Sustainable energy planning for remote islands and the waste legacy from renewable energy infrastructure deployment

This is the author accepted manuscript. The final version is available from Elsevier via the DOI in this record The transition towards a sustainable energy mix is required to achieve Sustainable Development Goal 7 for affordable and clean energy. Remote islands not connected to grid which depend on diesel generators may appear ideal because they can benefit from a variety of renewable energy sources. However, renewable energy deployment requires a lifetime perspective to not inherit waste and other problems to future generations. The aim of this paper is to present a life cycle sustainability framework developed and applied for the case of the island of Ushant off North West France. Seven renewable energy generation scenarios were examined and assessed using technoeconomic, social and environmental indicators utilising life cycle costing and life cycle assessment modelling. The results show that only three out of the seven examined renewable energy scenarios manage to cover the 6807 MWh per annum demand. These scenarios can improve all the indicators against the business-as-usual diesel generation scenario except the ones related to toxicity and reduce greenhouse gas emissions by more than 92%. The easy-to-use framework allows the users to adjust their scenarios and receive useful insight about the nature of the trade-offs between the various indicators. It can also be adapted and updated to include more technologies and support the investigation of more sustainable energy scenarios of other remote island cases in the future.France (Channel) England INTERREG VA programm

Performance and life cycle assessment of a small scale vertical axis wind turbine

This is the author accepted manuscriptWind energy is one of the most popular renewable energy technologies that is considered indispensable in any low carbon energy mix. Small scale wind technologies that occupy less space and can supply electricity directly to their owners are thought to be more environmental friendly than the large turbines and therefore attract less criticism. Based on these, smaller scale renewables especially micro wind turbines should be the ideal solution but this might be just a leap of logic. The aim of this paper is to investigate whether it is worth developing smaller scale vertical axis wind turbines (VAWT) as a solution towards mitigating climate change. A real case of a H-Rotor 5 kW Darrieus vertical axis wind turbine in Poland is investigated for its performance using actual generation data. More importantly, a life cycle assessment (LCA) is undertaken, by compiling a very detailed life cycle inventory based on primary data and two scenarios were examined for the end-of-life treatment, including recycling and incineration. The performance assessment results show that the actual performance is very poor mainly due to the low wind speed. For this reason a series of hypothetical capacity factors were used to facilitate comparison with other studies. Using the CML impact assessment methodology, eleven environmental impact categories are assessed. The results show that the majority of the impacts are accredited to the supporting infrastructure - especially the mast and the foundations - rather than the turbine itself, which in the case of the Global Warming Potential (GWP) accounts for only 30%. Although the specific VAWT cannot achieve a generation that could reduce the environmental impacts to the level of the existing wind energy in Poland, a feasible capacity factor of 1.4% could make the GWP lower than the average low voltage electricity mix in Poland. The environmental performance is very sensitive to the fluctuations of the capacity factor and recommendations are given for appropriate siting, recycling of the metals and integration of the turbine on existing building structure.France (Channel) England INTERREG IV

Potential trade-offs between eliminating plastics and mitigating climate change: An LCA perspective on Polyethylene Terephthalate (PET) bottles in Cornwall

This is the author accepted manuscript. The final version is available from Elsevier via the DOI in this recordThe aim of this study is to investigate whether eliminating plastics entirely under existing waste infrastructure and management practices could have an adverse effect on climate change, using a case study on the hypothetical substitution of Polyethylene Terephthalate (PET) with glass as the material for bottling liquids in the domestic sector in Cornwall, England. A life cycle environmental impacts-based model was created using high resolution local data on household waste and current management practices in combination with Life Cycle Assessment (LCA) datasets. The model allows users to define key system parameters such as masses of materials, transport options and end-of-life processes and produces results for 11 environmental impact categories including the Global Warming Potential (GWP). The results from the application of this model on the case study of Cornwall have shown that the substitution of PET with glass as the material for bottling under the current waste infrastructure and management practices could lead to significant increases in GWP and hinder efforts to tackle climate change. A sensitivity analysis of the glass/PET mass ratio suggests that in order to achieve equal GWP the glass bottles need to become approximately 38% of the weight they are now. Increasing the recycled content and decreasing losses during the recycling processes could also help lower the GWP by 18.9% and 14.5%, respectively. This model can be expanded further to include more types of plastics and other regions to evaluate designs of new regional circular economy with less plastics waste and pollution. Our study suggests that it is necessary and crucial to consider the specific waste infrastructure and management practices in place and use science-based models that incorporate life cycle thinking to evaluate any solutions to plastics pollution in order to avoid problem shifting.Engineering and Physical Sciences Research Council (EPSRC

Quantification of plastics in agriculture and fisheries at a regional scale: A case study of South West England

