36 research outputs found
High pressure effects in fluorinated HgBa2Ca2Cu3O(8+d)
We have measured the pressure sensitivity of Tc in fluorinated
HgBa2Ca2Cu3O(8+d) (Hg-1223) ceramic samples with different F contents, applying
pressures up to 30 GPa. We obtained that Tc increases with increasing pressure,
reaching different maximum values, depending on the F doping level, and
decreases for a further increase of pressure. A new high Tc record (166 K +/- 1
K) was achieved by applying pressure (23 GPa) in a fluorinated Hg-1223 sample
near the optimum doping level. Our results show that all our samples are at the
optimal doping, and that fluorine incorporation decreases the crystallographic
-parameter concomitantly increasing the maximum attainable Tc. This effect
reveals that the compression of the axes is one of the keys that controls
the Tc of high temperature superconductors.Comment: 4 pages, 4 figures, submitted to Phys. Rev.
Strong enhancement of superconductivity at high pressures within the charge-density-wave states of 2H-TaS 2 and 2H-TaSe 2
We present measurements of the superconducting and charge density wave
critical temperatures (Tc and TCDW) as a function of pressure in the transition
metal dichalchogenides 2H-TaSe2 and 2H-TaS2. Resistance and susceptibility
measurements show that Tc increases from temperatures below 1 K up to 8.5 K at
9.5 GPa in 2H-TaS2 and 8.2 K at 23 GPa in 2H-TaSe2. We observe a kink in the
pressure dependence of TCDW at about 4 GPa that we attribute to the lock-in
transition from incommensurate CDW to commensurate CDW. Above this pressure,
the commensurate TCDW slowly decreases coexisting with superconductivity within
our full pressure range.Comment: Published in Phys. Rev B 93, 184512 (2016
Interlayer Magnetic Frustration in Quasi-stoichiometric Li1-xNi1+xO2
Susceptibility, high-field magnetization and submillimeter wave electron spin
resonance measurements of layered quasi-stoichiometric Li1-xNi1+xO2 are
reported and compared to isomorphic NaNiO2. A new mechanism of magnetic
frustration induced by the excess Ni ions always present in the Li layers is
proposed. We finally comment on the possible realization of an orbital liquid
state in this controversial compound.Comment: 4 pages, 5 figures, submitted to Phys.Rev.B, Rapid Com
Far-infrared vibrational properties of linear C60 polymers: A comparison between neutral and charged materials
We report the far-infrared transmittance spectrum of a pure phase of the orthorhombic high-temperature and high-pressure C-60 polymer and compare the results with a previously published spectrum of the charged RbC60 orthorhombic polymer. Assignments for both spectra are made with the aid of first-principles quantum molecular dynamics simulations of the two materials. We find that the striking spectral differences between the neutral and charged linear fullerene polymers can be fully accounted for by charge effects on the C-60 ball
First order transition and phase separation in pyrochlores with colossal-magnetoresistance
TlMnO pyrochlores present colossal magnetoresistance (CMR)
around the long range ferromagnetic ordering temperature (T). The
character of this magnetic phase transition has been determined to be first
order, by purely magnetic methods, in contrast to the second order character
previously reported by Zhao et al. (Phys. Rev. Lett. 83, 219 (1999)). The
highest CMR effect, as in TlCdMnO, corresponds to a
stronger first order character. This character implies a second type of
magnetic interaction, besides the direct superexchange between the Mn
ions, as well as a phase coexistence. A model is proposed, with a complete
Hamiltonian (including superexchange and an indirect interaction), which
reproduce the observed phenomenology.Comment: 6 pages. Figures include
Far-infrared study of the Jahn-Teller distorted C60 monoanion in C60 tetraphenylphosphoniumiodide
We report high-resolution far-infrared transmission measurements on C(60)-tetraphenylphosphoniumiodide as a function of temperature. In the spectral region investigated (20-650 cm(-1)), we assign intramolecular modes of the C(60) monoanion and identify low-frequency combination modes. The well-known F(1u)(1) and F(1u)(2) modes are split into doublers at room temperature, indicating a D(5d) or D(3d) distorted ball. This result is consistent with a dynamic Jahn-Teller effect in the strong-coupling limit or with a static distortion stabilized by low-symmetry perturbations. The appearance of silent odd modes is in keeping with symmetry reduction of the hall, while activation of even modes is attributed to interband electron-phonon coupling and orientational disorder in the fulleride salt. Temperature dependences reveal a weak transition in the region 125-150 K in both C(60)(-) and counterion modes, indicating a bulk, rather than solely molecular, effect. Anomalous softening (with decreasing temperature) in several modes may correlate with the radial character of those vibrations. [S0163-1829(98)03245-7]
