Electrochemical and morphological studies of copper electrodeposits deposited onto a copper (111) substrate in the presence of halo-compounds of acetic acid

Halo-compounds of acetic acid present in small quantities in an acid copper sulphate bath have been found to modify the growth of copper deposits on a copper (111) substrate and to increase the cathodic polarization. At low d.c. densities a transition in the type of growth from triangular pyramids to twinned pyramids and finally to polycrystalline deposit was observed. At high d.c. densities triangular and hexagonal pyramids transformed to truncated hexagonal and twinned pyramids which subsequently changed to a polycrystalline deposit. These changes are attributed to adsorption of the halo-compounds of acetic acid on the substrate. The mechanism of the deposition process is discussed. Surface coverages of addition agents determined from exchange current density values were found to fit a Langmuir adsorption isotherm. The negative free energies of adsorption of the addition agents indicate strong adsorption and inhibition of the deposition process by halo-compounds of acetic acid. © 1979

Electrodeposition of Zn-​Ni alloy from an acid sulfate bath containing ethanolamines

Electrodeposition of Zn-​Ni alloy contg. 10-​15​% Ni was carried out from an acid sulfate bath contg. ethanolamines. The effect of plating variables - such as metal ion ratio in the bath, pH, c.d., temp., stirring, concn. of ethanolamines in the bath and thickness - on the alloy compn. and cathodic c.d. was studied. The phase structure and the surface morphol. of electrodeposited Zn-​Ni alloy (SEM) and harness (on Vicker's scale) are reported

Bose-Hubbard Models in Confining Potentials: An Inhomogeneous Mean-Field Theory

We present an extensive study of Mott insulator (MI) and superfluid (SF) shells in Bose-Hubbard (BH) models for bosons in optical lattices with harmonic traps. For this we develop an inhomogeneous mean-field theory. Our results for the BH model with one type of spinless bosons agrees quantitatively with quantum Monte Carlo (QMC) simulations. Our approach is numerically less intensive than such simulations, so we are able to perform calculation on experimentally realistic, large 3D systems, explore a wide range of parameter values, and make direct contact with a variety of experimental measurements. We also generalize our inhomogeneous mean-field theory to study BH models with harmonic traps and (a) two species of bosons or (b) spin-1 bosons. With two species of bosons we obtain rich phase diagrams with a variety of SF and MI phases and associated shells, when we include a quadratic confining potential. For the spin-1 BH model we show, in a representative case, that the system can display alternating shells of polar SF and MI phases; and we make interesting predictions for experiments in such systems.Comment: 17 pages, 18 figure

A Naïve Visual Cryptographic Algorithm for the Transfer of Compressed Medical Images

The transmission of a suitably compressed image over a bandwidth, over long distances, gives rise towards a new era in the field of information technology. A gradual increase in this appending scenic application, involving the transfer of the images securely over the Ethernet has become an increasingly important aspect to be addressed during thou phenomenon, especially in the transfer of the digital medical images vividly, encapsulated with abundant information related to these images. The compressed medical images of the DICOM format contain certain amount of confidential data, pertaining to a clinical research or to an individual, and the confidentiality of the same has to be preserved from various security threats and eves-dropping. With a widespread applications among various multimedia applicative systems, telemedicine, medical imaging, military and certain safety-critical applications, inter-net and intra-net communicative applications, etc, a reliable transfer of suitable information, efficiently & securely is considered as one of the revolutionary aims in today’s communication technology and visual cryptographic methodologies. Real-time applications as such detailed above majorly is concerned with the security measures and many algorithms have been developed as a proof for various visual cryptographic methodologies. In this paper we propose an efficient and a reliable visual cryptographic methodology which focuses on the encryption and decryption of the two-dimensional DICOM standard compressed medical image, effectively.  This paper discusses an efficient design of 192 bit encoder using AES Rijndael Algorithm with the decomposition of an image into square image size blocks and the image blocks are shuffled using 2D CAT map. The shuffling of the image blocks/pixels employs a Logistic map of these image pixels coupled with 2D mapping of the pixels of the DICOM standard medical image, generated randomly, being the control parameter thereby creating a confusion between the cipher and the plain image, gradually increasing the resistive factor against the significant attacks. This paper proposes various analytical metrics such as correlation analysis, entropy analysis, homogeneity analysis, energy analysis, contrast and mean of absolute deviation analysis, to evaluate the proposed algorithm, and their suitability in image encryption applications

Phases and transitions in the spin-1 Bose-Hubbard model: systematics of a mean-field theory

We generalize the mean-field theory for the spinless Bose-Hubbard model to account for the different types of superfluid phases that can arise in the spin-1 case. In particular, our mean-field theory can distinguish polar and ferromagnetic superfluids, Mott insulator, that arise at integer fillings at zero temperature, and normal Bose liquids into which the Mott insulators evolve at finite temperatures. We find, in contrast to the spinless case, that several of the superfluid-Mott insulator transitions are of first order at finite temperatures. Our systematic study yields rich phase diagrams that include first-order and second-order transitions and a variety of tricritical points. We discuss the possibility of realizing such phase diagrams in experimental systems

Quantum entanglement of spin-1 bosons with coupled ground states in optical lattices