This is the final version. Available from MDPI via the DOI in this record. Data Availability Statement: All data in this study are available through the online links provided throughout the document, except the data provided by FWAG, which needs to be requested.The use of plastics in agriculture and in fisheries has been vital to increase food production and meet the demands of an increasingly growing global population. However, there are several drawbacks to the use of plastics in these industries. Most plastics used in agriculture are disposed of after one single use and are highly susceptible to weathering. Abandoned, lost, or discarded fishing gear cause considerable damage to marine life. Quantification of plastic waste generation in these industries is scarce or non-existent in the case of fisheries. In this paper, we estimate the amount of plastic waste generated by agriculture and fisheries at a regional scale, considering the South West of the UK as a case study. We followed a mass balance approach to quantify the potential plastic waste generated by these industries. We find a generation of 49 kt of plastic waste in agriculture, 47% of which has an unknown fate. We estimate 454 t/year of fishing gear waste, with unclear end-of-life pathways. A detailed quantitative understanding of plastic waste generation per sector at a regional scale is fundamental for tracking plastic waste flows, locating hotspots of pollution, and planning actions to reduce the amount of plastic waste along the chain of end-users.Engineering and Physical Sciences Research Council (EPSRC

Hybrid Nanomaterials of Magnetic Iron Nanoparticles and Graphene Oxide as Matrices for the Immobilization of beta-Glucosidase:Synthesis, Characterization, and Biocatalytic Properties

Hybrid nanostructures of magnetic iron nanoparticles and graphene oxide were synthesized and used as nanosupports for the covalent immobilization of β-glucosidase. This study revealed that the immobilization efficiency depends on the structure and the surface chemistry of nanostructures employed. The hybrid nanostructure-based biocatalysts formed exhibited a two to four-fold higher thermostability as compared to the free enzyme, as well as an enhanced performance at higher temperatures (up to 70°C) and in a wider pH range. Moreover, these biocatalysts retained a significant part of their bioactivity (up to 40%) after 12 repeated reaction cycles

A heuristic method for determining CO2 efficiency in transportation planning

Background CO2 emissions are generally considered the most important indicator to determine the global warming effects. Their evaluation in the case of a transportation infrastructure is generally not easy and could be achieved through a separate balance

Life cycle assessment of a novel metal recovery method from co-processing of coal mine waste and low-grade printed circuit boards

This is the author accepted manuscript. The final version is available from Elsevier via the DOI in this recordA double waste stream problem arises from the increasing use of electrical and electronic equipment and their energy consumption: potentially toxic wastes from the equipment itself and potential acid mine drainage from the waste of the coal mines that provide the fuel to cover the energy demand. CEReS (Co-processing of Coal Mine & Electronic Wastes: Novel Resources for a Sustainable Future) is a novel method to co-process the coal mine and low-grade PCBs waste to reduce their environmental impacts while producing metals and other valuable products. The aim of this study is to investigate whether CEReS method is more environmentally friendly than the conventional practices of landfilling and incineration. Based on a Polish coal mine case study, our study found that the CEReS method could potentially eliminate the environmental impacts related to toxicity but increase the climate change impacts by ten times. A sensitivity analysis has shown that using a lower carbon electricity mix could reduce the climate change and fossil depletion impacts. It is also recommended to reduce water and energy requirements in some stages of the method.Research Fund for Coal and Stee

Graphene nanobuds: Synthesis and selective organic derivatisation

Herein, the formation and selective organic derivatisation of graphene nanobud, an all carbon nanohybrid comprised by C60 and graphene, are presented. C60 cages are directly attached to the graphenic surface with stable covalent bonds. Importantly, prepared graphene nanobud shows remarkable dispersibility, decreased number of defects and highly aromatic character that are associated to improved electrical conductivity compared to pristine graphene. The high chemical reactivity of the curved sp2 carbon atoms of C60 led to a selective covalent attachment of organic groups onto C60 avoiding damage of the graphene aromatic system

A bottom-up approach for the synthesis of highly ordered fullerene-intercalated graphene hybrids

Much of the research effort on graphene focuses on its use as a building block for the development of new hybrid nanostructures with well-defined dimensions and properties suitable for applications such as gas storage, heterogeneous catalysis, gas/liquid separations, nanosensing, and biomedicine. Toward this aim, here we describe a new bottom-up approach, which combines self-assembly with the Langmuir–Schaefer deposition technique to synthesize graphene-based layered hybrid materials hosting fullerene molecules within the interlayer space. Our film preparation consists in a bottom-up layer-by-layer process that proceeds via the formation of a hybrid organo-graphene oxide Langmuir film. The structure and composition of these hybrid fullerene-containing thin multilayers deposited on hydrophobic substrates were characterized by a combination of X-ray diffraction, Raman and X-ray photoelectron spectroscopies, atomic force and scanning electron microscopies, and conductivity measurements. The latter revealed that the presence of C60 within the interlayer spacing leads to an increase in electrical conductivity of the hybrid material as compared to the organo-graphene matrix alone

Highly dispersible disk-like graphene nanoflakes

We present the preparation of disk-like graphene nanoflakes, highly dispersible in dimethylformamide (DMF), with uniform size and thickness. The preparation procedure includes an overnight mild sonication of natural graphite in DMF, followed by a purification step using ultra-centrifugation. The mean diameter of the as produced well defined round shaped graphene nanoflakes is about 100 nm and they consisted of less than twenty graphenic layers