492 research outputs found
EXPERIMENTAL INVESTIGATION OF THE TRANSIENT CHARACTERISTICS AND MECHANICAL LOSSES IN Ni-Mn-Ga ALLOYS
The reported study was funded by RFBR, project number 20-32-90195
OBTAINING INTERMETALLIC COMPOUNDS IN Al–Ti–Zn SYSTEM
Binary intermetallic compounds – titanium aluminides (TiAl, Ti3Al) – when added to the alloys, significantly increase their strength and special properties. The most promising direction to produce intermetallic compounds are mechanochemical technologies, including mechanical alloy building. Mechanical alloying makes it possible to introduce much smaller particles into the metal matrix than can be achieved using standard powder metallurgy technologies. In addition to mechanical synthesis, aluminum-based intermetallic compounds were produced by self-propagating high-temperature synthesis (SHS) of solid chemical compounds. The synthesis was carried out according to a multistage scheme: preparation of titanium and aluminum powder, mixing; synthesis of the Al3Ti intermetallic compound by the SHS method in vacuum followed by mechanical activation of stoichiometric charges. The aim of the research was to study the dynamics of the development of nanodispersed phases in the process of synthesis during mechanical alloying. The power absorbed by the unit mass of the material for different processing times of the charge was calculated. When the level of the specific power (dose) of mechanical treatment was 3.5 kJ/g, the maximum content of intermetallic compound in the resulting material was achieved. Based on calculations and the data obtained during X-ray phase analysis, the dependence of the change in the content of ternary intermetallic compounds in the final product on the absorbed power was determined. As a result of the studies using raster electron microscopy and X-ray analysis, it was found that mechanical alloying of nanostructured intermetallic compounds Ti4ZnAl11 and Ti25Zn9Al66 with the size of nanodisperse phases less than 12 nm in the Al–Ti–Zn system, the weight ratio of proportion of the latter reaches 74 %
Optical spectra, crystal-field parameters, and magnetic susceptibility of the new multiferroic NdFe3(BO3)4
We report high-resolution optical absorption spectra for NdFe3(BO3)4 trigonal
single crystal which is known to exhibit a giant magnetoelectric effect below
the temperature of magnetic ordering TN = 33 K. The analysis of the
temperature-dependent polarized spectra reveals the energies and, in some
cases, symmetries and exchange splittings of Nd3+ 84 Kramers doublets. We
perform crystal-field calculations starting from the exchange-charge model,
obtain a set of six real crystal-field parameters, and calculate wave functions
and magnetic g-factors. In particular, the values g(perpendicular) = 2.385,
g(parallel) = 1.376 were found for the Nd3+ ground-state doublet. We obtain
Bloc=7.88 T and |JFN|= 0.48 K for the values of the local effective magnetic
field at liquid helium temperatures at the Nd3+ site and the Nd - Fe exchange
integral, respectively, using the experimentally measured Nd3+ ground-state
splitting of 8.8 cm-1. To check reliability of our set of crystal field
parameters we model the magnetic susceptibility data from literature. A dimer
containing two nearest-neighbor iron ions in the spiral chain is considered to
partly account for quasi-one-dimensional properties of iron borates, and then
the mean-field approximation is used. The results of calculations with the
exchange parameters for Fe3+ ions Jnn = -6.25 K (intra-chain interactions) and
Jnnn = -1.92 K (inter-chain interactions) obtained from fitting agree well with
the experimental data.Comment: 13 pages, 8 figures, 2 table
Positive Magneto-Resistance in Quasi-1D Conductors
We present here a simple qualitative model that interpolates between the high
and low temperature properties of quasi-1D conductors. At high temperatures we
argue that transport is governed by inelastic scattering whereas at low
temperatures the conductance decays exponentially with the electron dephasing
length. The crossover between these regimes occurs at the temperature at which
the elastic and inelastic scattering times become equal. This model is shown to
be in quantitative agreement with the organic conductor .
Within this model, we also show that on the insulating side, the positive
magnetoresistance of the form observed in and
other quasi-1D conductors can be explained by the role spin-flip scattering
plays in the electron dephasing rate.Comment: 4 pages, Latex, no figure
Negative magneto-resistance of electron gas in a quantum well with parabolic potential
We have studied the electrical conductivity of the electron gas in parallel
electric and magnetic fields directed along the plane of a parabolic quantum
well (across the profile of the potential). We found a general expression for
the electrical conductivity applicable for any magnitudes of the magnetic field
and the degree of degeneration of the electron gas. A new mechanism of
generation of the negative magnetoresistance has been revealed. It has been
shown that in a parabolic quantum well with a non-degenerated electron gas the
negative magnetoresistance results from spin splitting of the levels of the
size quantization.Comment: 15 pages, 3 figure
Outcome of bilateral periprosthetic hip infection management
Introduction Infection is a devastating complication after joint arthroplasty. In most cases of purulent infection, surgeons are forced to perform revision of the artificial joint. This is caused by the ability of microorganisms to adhere on the implant surface. Periprosthetic infection is a heavy burden both for patients due to a significant level of the disease recurrence and for medical institutions because of high medical treatment costs. Methods The analysis of the treatment outcome in a female patient with bilateral periprosthetic hip infection was conducted. One- and two-stage revisions were performed. Results The treatment measures stopped the purulent inflammatory process (according to Delphi) and restored the functional state of both hip joints (HHS of 79 points on the left and 93 points on the right side). Discussion Treatment of periprosthetic infection is a complex clinical task, which requires a personalized and comprehensive approach that includes implementation of the basic principles of diagnosis and treatment of the disease, understanding of this pathology, and teamwork. One- and two-stage revisions provide a successful arrest of periprosthetic infection and functional restoration of the affected joint
Nanocrystalline lanthanide-doped Lu3Ga5O12 garnets: interesting materials for light-emitting devices
Nanocrystalline Lu3Ga5O12, with average particle sizes of 40 nm, doped with a wide variety of luminescent trivalent lanthanide ions have been prepared using a sol\u2013gel technique. The structural and morphological properties of the powders have been investigated by x-ray powder diffraction, high resolution transmission electron microscopy and Raman spectroscopy. Structural data have been refined and are presented for Pr3+, Eu3+, Gd3+, Ho3+, Er3+ and Tm3+ dopants, while room temperature excited luminescence spectra and emission decay curves of Eu3+-, Tm3+- and Ho3+-doped Lu3Ga5O12 nanocrystals have been measured and are discussed.
The Eu3+ emission spectrum shows typical bands due to 5D0 \u21927FJ (J = 0, 1, 2, 3, 4) transitions and the broadening of these emission bands with the non-exponential behaviour of the decay curves indicates the presence of structural disorder around the lanthanide ions.
Lanthanide-doped nanocrystalline Lu3Ga5O12 materials show better luminescence intensities compared to Y2O3, Gd3Ga5O12 and Y3Al5O12 nanocrystalline hosts. Moreover, the upconversion emission intensity in the blue-green region for the Tm3+- and Ho3+-doped samples shows a significant increase upon 647.5 nm excitation with respect to other common oxide hosts doped with the same lanthanide ions
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