High quality anti-relaxation coating material for alkali atom vapor cells

We present an experimental investigation of alkali atom vapor cells coated with a high quality anti-relaxation coating material based on alkenes. The prepared cells with single compound alkene based coating showed the longest spin relaxation times which have been measured up to now with room temperature vapor cells. Suggestions are made that chemical binding of a cesium atom and an alkene molecule by attack to the C=C bond plays a crucial role in such improvement of anti-relaxation coating quality

Quantum noise limited and entanglement-assisted magnetometry

We study experimentally the fundamental limits of sensitivity of an atomic radio-frequency magnetometer. First we apply an optimal sequence of state preparation, evolution, and the back-action evading measurement to achieve a nearly projection noise limited sensitivity. We furthermore experimentally demonstrate that Einstein-Podolsky-Rosen (EPR) entanglement of atoms generated by a measurement enhances the sensitivity to pulsed magnetic fields. We demonstrate this quantum limited sensing in a magnetometer utilizing a truly macroscopic ensemble of 1.5*10^12 atoms which allows us to achieve sub-femtoTesla/sqrt(Hz) sensitivity.Comment: To appear in Physical Review Letters, April 9 issue (provisionally

Raman and nuclear magnetic resonance investigation of alkali metal vapor interaction with alkene-based anti-relaxation coating

The use of anti-relaxation coatings in alkali vapor cells yields substantial performance improvements by reducing the probability of spin relaxation in wall collisions by several orders of magnitude. Some of the most effective anti-relaxation coating materials are alpha-olefins, which (as in the case of more traditional paraffin coatings) must undergo a curing period after cell manufacturing in order to achieve the desired behavior. Until now, however, it has been unclear what physicochemical processes occur during cell curing, and how they may affect relevant cell properties. We present the results of nondestructive Raman-spectroscopy and magnetic-resonance investigations of the influence of alkali metal vapor (Cs or K) on an alpha-olefin, 1-nonadecene coating the inner surface of a glass cell. It was found that during the curing process, the alkali metal catalyzes migration of the carbon-carbon double bond, yielding a mixture of cis- and trans-2-nonadecene.Comment: 5 pages, 6 figure

Relaxation of atomic polarization in paraffin-coated cesium vapor cells

The relaxation of atomic polarization in buffer-gas-free, paraffin-coated cesium vapor cells is studied using a variation on Franzen's technique of ``relaxation in the dark'' [Franzen, Phys. Rev. {\bf 115}, 850 (1959)]. In the present experiment, narrow-band, circularly polarized pump light, resonant with the Cs D2 transition, orients atoms along a longitudinal magnetic field, and time-dependent optical rotation of linearly polarized probe light is measured to determine the relaxation rates of the atomic orientation of a particular hyperfine level. The change in relaxation rates during light-induced atomic desorption (LIAD) is studied. No significant change in the spin relaxation rate during LIAD is found beyond that expected from the faster rate of spin-exchange collisions due to the increase in Cs density.Comment: 14 pages, 14 figure

Electric-field-induced change of alkali-metal vapor density in paraffin-coated cells

Alkali vapor cells with antirelaxation coating (especially paraffin-coated cells) have been a central tool in optical pumping and atomic spectroscopy experiments for 50 years. We have discovered a dramatic change of the alkali vapor density in a paraffin-coated cell upon application of an electric field to the cell. A systematic experimental characterization of the phenomenon is carried out for electric fields ranging in strength from 0-8 kV/cm for paraffin-coated cells containing rubidium and cells containing cesium. The typical response of the vapor density to a rapid (duration < 100 ms) change in electric field of sufficient magnitude includes (a) a rapid (duration of < 100 ms) and significant increase in alkali vapor density followed by (b) a less rapid (duration of ~ 1 s) and significant decrease in vapor density (below the equilibrium vapor density), and then (c) a slow (duration of ~ 100 s) recovery of the vapor density to its equilibrium value. Measurements conducted after the alkali vapor density has returned to its equilibrium value indicate minimal change (at the level of < 10%) in the relaxation rate of atomic polarization. Experiments suggest that the phenomenon is related to an electric-field-induced modification of the paraffin coating.Comment: 15 pages, 15 figure

Rubidium "whiskers" in a vapor cell

Crystals of metallic rubidium are observed ``growing'' from paraffin coating of buffer-gas-free glass vapor cells. The crystals have uniform square cross-section, $\approx 30 \mu$m on the side, and reach several mm in length.Comment: 2 pages, 1 figur

Detection of low-conductivity objects using eddy current measurements with an optical magnetometer

Detection and imaging of an electrically conductive object at a distance can be achieved by inducing eddy currents in it and measuring the associated magnetic field. We have detected low-conductivity objects with an optical magnetometer based on room-temperature cesium atomic vapor and a noise-canceling differential technique which increased the signal-to-noise ratio (SNR) by more than three orders of magnitude. We detected small containers with a few mL of salt-water with conductivity ranging from 4-24 S/m with a good SNR. This demonstrates that our optical magnetometer should be capable of detecting objects with conductivity 1 and opens up new avenues for using optical magnetometers to image low-conductivity biological tissue including the human heart which would enable non-invasive diagnostics of heart diseases.Comment: Main article with supplemental materia

Controlling atomic vapor density in paraffin-coated cells using light-induced atomic desorption

Atomic-vapor density change due to light induced atomic desorption (LIAD) is studied in paraffin-coated rubidium, cesium, sodium and potassium cells. In the present experiment, low-intensity probe light is used to obtain an absorption spectrum and measure the vapor density, while light from an argon-ion laser, array of light emitting diodes, or discharge lamp is used for desorption. Potassium is found to exhibit significantly weaker LIAD from paraffin compared to Rb and Cs, and we were unable to observe LIAD with sodium. A simple LIAD model is applied to describe the observed vapor-density dynamics, and the role of the cell's stem is explored through the use of cells with lockable stems. Stabilization of Cs vapor density above its equilibrium value over 25 minutes is demonstrated. The results of this work could be used to assess the use of LIAD for vapor-density control in magnetometers, clocks, and gyroscopes utilizing coated cells.Comment: 10 pages, 11 figure