166 research outputs found
Exponential Krylov time integration for modeling multi-frequency optical response with monochromatic sources
Light incident on a layer of scattering material such as a piece of sugar or
white paper forms a characteristic speckle pattern in transmission and
reflection. The information hidden in the correlations of the speckle pattern
with varying frequency, polarization and angle of the incident light can be
exploited for applications such as biomedical imaging and high-resolution
microscopy. Conventional computational models for multi-frequency optical
response involve multiple solution runs of Maxwell's equations with
monochromatic sources. Exponential Krylov subspace time solvers are promising
candidates for improving efficiency of such models, as single monochromatic
solution can be reused for the other frequencies without performing full
time-domain computations at each frequency. However, we show that the
straightforward implementation appears to have serious limitations. We further
propose alternative ways for efficient solution through Krylov subspace
methods. Our methods are based on two different splittings of the unknown
solution into different parts, each of which can be computed efficiently.
Experiments demonstrate a significant gain in computation time with respect to
the standard solvers.Comment: 22 pages, 4 figure
Analytical modeling of light transport in scattering materials with strong absorption
We have investigated the transport of light through slabs that both scatter
and strongly absorb, a situation that occurs in diverse application fields
ranging from biomedical optics, powder technology, to solid-state lighting. In
particular, we study the transport of light in the visible wavelength range
between and nm through silicone plates filled with YAG:Ce
phosphor particles, that even re-emit absorbed light at different wavelengths.
We measure the total transmission, the total reflection, and the ballistic
transmission of light through these plates. We obtain average single particle
properties namely the scattering cross-section , the absorption
cross-section , and the anisotropy factor using an analytical
approach, namely the P3 approximation to the radiative transfer equation. We
verify the extracted transport parameters using Monte-Carlo simulations of the
light transport. Our approach fully describes the light propagation in phosphor
diffuser plates that are used in white LEDs and that reveal a strong absorption
() up to , where is the
slab thickness, is the absorption mean free path. In
contrast, the widely used diffusion theory fails to describe this parameter
range. Our approach is a suitable analytical tool for industry, since it
provides a fast yet accurate determination of key transport parameters, and
since it introduces predictive power into the design process of white light
emitting diodes
4-Hydroxy-3-methoxy-5-nitroacetophenone (5-nitroapocynin)
The title molecule, C9H9NO5, is close to planar (r.m.s. deviation from the mean plane of the non-H atoms = 0.058 Å). The OH group forms a bifurcated O—H⋯(O,O) hydrogen bond, with the intramolecular component to a nitro O atom and the intermolecular component to a keto O atom, the latter resulting in chains along [20]. A C—H⋯O interaction reinforces the packing
Deterministic and controllable photonic scattering media via direct laser writing
Photonic scattering materials, such as biological tissue and white paper, are
made of randomly positioned nanoscale inhomogeneities in refractive index that
lead to multiple scattering of light. Typically these materials, both
naturally-occurring or man-made, are formed through self assembly of the
scattering inhomogeneities, which imposes challenges in tailoring the disorder
and hence the optical properties. Here, We report on the nanofabrication of
photonic scattering media using direct laser writing with deterministic design.
These deterministic scattering media consist of submicron thick polymer
nanorods that are randomly oriented within a cubic volume. We study the total
transmission of light as a function of the number density of rods and of the
sample thickness to extract the scattering and transport mean free paths using
radiative transfer theory. Such photonic scattering media with deterministic
and controllable properties are model systems for fundamental light scattering
in particular with strong anisotropy and offer new applications in solid-state
lighting and photovoltaics.Comment: 18 pages, 9 figure
3,3′-Dinitrobisphenol A
The title compound [systematic name: 2,2′-dinitro-4,4′-(propane-2,2-diyl)diphenol], C15H14N2O6, crystallizes with two molecules in the asymmetric unit. Both have a trans conformation for their OH groups, and in each, the two aromatic rings are nearly orthogonal, with dihedral angles of 88.30 (3) and 89.62 (2)°. The nitro groups are nearly in the planes of their attached benzene rings, with C—C—N—O torsion angles in the range 1.21 (17)–4.06 (17)°, and they each accept an intramolecular O—H⋯O hydrogen bond from their adjacent OH groups. One of the OH groups also forms a weak intermolecular O—H⋯O hydrogen bond
Wafer-Scale Epitaxial Modulation of Quantum Dot Density
Precise control of the properties of semiconductor quantum dots (QDs) is
vital for creating novel devices for quantum photonics and advanced
opto-electronics. Suitable low QD-density for single QD devices and experiments
are challenging to control during epitaxy and are typically found only in
limited regions of the wafer. Here, we demonstrate how conventional molecular
beam epitaxy (MBE) can be used to modulate the density of optically active QDs
in one- and two- dimensional patterns, while still retaining excellent quality.
