Clay coated sand grains in petroleum reservoirs: understanding their distribution via a modern analogue

Clay-coated grains can inhibit ubiquitous, porosity-occluding quartz cement in deeply buried sandstones and thus lead to anomalously high porosity. A moderate amount of clay that is distributed as grain coats is good for reservoir quality in deeply buried sandstones. Being able to predict the distribution of clay-coated sand grains in petroleum reservoirs is thus important to help find and exploit anomalously good reservoir quality. Here we have adopted a high-resolution, analogue approach, using the Ravenglass Estuary marginal-shallow marine system, in NW England, U.K. Extensive geomorphic mapping, grain-size analysis, and bioturbation-intensity counts were linked to a range of scanning electron microscopy techniques to characterize the distribution and origin of clay-coated sand grains in surface sediment. Our work shows that grain coats are common in this marginal–shallow marine system, but they are heterogeneously distributed as a function of grain size, clay fraction, and depositional facies. The distribution and characteristics of detrital-clay-coated grains can be predicted with knowledge of specific depositional environment, clay fraction percentage, and grain size. The most extensive detrital-clay-coated grains are found in sediment composed of fine-grained sand containing 3.5 to 13.0% clay fraction, associated with inner-estuary tidal-flat facies. Thus, against common convention, the work presented here suggests that, in deeply buried prospects, the best porosity might be found in fine-grained, clay-bearing inner-tidal-flat-facies sands and not in coarse, clean channel-fill and bar facies

Compositional variation in modern estuarine sands: predicting major controls on sandstone reservoir quality

Primary depositional mineralogy has a major impact on sandstone reservoir quality. The spatial distribution of primary depositional mineralogy in sandstones is poorly-understood and consequently empirical models typically fail to accurately predict reservoir quality. To address this challenge, we have determined the spatial distribution of detrital minerals (quartz, feldspar, carbonates and clay minerals) in surface sediment throughout the Ravenglass Estuary, UK. We have produced, for the first time, high resolution maps of detrital mineral quantities over an area that is similar to many oil and gas reservoirs. Spatial mineralogy patterns (based on X-ray diffraction data) and statistical analyses revealed that estuarine sediment composition is primarily controlled by provenance, i.e. the character of bedrock and sediment drift in the source area. The distributions of quartz, feldspar, carbonates and clay minerals are primarily controlled by the grain size of specific minerals (e.g. rigid versus brittle grains) and estuarine hydrodynamics. The abundance of quartz, feldspar, carbonates and clay minerals is predictable as a function of depositional environment and critical grain-size thresholds. This study may be used, by analogy, to better predict the spatial distribution of sandstone composition, and thus reservoir quality in ancient and deeply-buried estuarine sandstones

The fire resistance of high-strength concrete containing natural zeolites

More sustainable and environmentally friendly concretes are essential to reduce the climatic and environmental impact of the growing demand for concrete to fuel urban sprawl. This manuscript reports on an experimental study designed to test the fire resistance of one such concrete, prepared to contain natural zeolite-bearing tuff. The fire resistance of concretes containing natural zeolites has received little attention and is therefore poorly understood. Relative reductions in residual uniaxial compressive strength as a function of increasing temperature (up to 1000 °C) were very similar for the reference concrete (containing no tuff) and the tuff-bearing concrete. These data can be explained by the similar influence of high-temperature on the chemical (dehydroxylation reactions) and physical (microcracking and porosity) properties of both concretes. The satisfactory performance of the concrete containing natural zeolites following fire is welcome owing to the economic, climatic, and environmental benefits of using natural pozzolan and aggregate substitutes