to generate additional support for protecting and restoring nature in the Isles of Scilly. The project identified the following ideas as worthy of further development: – A Scilly Pledge to raise awareness and appreciation of Scilly’s environment and culture, encouraging responsible behaviours. – A baseline assessment and monitoring programme to understand the changing ‘State of Nature’ in Scilly. – Raising charitable donations from visitors to help maintain Scilly’s natural environment including promotion of the Friends of Scilly Wildlife Scheme.UKRI Strategic Priorities Fund