Solubility of Tar Model Compounds in Various Solvents for Tar Removal in a Dual Fluidized Bed Biomass Gasification Process

Production of high quality product gas via biomass steam gasification is a promising technology. However, impurities in the product gas, namely tars, cause problems in the downstream gas processing operations and thus they need to be removed efficiently. Oil scrubbing is an effective solution for tar removal due to its non-polar characteristic which is similar to tar nature. In this research, solubility values of five simulated tar compounds were experimentally investigated for selecting the new scrubbing solvent. The simulated tar compounds investigated represent those found in the dual fluidized bed steam gasification of wood biomass, which are: naphthalene, biphenyl, anthracene, fluoranthene, and pyrene. The scrubbing solvents tested in this research are classified into biodiesels, vegetable oils, and diesel. Biodiesel used are rapeseed methyl ester (RME) and 2 different palm methyl esters (denoted as PME1 and PME2). Vegetable oils are sunflower oil, refined palm oil, Thai rice bran oil, and crude palm oil. All of the solubility tests were performed in the laboratory-scale test-rig at 30, 50, 70, and 80°C. Biodiesels are found to be the effective solvent in dissolving the tar compounds. PME1 shows the similar tar removal performance to RME but is more readily available; therefore, PME1 is chosen to be used as a scrubbing solvent at the Thailand 1 MWel prototype DFB gasifier at Nong Bua district in Nakhon Sawan province, Thailand

Influence of Solvent Temperature and Type on Naphthalene Solubility for Tar Removal in a Dual Fluidized Bed Biomass Gasification Process

Tar condensation is a cause of blockage in downstream application of the gasification process. An oil scrubber is considered as an effective method for tar removal. In this research, the naphthalene solubility in different local Thai oils and water was investigated in a laboratory-scale test-rig. The solubility value was conducted at 30, 50, 70, and 80°C. Biodiesels investigated were rapeseed methyl ester (RME) and two different palm methyl esters (PME 1 and PME 2). Furthermore, vegetable oils including sunflower oil, rice bran oil, crude palm oil, and refined palm oil were examined. The results showed that higher temperature enhanced naphthalene solubility in all types of investigated oils. Biodiesel has the highest value of naphthalene solubility. All scrubbing oils have similar naphthalene solubility trends at the temperature range of 50-80°C in the order of RME > PME 1 > PME 2 > diesel > sunflower oil > refined palm oil > rice bran oil > crude palm oil. Based on these experimental investigations, PME 1 has a naphthalene solubility value similar to RME. Therefore, PME 1 has been selected to be tested as scrubbing solvent in the 1 MWel prototype dual fluidized gasifier located in Nong Bua district, Nakhon Sawan province, Thailand

Replacement of Palm Methyl Ester to Rapeseed Methyl Ester for Tar Removal in the Nong Bua Dual Fluidized Bed Gasification Power Plant

The blockage problem of tar in a biomass power plant is a main problem and it must be removed. Rapeseed methyl ester (RME) was imported and used as scrubbing solvent to scrub tar at a 1 MWel Nong Bua prototype Dual Fluidised Bed (DFB) gasifier in Nong Bua district, Nakhonsawan province, Thailand. Using local oil in Thailand is an attractive choice from economic viewpoint. Pervious lab test study on naphthalene solubility in different local oils in Thailand was investigated. Local palm methyl ester (PME) shows the competitive performance to the RME. In this research, PME was tested to scrub tar in an oil scrubber at the Nong Bua DFB gasifier plant. Gravimetric tar content after passed a PME scrubber was measured and compared to that from a RME oil scrubber. The results show that both solvents have similar tar removal performance due to their contents of ester, methanol, and glycerin are similar. In addition, viscosity of both solvents has no significant effect on tar removal. From the current research, therefore, PME has been used as solvent in an oil scrubber at 1 MWel Nong Bua prototype DFB gasifier with technical and economic reasons

Effect of the presence of HCl on simultaneous CO₂ capture andcontaminants removal from simulated biomass gasification producer gas by CaO-Fe₂O₃ sorbent in calcium looping cycles

This study investigated the effect of HCl in biomass gasification producer gas on the CO2 capture efficiency and contaminants removal efficiency by CaO-Fe2O3 based sorbent material in the calcium looping process. Experiments were conducted in a fixed bed reactor to capture CO2 from the producer gas with the combined contaminants of HCl at 200 ppmv, H2S at 230 ppmv, and NH3 at 2300 ppmv. The results show that with presence of HCl in the feeding gas, sorbent reactivity for CO2 capture and contaminants removal was enhanced. The maximum CO2 capture was achieved at carbonation temperatures of 680 °C, with efficiencies of 93%, 92%, and 87%, respectively, for three carbonation-calcination cycles. At this carbonation temperature, the average contaminant removal efficiencies were 92.7% for HCl, 99% for NH3, and 94.7% for H2S. The outlet contaminant concentrations during the calcination process were also examined which is useful for CO2 reuse. The pore structure change of the used sorbent material suggests that the HCl in the feeding gas contributes to high CO2 capture efficiency and contaminants removal simultaneously

Co-gasification of Cassava Rhizome and Woody Biomass in the 1 MWel_{el} Prototype Dual Fluidised Bed Gasifier by Gussing Renewable Energy

In the current research, the effect of the mixture ratio by weight of wood chips to cassava rhizome (100%:0%, 75%:25%, and 50%:50%) was investigated on the properties of the product gas produced from the Dual Fluidised Bed gasifier power plant. The DFB gasifier power plant is located in Nongbua district, Nakhon Sawan province, Thailand. The results from this study show that the use of 100% wood chips as a fuel generates high quality product gas as designed. The mixture of wood chips and cassava rhizome in the weight ratio of 75%:25% and 50%:50% also gives satisfactory results: steady operation conditions of the whole power plant process, good quality and quantity of product gas, however, the tar content in the product gas was slightly higher than that of using wood chips alone. The researchers found that cassava rhizome can be used as a fuel mixture together with wood chips in the current DFB gasifier at site to generate heat and electricity. The outcome of this research will create the use of waste cassava rhizome, enormously available around the power plant, as well as the broad application of gasification technology using various biomass feedstock types available in Thailand