2,677 research outputs found
A Dynamical Theory of Electron Transfer: Crossover from Weak to Strong Electronic Coupling
We present a real-time path integral theory for the rate of electron transfer
reactions. Using graph theoretic techniques, the dynamics is expressed in a
formally exact way as a set of integral equations. With a simple approximation
for the self-energy, the rate can then be computed analytically to all orders
in the electronic coupling matrix element. We present results for the crossover
region between weak (nonadiabatic) and strong (adiabatic) electronic coupling
and show that this theory provides a rigorous justification for the salient
features of the rate expected within conventional electron transfer theory.
Nonetheless, we find distinct characteristics of quantum behavior even in the
strongly adiabatic limit where classical rate theory is conventionally thought
to be applicable. To our knowledge, this theory is the first systematic
dynamical treatment of the full crossover region.Comment: 11 pages, LaTeX, 8 Postscript figures to be published in J. Chem.
Phy
Multilevel blocking approach to the fermion sign problem in path-integral Monte Carlo simulations
A general algorithm toward the solution of the fermion sign problem in
finite-temperature quantum Monte Carlo simulations has been formulated for
discretized fermion path integrals with nearest-neighbor interactions in the
Trotter direction. This multilevel approach systematically implements a simple
blocking strategy in a recursive manner to synthesize the sign cancellations
among different fermionic paths throughout the whole configuration space. The
practical usefulness of the method is demonstrated for interacting electrons in
a quantum dot.Comment: 4 pages RevTeX, incl. two figure
Recommended from our members
When a few undermine the whole: a class of social dilemmas in ridesharing
We investigate a class of social dilemmas that arise when a heterogeneous group of agents potentially benefit from a joint enterprise such as ridesharing. Participation in the enterprise incurs positive externalities to other participants; social welfare is maximized with full participation. However, if some agents find it a dominant strategy to opt out, then the potential benefit from the enterprise will decrease, leading to more members opting out. This iterated disincentivizing effect could result in massive welfare losses. We construct a game-theoretical model to implement these social dilemmas and report experimental evidence for their existence and welfare impact.NSF Grant SES-141892
Crossover from Fermi liquid to Wigner molecule behavior in quantum dots
The crossover from weak to strong correlations in parabolic quantum dots at
zero magnetic field is studied by numerically exact path-integral Monte Carlo
simulations for up to eight electrons. By the use of a multilevel blocking
algorithm, the simulations are carried out free of the fermion sign problem. We
obtain a universal crossover only governed by the density parameter . For
, the data are consistent with a Wigner molecule description, while
for , Fermi liquid behavior is recovered. The crossover value is surprisingly small.Comment: 4 pages RevTeX, 3 figures, corrected Tabl
Dynamical simulation of transport in one-dimensional quantum wires
Transport of single-channel spinless interacting fermions (Luttinger liquid)
through a barrier has been studied by numerically exact quantum Monte Carlo
methods. A novel stochastic integration over the real-time paths allows for
direct computation of nonequilibrium conductance and noise properties. We have
examined the low-temperature scaling of the conductance in the crossover region
between a very weak and an almost insulating barrier.Comment: REVTex, 4 pages, 2 uuencoded figures (submitted to Phys. Rev. Lett.
Thermodynamic phase diagram and phase competition in BaFe2(As1-xPx)2 studied by thermal expansion
High-resolution thermal-expansion and specific-heat measurements were
performed on single crystalline BaFe2(As1-xPx)2 (0 < x < 0.33, x = 1). The
observation of clear anomalies allows to establish the thermodynamic phase
diagram which features a small coexistence region of SDW and superconductivity
with a steep rise of Tc on the underdoped side. Samples that undergo the
tetragonal-orthorhombic structural transition are detwinned in situ, and the
response of the sample length to the magneto-structural and superconducting
transitions is studied for all three crystallographic directions. It is shown
that a reduction of the magnetic order by superconductivity is reflected in all
lattice parameters. On the overdoped side, superconductivity affects the
lattice parameters in much the same way as the SDW on the underdoped side,
suggesting an intimate relation between the two types of order. Moreover, the
uniaxial pressure derivatives of Tc are calculated using the Ehrenfest relation
and are found to be large and anisotropic. A correspondence between
substitution and uniaxial pressure is established, i.e., uniaxial pressure
along the b-axis (c-axis) corresponds to a decrease (increase) of the P
content. By studying the electronic contribution to the thermal expansion we
find evidence for a maximum of the electronic density of states at optimal
doping
Effect of monolingualism and bilingualism in the anterior cingulate cortex: a proton magnetic resonance spectroscopy study in two centers