Magnetic and structural properties of the iron silicide superconductor LaFeSiH
The magnetic and structural properties of the recently discovered
pnictogen/chalcogen-free superconductor LaFeSiH (~K) have been
investigated by Fe synchrotron M{\"o}ssbauer source (SMS) spectroscopy,
x-ray and neutron powder diffraction and Si nuclear magnetic resonance
spectroscopy (NMR). No sign of long range magnetic order or local moments has
been detected in any of the measurements and LaFeSiH remains tetragonal down to
2 K. The activated temperature dependence of both the NMR Knight shift and the
relaxation rate is analogous to that observed in strongly overdoped
Fe-based superconductors. These results, together with the
temperature-independent NMR linewidth, show that LaFeSiH is an homogeneous
metal, far from any magnetic or nematic instability, and with similar Fermi
surface properties as strongly overdoped iron pnictides. This raises the
prospect of enhancing the of LaFeSiH by reducing its carrier
concentration through appropriate chemical substitutions. Additional SMS
spectroscopy measurements under hydrostatic pressure up to 18.8~GPa found no
measurable hyperfine field
High temperature superconductivity (Tc onset at 34K) in the high pressure orthorhombic phase of FeSe
We have studied the structural and superconducting properties of tetragonal
FeSe under pressures up to 26GPa using synchrotron radiation and diamond anvil
cells. The bulk modulus of the tetragonal phase is 28.5(3)GPa, much smaller
than the rest of Fe based superconductors. At 12GPa we observe a phase
transition from the tetragonal to an orthorhombic symmetry. The high pressure
orthorhombic phase has a higher Tc reaching 34K at 22GPa.Comment: 15 pages, 4 figure
NEOTROPICAL XENARTHRANS: a data set of occurrence of xenarthran species in the Neotropics
Xenarthrans â anteaters, sloths, and armadillos â have essential functions for ecosystem maintenance, such as insect control and nutrient cycling, playing key roles as ecosystem engineers. Because of habitat loss and fragmentation, hunting pressure, and conflicts with 24 domestic dogs, these species have been threatened locally, regionally, or even across their full distribution ranges. The Neotropics harbor 21 species of armadillos, ten anteaters, and six sloths. Our dataset includes the families Chlamyphoridae (13), Dasypodidae (7), Myrmecophagidae (3), Bradypodidae (4), and Megalonychidae (2). We have no occurrence data on Dasypus pilosus (Dasypodidae). Regarding Cyclopedidae, until recently, only one species was recognized, but new genetic studies have revealed that the group is represented by seven species. In this data-paper, we compiled a total of 42,528 records of 31 species, represented by occurrence and quantitative data, totaling 24,847 unique georeferenced records. The geographic range is from the south of the USA, Mexico, and Caribbean countries at the northern portion of the Neotropics, to its austral distribution in Argentina, Paraguay, Chile, and Uruguay. Regarding anteaters, Myrmecophaga tridactyla has the most records (n=5,941), and Cyclopes sp. has the fewest (n=240). The armadillo species with the most data is Dasypus novemcinctus (n=11,588), and the least recorded for Calyptophractus retusus (n=33). With regards to sloth species, Bradypus variegatus has the most records (n=962), and Bradypus pygmaeus has the fewest (n=12). Our main objective with Neotropical Xenarthrans is to make occurrence and quantitative data available to facilitate more ecological research, particularly if we integrate the xenarthran data with other datasets of Neotropical Series which will become available very soon (i.e. Neotropical Carnivores, Neotropical Invasive Mammals, and Neotropical Hunters and Dogs). Therefore, studies on trophic cascades, hunting pressure, habitat loss, fragmentation effects, species invasion, and climate change effects will be possible with the Neotropical Xenarthrans dataset