We find that material thickness gradients during layer-by-layer growth result
in surface roughness modulations across the whole wafer. Growth on such
templates strongly influences the QD nucleation probability. We obtain density
modulations between 1 and 10 QDs/ and periods ranging from several
millimeters down to at least a few hundred microns. This novel method is
universal and expected to be applicable to a wide variety of different
semiconductor material systems. We apply the method to enable growth of
ultra-low noise QDs across an entire 3-inch semiconductor wafer
Wafer-scale epitaxial modulation of quantum dot density
Precise control of the properties of semiconductor quantum dots (QDs) is vital for creating novel devices for quantum photonics and advanced opto-electronics. Suitable low QD-densities for single QD devices and experiments are challenging to control during epitaxy and are typically found only in limited regions of the wafer. Here, we demonstrate how conventional molecular beam epitaxy (MBE) can be used to modulate the density of optically active QDs in one- and two- dimensional patterns, while still retaining excellent quality. We find that material thickness gradients during layer-by-layer growth result in surface roughness modulations across the whole wafer. Growth on such templates strongly influences the QD nucleation probability. We obtain density modulations between 1 and 10 QDs/µm2 and periods ranging from several millimeters down to at least a few hundred microns. This method is universal and expected to be applicable to a wide variety of different semiconductor material systems. We apply the method to enable growth of ultra-low noise QDs across an entire 3-inch semiconductor wafer
Recommended from our members
Cardiovascular magnetic resonance techniques and findings in children with myocarditis: a multicenter retrospective study
Background: Cardiovascular magnetic resonance (CMR) is increasingly used to diagnose myocarditis in adults but its use in children is not well-established. We sought to describe the presentation, CMR protocol and findings, and outcomes in a multicenter cohort of children with myocarditis. Methods: Thirteen hospitals retrospectively identified patients meeting the following inclusion criteria: 1) diagnosis of myocarditis by the managing physicians, 2) age <21 years, 3) CMR examination within 30 days of presentation, and 4) no congenital heart disease. Clinical data and test results, including CMR findings, were abstracted from the medical record. Results: For the 143 patients meeting inclusion criteria, the median age was 16.0 years (range, 0.1-20.3) and 139 (97 %) were hospitalized at the time of CMR. The median time from presentation to CMR was 2 days (0-28). The median left ventricular ejection fraction at CMR was 56 % (10-74), with 29 (20 %) below 45 %. The median right ventricular ejection fraction was 54 % (15-72), with 11 (8 %) below 40 %. There was significant variability among centers in the types of tissue characterization techniques employed (p < 0.001). Overall, late gadolinium enhancement (LGE) was used in 100 % of studies, followed by T2-weighted imaging (T2W) in 69 %, first-pass contrast perfusion (FPP) in 48 %, and early gadolinium enhancement (EGE) in 28 %. Abnormalities were most common with LGE (81 %), followed by T2W (74 %), EGE (55 %), and FPP (8 %). The CMR study was interpreted as positive for myocarditis in 117 patients (82 %), negative in 18 (13 %), and equivocal in 7 (5 %), yielding a sensitivity of 82 %. At a median follow-up of 7.1 months (0-87), all patients were alive and 5 had undergone cardiac transplantation. CMR parameters at presentation associated with persistent left ventricular dysfunction were larger left ventricular end-diastolic volume and lower left and right ventricular ejection fraction but not abnormal LGE. Conclusions: Despite significant practice variation in imaging protocol among centers, CMR had a high sensitivity for the diagnosis of myocarditis in pediatric patients. Abnormalities were most often seen with LGE followed by T2W, EGE, and FPP. These findings should be useful in designing future prospective studies
Glutathione-Related Antioxidant Defense System in Elderly Patients Treated for Hypertension
The purpose of this study was to analyze glutathione antioxidant defense system in elderly patients treated for hypertension. Studies were carried out in the blood collected from 18 hypertensive and 15 age- and sex-matched controls, all subjects age over 60. Hypertensives were on their usual antihypertensive treatment at the time of blood collection. The concentration of glutathione (GSH) in whole blood and activities of glutathione peroxidase (GPx-1), glutathione transferase (GST), and glutathione reductase (GR) in erythrocytes were measured. The data from patients and controls were compared using independent-samples t test. P value of 0.05 and less was considered statistically significant. We observed increased glutathione-related antioxidant defense in treated hypertensive elderly patients (HT) when compared with healthy controls (C). Mean GSH concentration was significantly higher in HT when compared with C: 3.1 ± 0.29 and 2.6 ± 0.25 mmol/L, respectively, P < 0.001. Mean activity of GR was significantly higher in HT group if compared with C: 83.4 ± 15.25 U/g Hb versus 64.2 ± 8.26 U/g Hb, respectively, P < 0.001. Mean activity of GST was significantly higher in HT group compared with C: 3.0 ± 0.60 mmol CDNB-GSH/mgHb/min and 2.6 ± 0.36 mmol CDNB-GSH/mgHb/min, respectively, P < 0.05. No difference in GPx activity was observed between two groups. These results show that glutathione-related antioxidant defense system was enhanced in elderly hypertensive patients treated for their conditions. This suggests important role of glutathione system in blood pressure regulation. Alterations in concentration and activity of antioxidants observed during antihypertensive medication are likely to be related to the effect of the treatment on NO bioavailability
- …