Reports of an advantage of bilingualism on brain structure in young adult participants are inconsistent. Abutalebi et al. (2012) reported more efficient monitoring of conflict during the Flanker task in young bilinguals compared to young monolingual speakers. The present study compared young adult (mean age = 24) Cantonese-English bilinguals in Hong Kong and young adult monolingual speakers. We expected (a) differences in metabolites in neural tissue to result from bilingual experience, as measured by 1H-MRS at 3T, (b) correlations between metabolic levels and Flanker conflict and interference effects (c) different associations in bilingual and monolingual speakers. We found evidence of metabolic differences in the ACC due to bilingualism, specifically in metabolites Cho, Cr, Glx and NAA. However, we found no significant correlations between metabolic levels and conflict and interference effects and no significant evidence of differential relationships between bilingual and monolingual speakers. Furthermore, we found no evidence of significant differences in the mean size of conflict and interference effects between groups i.e. no bilingual advantage. Lower levels of Cho, Cr, Glx and NAA in bilingual adults compared to monolingual adults suggest that the brains of bilinguals develop greater adaptive control during conflict monitoring because of their extensive bilingual experience
General Relativistic Radiant Shock Waves in the Post-Quasistatic Approximation
An evolution of radiant shock wave front is considered in the framework of a
recently presented method to study self-gravitating relativistic spheres, whose
rationale becomes intelligible and finds full justification within the context
of a suitable definition of the post-quasistatic approximation. The spherical
matter configuration is divided into two regions by the shock and each side of
the interface having a different equation of state and anisotropic phase. In
order to simulate dissipation effects due to the transfer of photons and/or
neutrinos within the matter configuration, we introduce the flux factor, the
variable Eddington factor and a closure relation between them. As we expected
the strength of the shock increases the speed of the fluid to relativistic
values and for some critical ones is larger than light speed. In addition, we
find that energy conditions are very sensible to the anisotropy, specially the
strong one. As a special feature of the model, we find that the contribution of
the matter and radiation to the radial pressure are the same order of magnitude
as in the mant as in the core, moreover, in the core radiation pressure is
larger than matter pressure.Comment: To appear in Journal of Physics:Conference Series:"XXIX Spanish
Relativity Meeting (ERE 2006): Einstein's Legacy: From the Theoretical
Paradise to Astrophysical Observations
Optical signature of symmetry variations and spin-valley coupling in atomically thin tungsten dichalcogenides
Motivated by the triumph and limitation of graphene for electronic
applications, atomically thin layers of group VI transition metal
dichalcogenides are attracting extensive interest as a class of graphene-like
semiconductors with a desired band-gap in the visible frequency range. The
monolayers feature a valence band spin splitting with opposite sign in the two
valleys located at corners of 1st Brillouin zone. This spin-valley coupling,
particularly pronounced in tungsten dichalcogenides, can benefit potential
spintronics and valleytronics with the important consequences of spin-valley
interplay and the suppression of spin and valley relaxations. Here we report
the first optical studies of WS2 and WSe2 monolayers and multilayers. The
efficiency of second harmonic generation shows a dramatic even-odd oscillation
with the number of layers, consistent with the presence (absence) of inversion
symmetry in even-layer (odd-layer). Photoluminescence (PL) measurements show
the crossover from an indirect band gap semiconductor at mutilayers to a
direct-gap one at monolayers. The PL spectra and first-principle calculations
consistently reveal a spin-valley coupling of 0.4 eV which suppresses
interlayer hopping and manifests as a thickness independent splitting pattern
at valence band edge near K points. This giant spin-valley coupling, together
with the valley dependent physical properties, may lead to rich possibilities
for manipulating spin and valley degrees of freedom in these atomically thin 2D
materials
Optoelectronics with electrically tunable PN diodes in a monolayer dichalcogenide
One of the most fundamental devices for electronics and optoelectronics is
the PN junction, which provides the functional element of diodes, bipolar
transistors, photodetectors, LEDs, and solar cells, among many other devices.
In conventional PN junctions, the adjacent p- and n-type regions of a
semiconductor are formed by chemical doping. Materials with ambipolar
conductance, however, allow for PN junctions to be configured and modified by
electrostatic gating. This electrical control enables a single device to have
multiple functionalities. Here we report ambipolar monolayer WSe2 devices in
which two local gates are used to define a PN junction exclusively within the
sheet of WSe2. With these electrically tunable PN junctions, we demonstrate
both PN and NP diodes with ideality factors better than 2. Under excitation
with light, the diodes show photodetection responsivity of 210 mA/W and
photovoltaic power generation with a peak external quantum efficiency of 0.2%,
promising numbers for a nearly transparent monolayer sheet in a lateral device
geometry. Finally, we demonstrate a light-emitting diode based on monolayer
WSe2. These devices provide a fundamental building block for ubiquitous,
ultra-thin, flexible, and nearly transparent optoelectronic and electronic
applications based on ambipolar dichalcogenide materials.Comment: 14 pages, 4 figure
- …