8,638 research outputs found

    Research study of droplet sizing technology leading to the development of an advanced droplet sizing system

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    An instrument to measure the size and velocity of droplets was developed. The instrument uses one of two techniques, as appropriate. In the first technique two small laser beams of one color identify the center of a larger laser beam of a different color. This defines a region of almost uniform intensity where the light scattered by the individual droplets can be related to their size. The first technique uses the visibility of a Doppler burst and validates it against the peak intensity of the signal's pedestal. Results are presented for monodisperse, bimodal, trimodal, and polydisperse sprays produced by the Berglund-Liu droplet generator and a pressure nozzle. Size distributions of a given spray obtained using three different size ranges show excellent self-consistency in the overlapping region. Measurements of sprays of known characteristics exhibit errors in the order of 10%. The principles of operation and design criteria of the instrument are discussed in great detail

    Li-Ion Cells Employing Electrolytes With Methyl Propionate and Ethyl Butyrate Co-Solvents

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    Future NASA missions aimed at exploring Mars and the outer planets require rechargeable batteries that can operate at low temperatures to satisfy the requirements of such applications as landers, rovers, and penetrators. A number of terrestrial applications, such as hybrid electric vehicles (HEVs) and electric vehicles (EVs) also require energy storage devices that can operate over a wide temperature range (i.e., -40 to +70 C), while still providing high power capability and long life. Currently, the state-of-the-art lithium-ion system has been demonstrated to operate over a wide range of temperatures (-30 to +40 C); however, the rate capability at the lower temperatures is very poor. These limitations at very low temperatures are due to poor electrolyte conductivity, poor lithium intercalation kinetics over the electrode surface layers, and poor ionic diffusion in the electrode bulk. Two wide-operating-temperature-range electrolytes have been developed based on advances involving lithium hexafluorophosphate-based solutions in carbonate and carbonate + ester solvent blends, which have been further optimized in the context of the technology and targeted applications. The approaches employed include further optimization of electrolytes containing methyl propionate (MP) and ethyl butyrate (EB), which are effective co-solvents, to widen the operating temperature range beyond the baseline systems. Attention was focused on further optimizing ester-based electrolyte formulations that have exhibited the best performance at temperatures ranging from -60 to +60 C, with an emphasis upon improving the rate capability at -20 to -40 C. This was accomplished by increasing electrolyte salt concentration to 1.20M and increasing the ester content to 60 percent by volume to increase the ionic conductivity at low temperatures. Two JPL-developed electrolytes 1.20M LiPF6 in EC+EMC+MP (20:20:60 v/v %) and 1.20M LiPF6 in EC+EMC+EB (20:20:60 v/v %) operate effectively over a wide temperature range in MCMB-LiNiCoAlO2 and Li4Ti5O12-LiNi-CoAlO2 prototype cells. These electrolytes have enabled high rate performance at low temperature (i.e., up to 2.0C rates at -50 C and 5.0C rates at -40 C), and good cycling performance over a wide temperature range (i.e., from -40 to +70 C). Current efforts are focused upon improving the high temperature resilience of the methyl propionatebased system through the use of electrolyte additives, which are envisioned to improve the nature of the solid electrolyte interphase (SEI) layers

    Improved Wide Operating Temperature Range of Li-Ion Cells

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    Future NASA missions aimed at exploring the Moon, Mars, and the outer planets require rechargeable batteries that can operate over a wide temperature range (-60 to +60 C) to satisfy the requirements of various applications including landers, rovers, penetrators, CEV, CLV, etc. This work addresses the need for robust rechargeable batteries that can operate well over a wide temperature range. The Department of Energy (DoE) has identified a number of technical barriers associated with the development of Liion rechargeable batteries for PHEVs. For this reason, DoE has interest in the development of advanced electrolytes that will improve performance over a wide range of temperatures, and lead to long life characteristics (5,000 cycles over a 10-year life span). There is also interest in improving the high-voltage stability of these candidate electrolyte systems to enable the operation of up to 5 V with high specific energy cathode materials. Currently, the state-of-the-art lithium-ion system has been demonstrated to operate over a wide range of temperatures (-40 to +40 C); however, the rate capability at the lower temperatures is very poor. In addition, the low-temperature performance typically deteriorates rapidly upon being exposed to high temperatures. A number of electrolyte formulations were developed that incorporate the use of electrolyte additives to improve the high-temperature resilience, low-temperature power capability, and life characteristics of methyl propionate (MP)-based electrolyte solutions. These electrolyte additives include mono-fluoroethylene carbonate (FEC), lithium oxalate, vinylene carbonate (VC), and lithium bis(oxalate borate) (LiBOB), which have previously been shown to result in improved high-temperature resilience of all carbonate-based electrolytes. These MP-based electrolytes with additives have been shown to have improved performance in experiments with MCMB-LiNiCoAlO2 cells

