946 research outputs found
Direct diffusion through interpenetrating networks: Oxygen in titanium
How impurity atoms move through a crystal is a fundamental and recurrent
question in materials. The previous understanding of oxygen diffusion in
titanium relied on interstitial lattice sites that were recently found to be
unstable, making the diffusion pathways for oxygen unknown. Using
first-principles quantum-mechanical methods, we find three oxygen interstitial
sites in titanium, and quantify the multiple interpenetrating networks for
oxygen diffusion. Surprisingly, no single transition dominates, but all
contribute to diffusion.Comment: 10 pages, 3 figures; additional supporting materia
Review: Sublethal effects of temperature on freshwater organisms, with special reference to aquatic insects
Water temperature is a key variable affecting aquatic organisms. Understanding their response to elevated water temperatures is important for estimating upper thermal limits, and ultimately for assisting with setting defendable, biologically-relevant water temperature guidelines for lotic systems. Sublethal effects impacting on an individual organism or species may manifest at higher levels of the hierarchy, namely, populations, communities and entire ecosystems. Sublethal effects typically include those affecting an organism’s physiology and metabolism (e.g. growth rates, secondary productivity, respiration); phenology (e.g. development time, voltinism, emergence); reproductive success and fitness (e.g. fecundity, rates and success of egg development and hatching); behaviour (e.g. migration, movement, drift); and broad-scale ecological effects (e.g. species richness, composition, density, distribution patterns). Sublethal effects are discussed with examples drawn from freshwater studies, in particular those focused on aquatic insects. Commonly-used methods, which vary from simple, cost-effective, laboratory-based methods to more elaborate, expensive, laboratory- and field-based studies, are assimilated to serve as a toolbox for future thermal research. Ultimately, the method adopted depends largely on the question(s) being asked and available resources.Keywords: biotic responses, experimental, riverine ecosystems, thermal research, toleranc
Nutritional intervention and impact of polyphenol on glycohaemoglobin (HbA1c) in non-diabetic and type 2 diabetic subjects: systematic review and meta-analysis
Polyphenols have been extensively studied for their antioxidant and anti-inflammatory properties. Recently, their antiglycative actions by oxidative stress modulation have been linked to prevention of diabetes and associated complications. This paper assesses the evidence for polyphenol interventions on glycohaemoglobin (HbA1c) in non-diabetic, pre-diabetic and type 2 diabetes mellitus (T2DM) subjects. A systematic review of polyphenols clinical trials on HbA1c in humans was performed according to the Preferred Reporting Items for Systematic Review and Meta-Analysis. Thirty-six controlled randomized trials with HbA1c values were included. Polyphenols (extracts, supplements, foods), were supplemented (28 mg to 1.5g) for 0.7 to 12 months. Combining all subjects (n=1954, mean baseline HbA1c=7.03%, 53 mmol/mol), polyphenol supplementation significantly (p<0.001) lowered HbA1c% by -0.53±0.12 units (-5.79±0.13 mmol/mol). This reduction was significant (p<0.001) in T2DM subjects, specifically (n=1426, mean baseline HbA1c=7.44%, 58 mmol/mol), with HbA1c% lowered by -0.21±0.04 units (-2.29±0.4 mmol/mol). Polyphenol supplementation had no significant effect (p>0.21) in the non-diabetic (n=258, mean baseline HbA1c=5.47%, 36 mmol/mol) and the pre-diabetic subjects (n=270, mean baseline HbA1c=6.06%, 43 mmol/mol) strata: -0.39±0.27 HbA1c% units (-4.3±0.3 mmol/mol), and -0.38±0.31 units (-4.2±0.31 mmol/mol), respectively. In conclusion, polyphenols can successfully reduce HbA1c in T2DM, without any intervention at glycaemia, and could contribute to the prevention of diabetes complications
Correlations between the HMH plus, minus and combined accommodative rock tests
Correlations between the HMH plus, minus and combined accommodative rock test
Correlations between the HMH Plus, Minus, and Combined accommodative rock tests
Correlations between the HMH Plus, Minus, and Combined accommodative rock test
Fullerol ionic fluids
http://pubs.rsc.org/en/Content/ArticlePDF/2010/NR/C0NR00307G/2010-06-08?page=SearchWe report for the first time an ionic fluid based on hydroxylated fullerenes (fullerols). The ionic fluid was synthesized by neutralizing the fully protonated fullerol with an amine terminated polyethylene/polypropylene oxide oligomer (Jeffamine(R)). The ionic fluid was compared to a control synthesized by mixing the parially protonated from (sodium form) of hte fullerols with the same oligomeric amine in the same ratio as in the ionic fluids (20 wt% fullerol). In the fullerol fluid the ionic bonding significantly perturbs the thermal transitions and melting/crystallization behavior of the amine. In contrast, both the normalized heat of fusion and crystallization of the amine in the control are similar to those of the neat amine consistent with a physical mixture of the fullerols/amine with minimal interactions. In addition to differences in thermal behavior, the fullerol ionic fluid exhibits a complex viscoelastic behavior intermediate between the neat Jeffamine (R) (liquid-like) and the control (solid-like).This publication is based on work supported in part by Award No. KUS-C1-018-02 made by King Abdullah University of Science and Technology (KAUST)
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