We examine particle entanglement, characterized by pseudo-spin squeezing, of spin-1 bosonic atoms with coupled ground states in a one-dimensional optical lattice. Both the superfluid and Mott-insulator phases are investigated separately for ferromagnetic and antiferromagnetic interactions. Mode entanglement is also discussed in the Mott insulating phase. The role of a small but nonzero angle between the polarization vectors of counter-propagating lasers forming the optical lattice on quantum correlations is investigated as well.Comment: 18 pages, 8 figures. To be published in Journal of Physics

Hanbury Brown-Twiss Interferometry for Fractional and Integer Mott Phases

Hanbury-Brown-Twiss interferometry (HBTI) is used to study integer and fractionally filled Mott Insulator (MI) phases in period-2 optical superlattices. In contrast to the quasimomentum distribution, this second order interferometry pattern exhibits high contrast fringes in the it insulating phases. Our detailed study of HBTI suggests that this interference pattern signals the various superfluid-insulator transitions and therefore can be used as a practical method to determine the phase diagram of the system. We find that in the presence of a confining potential the insulating phases become robust as they exist for a finite range of atom numbers. Furthermore, we show that in the trapped case the HBTI interferogram signals the formation of the MI domains and probes the shell structure of the system.Comment: 13 pages, 15 figure

Revealing Superfluid--Mott-Insulator Transition in an Optical Lattice

We study (by an exact numerical scheme) the single-particle density matrix of $\sim 10^3$ ultracold atoms in an optical lattice with a parabolic confining potential. Our simulation is directly relevant to the interpretation and further development of the recent pioneering experiment by Greiner et al. In particular, we show that restructuring of the spatial distribution of the superfluid component when a domain of Mott-insulator phase appears in the system, results in a fine structure of the particle momentum distribution. This feature may be used to locate the point of the superfluid--Mott-insulator transition.Comment: 4 pages (12 figures), Latex. (A Latex macro is corrected

Globally Optimal Crowdsourcing Quality Management

We study crowdsourcing quality management, that is, given worker responses to a set of tasks, our goal is to jointly estimate the true answers for the tasks, as well as the quality of the workers. Prior work on this problem relies primarily on applying Expectation-Maximization (EM) on the underlying maximum likelihood problem to estimate true answers as well as worker quality. Unfortunately, EM only provides a locally optimal solution rather than a globally optimal one. Other solutions to the problem (that do not leverage EM) fail to provide global optimality guarantees as well. In this paper, we focus on filtering, where tasks require the evaluation of a yes/no predicate, and rating, where tasks elicit integer scores from a finite domain. We design algorithms for finding the global optimal estimates of correct task answers and worker quality for the underlying maximum likelihood problem, and characterize the complexity of these algorithms. Our algorithms conceptually consider all mappings from tasks to true answers (typically a very large number), leveraging two key ideas to reduce, by several orders of magnitude, the number of mappings under consideration, while preserving optimality. We also demonstrate that these algorithms often find more accurate estimates than EM-based algorithms. This paper makes an important contribution towards understanding the inherent complexity of globally optimal crowdsourcing quality management

Positioning canine induced pluripotent stem cells (iPSCs) in the reprogramming landscape of naïve or primed state in comparison to mouse and human iPSCs

Aims: Deriving canine-induced pluripotent stem cells (ciPSCs) have paved the way for developing novel cell-based disease models and transplantation therapies in the dog. Though ciPSCs have been derived in the presence of Leukemia inhibitory factor (LIF) as well in the presence of basic fibroblast growth factor (bFGF), the positioning of ciPSCs in the naïve or the primed state of pluripotency remains elusive. This study aims to understand whether canine iPSCs belong to naïve or prime state in comparison to mouse (m) iPSCs and human (h) iPSCs.// Main methods: In the present study, we derived ciPSCs in presence of LIF and compared their state of pluripotency with that of miPSCs and hiPSCs by culturing them in the presence of LIF, bFGF, and LIF + bFGF. Gene expression level at transcript level was performed by RT-PCR and qRT-PCR and at the protein level was analysed by immunofluorescence. We also attempted to understand the pluripotency state using lipid body analysis by bodipy staining and blue fluorescence emission.// Key findings: In contrast to miPSCs, the naïve pluripotent stem cells, ciPSCs showed the expression of FGF5 similar to that of primed pluripotent stem cell, hiPSCs. Compared to miPSCs, ciPSCs cultured in presence of LIF showed enhanced expression of primed pluripotent marker FGF5, similar to hiPSCs cultured in presence of bFGF. Upon culturing in hiPSC culture condition, ciPSCs showed enhanced expression of core pluripotency genes compared to miPSCs cultured in similar condition. However, ciPSCs expressed naïve pluripotent marker SSEA1 similar to miPSCs and lacked the expression of primed state marker SSEA4 unlike hiPSCs. Interestingly, for the first time, we demonstrate the ciPSC pluripotency using lipid body analysis wherein ciPSCs showed enhanced bodipy staining and blue fluorescence emission, reflecting the primed state of pluripotency. ciPSCs expressed higher levels of fatty acid synthase (FASN), the enzyme involved in the synthesis of palmitate, similar to that of hiPSCs and higher than that of miPSCs. As ciPSCs exhibit characteristic properties of both naïve and primed pluripotent state, it probably represents a unique intermediary state of pluripotency that is distinct from that of mice and human pluripotent stem cells.// Significance: Elucidating the pluripotent state of ciPSCs assists in better understanding of the reprogramming events and development in different species. The study would provide a footprint of species-specific differences involved in reprogramming and the potential implication of iPSCs as a tool to analyse evolution