    Dynamic light scattering homodyne probe

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    An optical probe for analyzing a sample illuminated by a laser includes an input optical fiber operably connectable to the laser where the input optical fiber has an entrance end and an exit end. The probe also includes a first beam splitter where the first beam splitter is adapted to transmit an alignment portion of a light beam from the input fiber exit end and to reflect a homodyning portion of the light beam from the input fiber. The probe also includes a lens between the input fiber exit end and the first beam splitter and a first and a second output optical fiber, each having an entrance end and an exit end, each exit end being operably connectable to respective optical detectors. The probe also includes a second beam splitter which is adapted to reflect at least a portion of the reflected homodyning portion into the output fiber entrance ends and to transmit light from the laser scattered by the sample into the entrance ends

    GLE and Sub-GLE Redefinition in the Light of High-Altitude Polar Neutron Monitors

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    The conventional definition of ground-level enhancement (GLE) events requires a detection of solar energetic particles (SEP) by at least two differently located neutron monitors. Some places are exceptionally well suitable for ground-based detection of SEP - high-elevation polar regions with negligible geomagnetic and reduced atmospheric energy/rigidity cutoffs. At present, there are two neutron-monitor stations in such locations on the Antarctic plateau: SOPO/SOPB (at Amundsen-Scott station, 2835 m elevation), and DOMC/DOMB (at Concordia station, 3233 m elevation). Since 2015, when the DOMC/DOMB station started continuous operation, a relatively weak SEP event that was not detected by sea-level neutron-monitor stations was registered by both SOPO/SOPB and DOMC/DOMB, and it was accordingly classified as a GLE. This would lead to a distortion of the homogeneity of the historic GLE list and the corresponding statistics. To address this issue, we propose to modify the GLE definition so that it maintains the homogeneity: A GLE event is registered when there are near-time coincident and statistically significant enhancements of the count rates of at least two differently located neutron monitors, including at least one neutron monitor near sea level and a corresponding enhancement in the proton flux measured by a space-borne instrument(s). Relatively weak SEP events registered only by high-altitude polar neutron monitors, but with no response from cosmic-ray stations at sea level, can be classified as sub-GLEs

    The Power of General Relativity

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    We study the cosmological and weak-field properties of theories of gravity derived by extending general relativity by means of a Lagrangian proportional to R1+δR^{1+\delta}. This scale-free extension reduces to general relativity when δ0\delta \to 0. In order to constrain generalisations of general relativity of this power class we analyse the behaviour of the perfect-fluid Friedmann universes and isolate the physically relevant models of zero curvature. A stable matter-dominated period of evolution requires δ>0\delta >0 or δ<1/4\delta <-1/4. The stable attractors of the evolution are found. By considering the synthesis of light elements (helium-4, deuterium and lithium-7) we obtain the bound 0.017<δ<0.0012.-0.017<\delta <0.0012. We evaluate the effect on the power spectrum of clustering via the shift in the epoch of matter-radiation equality. The horizon size at matter--radiation equality will be shifted by 1\sim 1% for a value of δ0.0005.\delta \sim 0.0005. We study the stable extensions of the Schwarzschild solution in these theories and calculate the timelike and null geodesics. No significant bounds arise from null geodesic effects but the perihelion precession observations lead to the strong bound δ=2.7±4.5×1019\delta =2.7\pm 4.5\times 10^{-19} assuming that Mercury follows a timelike geodesic. The combination of these observational constraints leads to the overall bound 0δ<7.2×10190\leq \delta <7.2\times 10^{-19} on theories of this type.Comment: 26 pages and 5 figures. Published versio
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