The Origin of the Boson Peak and the Thermal Conductivity Plateau in Low Temperature Glasses

We argue that the intrinsic glassy degrees of freedom in amorphous solids giving rise to the thermal conductivity plateau and the ``boson peak'' in the heat capacity at moderately low temperatures are directly connected to those motions giving rise to the two-level like excitations seen at still lower temperatures. These degrees of freedom can be thought of as strongly anharmonic transitions between the local minima of the glassy energy landscape that are accompanied by ripplon-like domain wall motions of the glassy mosaic structure predicted to occur at $T_g$ by the random first order transition theory. The energy spectrum of the vibrations of the mosaic depends on the glass transition temperature, the Debye frequency and the molecular length scale. The resulting spectrum reproduces the experimental low temperature Boson peak. The ``non-universality'' of the thermal conductivity plateau depends on $k_B T_g/\hbar \omega_D$ and arises from calculable interactions with the phonons.Comment: 4 pages, submitted to PR

Large deviations for local times and intersection local times of fractional Brownian motions and Riemann-Liouville processes

In this paper we prove exact forms of large deviations for local times and intersection local times of fractional Brownian motions and Riemann-Liouville processes. We also show that a fractional Brownian motion and the related Riemann-Liouville process behave like constant multiples of each other with regard to large deviations for their local and intersection local times. As a consequence of our large deviation estimates, we derive laws of iterated logarithm for the corresponding local times. The key points of our methods: (1) logarithmic superadditivity of a normalized sequence of moments of exponentially randomized local time of a fractional Brownian motion; (2) logarithmic subadditivity of a normalized sequence of moments of exponentially randomized intersection local time of Riemann-Liouville processes; (3) comparison of local and intersection local times based on embedding of a part of a fractional Brownian motion into the reproducing kernel Hilbert space of the Riemann-Liouville process.Comment: To appear in the Annals of Probabilit

High Thermoelectric Performance and Defect Energetics of Multipocketed Full Heusler Compounds

We report a first-principles density-functional study of electron-phonon interactions in and thermoelectric transport properties of the full Heusler compounds Sr2BiAu and Sr2SbAu. Our results show that ultrahigh intrinsic bulk thermoelectric performance across a wide range of temperatures is physically possible and point to the presence of multiply degenerate and highly dispersive carrier pockets as the key factor for achieving this. Sr2BiAu, which features ten energy-aligned low-effective-mass pockets (six along Γ-X and four at L), is predicted to deliver n-type zT=0.4-4.9 at T=100-700 K. Comparison with the previously investigated compound Ba2BiAu shows that the additional L pockets in Sr2BiAu significantly increase its low-temperature power factor to a maximum value of 12 mW m-1 K-2 near T=300 K. However, at high temperatures the power factor of Sr2BiAu drops below that of Ba2BiAu because the L states are heavier and subject to strong scattering by phonon deformation, as opposed to the lighter Γ-X states, which are limited by polar-optical scattering. Sr2SbAu is predicted to deliver a lower n-type zT=3.4 at T=750 K due to appreciable misalignment between the L and Γ-X carrier pockets, generally heavier scattering, and a slightly higher lattice thermal conductivity. Soft acoustic modes, which are responsible for the low lattice thermal conductivity, also increase the vibrational entropy and high-temperature stability of these Heusler compounds, suggesting that their experimental synthesis may be feasible. The dominant intrinsic defects are found to be Au vacancies, which drive the Fermi level towards the conduction band and work in favor of n-doping

High-quality positrons from a multi-proton bunch driven hollow plasma wakefield accelerator

By means of hollow plasma, multiple proton bunches work well in driving nonlinear plasma wakefields and accelerate electrons to energy frontier with preserved beam quality. However, the acceleration of positrons is different because the accelerating structure is strongly charge dependent. There is a discrepancy between keeping a small normalized emittance and a small energy spread. This results from the conflict that the plasma electrons used to provide focusing to the multiple proton bunches dilute the positron bunch. By loading an extra electron bunch to repel the plasma electrons and meanwhile reducing the plasma density slightly to shift the accelerating phase with a conducive slope to the positron bunch, the positron bunch can be accelerate to 400 GeV (40% of the driver energy) with an energy spread as low as 1% and well preserved normalized emittance. The successful generation of high quality and high energy positrons paves the way to the future energy frontier lepton colliders.Comment: 14 pages, 5 figure

Observation of the Presuperfluid Regime in a Two-Dimensional Bose Gas

In complementary images of coordinate-space and momentum-space density in a trapped 2D Bose gas, we observe the emergence of pre-superfluid behavior. As phase-space density $\rho$ increases toward degenerate values, we observe a gradual divergence of the compressibility $\kappa$ from the value predicted by a bare-atom model, $\kappa_{ba}$. $\kappa/\kappa_{ba}$ grows to 1.7 before $\rho$ reaches the value for which we observe the sudden emergence of a spike at $p=0$ in momentum space. Momentum-space images are acquired by means of a 2D focusing technique. Our data represent the first observation of non-meanfield physics in the pre-superfluid but degenerate 2D Bose gas.Comment: Replace with the version appeared in PR

Characterization of the Soluble Nanoparticles Formed through Coulombic Interaction of Bovine Serum Albumin with Anionic Graft Copolymers at Low pH

A static light scattering (SLS) study of bovine serum albumin (BSA) mixtures with two anionic graft copolymers of poly (sodium acrylate-co-sodium 2-acrylamido-2-methyl-1-propanesulphonate)-graft-poly (N, N-dimethylacrylamide), with a high composition in poly (N, N-dimethylacrylamide) (PDMAM) side chains, revealed the formation of oppositely charged complexes, at pH lower than 4.9, the isoelectric point of BSA. The core-corona nanoparticles formed at pH = 3.00, were characterized. Their molecular weight and radius of gyration were determined by SLS, while their hydrodynamic radius was determined by dynamic light scattering. Small angle neutron scattering measurements were used to determine the radius of the insoluble complexes, comprising the core of the particles. The values obtained indicated that their size and aggregation number of the nanoparticles, were smaller when the content of the graft copolymers in neutral PDMAM side chains was higher. Such particles should be interesting drug delivery candidates, if the gastrointestinal tract was to be used