2,389 research outputs found
Reactivity of organism in prolonged space flights
An analysis of published data are presented as well as the results of experiments which show that the state of weightlessness and hypodynamia result in a reduced orthostatic and vestibular resistance, increased sensitivity to infections, decreased endurance of accelerations and physical exercises, and altered reactivity of the organism to drugs. Various consequences of weightlessness on the human body, especially weightlessness combined with other factors linked to long space flights are also considered
Molecular Structures of the Metastable Charge-Transfer Complexes of Benzene (and Toluene) With Bromine as the Pre-Reactive Intermediates in Electrophilic Aromatic Bromination
Successful crystallization and X-ray crystallographic analyses of the highly metastable (1∶1) complexes of bromine with benzene and toluene establish the unique (localized) structure B that differs in notable ways from the long-accepted (delocalized) structure A. Furthermore, we demonstrate the (highly structured) charge-transfer complexes [C6H6,Br2] and [CH3C6H5,Br2] to be the pre-reactive intermediates that are converted (via an overall Br+ transfer) to the Wheland intermediates in electrophilic aromatic bromination. The role of the dative ion pairs [C6H6˙+ Br2˙−] and [CH3C6H5˙+ Br2˙−] in the rate-limiting activation processes is underscored
Noncovalent Binding of the Halogens to Aromatic Donors. Discrete Structures of Labile Br\u3csub\u3e2\u3c/sub\u3e Complexes with Benzene and Toluene
Precise molecular structures resulting from the noncovalent interaction of Br2 with benzene (and toluene) reveal the unusual localized bonding to specific (one or two) carbon centers in prereactive complexes leading directly to the transition states for electrophilic aromatic brominations
Pseudo-differential equations and conical potentials: 2-dimensional case
We consider two-dimensional elliptic pseudo-differential equation in a plane secto
Current-mediated synchronization of a pair of beating non-identical flagella
The basic phenomenology of experimentally observed synchronization (i.e., a
stochastic phase locking) of identical, beating flagella of a biflagellate alga
is known to be captured well by a minimal model describing the dynamics of
coupled, limit-cycle, noisy oscillators (known as the noisy Kuramoto model). As
demonstrated experimentally, the amplitudes of the noise terms therein, which
stem from fluctuations of the rotary motors, depend on the flagella length.
Here we address the conceptually important question which kind of synchrony
occurs if the two flagella have different lengths such that the noises acting
on each of them have different amplitudes. On the basis of a minimal model,
too, we show that a different kind of synchrony emerges, and here it is
mediated by a current carrying, steady-state; it manifests itself via
correlated "drifts" of phases. We quantify such a synchronization mechanism in
terms of appropriate order parameters and - for an ensemble of
trajectories and for a single realization of noises of duration ,
respectively. Via numerical simulations we show that both approaches become
identical for long observation times . This reveals an ergodic
behavior and implies that a single-realization order parameter is
suitable for experimental analysis for which ensemble averaging is not always
possible.Comment: 10 pages, 2 figure
- …