SPECTROPHOTOMETRIC DETERMINATION OF PHENOL BY CHARGE-TRANSFER COMPLEXATION

The phenol is used in pharmaceutical domain as agent of preservation, a rapid and reliable spectrophotometric method was validated for its determination in routine control. This method is based on the formation of a charge transfer complex between phenol and 2,6-dichloroquinone-4-chloroimide (DCQ) in basic medium. This produced a blue product with maximum absorption at 610nm. Beer's law is obeyed and the calibration curve was linear (r = 0.999) over the range 7.5 10 -6 M -7.5 10 -

Tunable and precise two-bunch generation at FLASHForward

Beam-driven plasma-wakefield acceleration based on external injection has the potential to significantly reduce the size of future accelerators. Stability and quality of the acceleration process substantially depends on the incoming bunch parameters. Precise control of the current profile is essential for optimising energy-transfer efficiency and preserving energy spread. At the FLASHForward facility, driver--witness bunch pairs of adjustable bunch length and separation are generated by a set of collimators in a dispersive section, which enables fs-level control of the longitudinal bunch profile. The design of the collimator apparatus and its commissioning is presented.Comment: 7 pages, 5 figures, to be published in the proceedings of the 4th European Advanced Accelerator Concepts Workshop, 15-21 September 2019, La Biodola Bay, Isola d'Elba, Ital

Derivation of dual horizon state-based peridynamics formulation based on euler-lagrange equation

The numerical solution of peridynamics equations is usually done by using uniform spatial discretisation. Although implementation of uniform discretisation is straightforward, it can increase computational time significantly for certain problems. Instead, non-uniform discretisation can be utilised and different discretisation sizes can be used at different parts of the solution domain. Moreover, the peridynamic length scale parameter, horizon, can also vary throughout the solution domain. Such a scenario requires extra attention since conservation laws must be satisfied. To deal with these issues, dual-horizon peridynamics was introduced so that both non-uniform discretisation and variable horizon sizes can be utilised. In this study, dual-horizon peridynamics formulation is derived by using Euler–Lagrange equation for state-based peridynamics. Moreover, application of boundary conditions and determination of surface correction factors are also explained. Finally, the current formulation is verified by considering two benchmark problems including plate under tension and vibration of a plate

Lichenological exploration of Algeria: historical overview and annotated bibliography, 1799-2013

yesDespite more than two centuries of almost uninterrupted surveys and studies of Algerian lichenology, the history and lichen diversity of Algeria are still poorly understood. During the preparation of a forthcoming checklist of Algerian lichens it was considered necessary to provide the present historical overview of lichenological exploration of the country from 1799 to 2013, supported by a reasonably comprehensive annotated bibliography of 171 titles

Computational Homogenization of Architectured Materials

Architectured materials involve geometrically engineered distributions of microstructural phases at a scale comparable to the scale of the component, thus calling for new models in order to determine the effective properties of materials. The present chapter aims at providing such models, in the case of mechanical properties. As a matter of fact, one engineering challenge is to predict the effective properties of such materials; computational homogenization using finite element analysis is a powerful tool to do so. Homogenized behavior of architectured materials can thus be used in large structural computations, hence enabling the dissemination of architectured materials in the industry. Furthermore, computational homogenization is the basis for computational topology optimization which will give rise to the next generation of architectured materials. This chapter covers the computational homogenization of periodic architectured materials in elasticity and plasticity, as well as the homogenization and representativity of random architectured materials

Emulsification of chemical and enzymatic hydrolysates of beta-lactoglobulin : characterization of the peptides adsorbed at the interface

International audienc

Surface effects of network materials based on strain gradient homogenized media

The asymptotic homogenization of periodic network materials modeled as beam networks is pursued in this contribution, accounting for surface effects arising from the presence of a thin coating on the surface of the structural beam elements of the network. Cauchy and second gradient effective continua are considered and enhanced by the consideration of surface effects. The asymptotic homogenization technique is here extended to account for the additional surface properties, which emerge in the asymptotic expansion of the effective stress and hyperstress tensors versus the small scale parameters and the additional small parameters related to surface effects. Based on the elaboration of small dimensionless parameters of geometrical or mechanical nature reflecting the different length scales, we construct different models in which the importance of surface effects is dictated by specific choice of the scaling relations between the introduced small parameters. The effective moduli reflect the introduced surface properties. We show in particular that surface effects may become dominant for specific choices of the scaling laws of the introduced small parameters. Examples of networks are given for each class of the considered effective constitutive models to illustrate the proposed general framework