CoCu/Cu Multilayers: Influence of Cu Layer Deposition Potential

The electrochemical, structural and magnetic properties of CoCu/Cu multilayers electrodeposited at different cathode potentials were investigated from a single bath. The Cu layer deposition potentials were selected as , and with respect to saturated calomel electrode (SCE) while the Co layer deposition potential was constant at versus SCE. For the electrochemical analysis, the current-time transients were obtained. The amount of noble non-magnetic (Cu) metal materials decreased with the increase of deposition potentials due to anomalous codeposition. Further, current-time transient curves for the Co layer deposition and capacitance were calculated. In the structural analysis, the multilayers were found to be polycrystalline with both Co and Cu layers adopting the face-centered cubic structure. The (111) peak shifts towards higher angle with the increase of the deposition potentials. Also, the lattice parameters of the multilayers decrease from 0.3669 nm to 0.3610 nm with the increase of the deposition potentials from to , which corresponds to the bulk values of Cu and Co, respectively. The electrochemical and structural results demonstrate that the amount of Co atoms increased and the Cu atoms decreased in the layers with the increase of deposition potentials due to anomalous codeposition. For magnetic measurements, the saturation magnetizations, obtained from the magnetic curves of the multilayers were obtained as 212 kA/m, 276 kA/m, and 366 kA/m with , , and versus SCE, respectively. It is seen that the values increased with the increase of the deposition potentials confirming the increase of the Co atoms and decrease of the Cu amount. The results of electrochemical and structural analysis show that the deposition potentials of non-magnetic layers plays important role on the amount of magnetic and non-magnetic materials in the layers and thus on the magnetic properties of the multilayers

Syngas cleaning for coal to methanol demo plant - H2S and COS removal

Syngas cleaning, especially the removal of COS and H2S, is a crucial step in the production of valuable chemicals from coal. As a part of the Tuncbilek Coal to Methanol project, a gas cleaning demo plant has been built. The aim of this paper is to disseminate the experience gained from these demo plant experiments concerning the performance of the gasifier and syngas cleaning demo-plant, especially about the removal of sulfur compounds. Additionally, some practical recommendations regarding the design and operation of such demo plants are given. The design-basis for the demo plant was a gas stream of 450 m(3)/h (at STP) containing 4,000 ppmv H2S and 2,000 ppmv COS. The performance target was to reduce H2S and COS concentrations to less than one ppmv each. The gas cleaning process consisted of a particulate filter, COS hydrolysis reactors, caustic scrubbers, H2S guard beds and heat exchangers. Two demo plant runs were conducted, and Tuncbilek lignite was gasified in the 6 ton/day (coal feeding capacity) entrained flow gasifier. The gasifier produced syngases with lower heating values of 7.64 and 8.86 MJ/m(3) (at STP), and cold gas efficiencies of 71 and 81% were achieved. The H2S and COS content of the successful run were 3,300 ppmv and 550 ppmv, respectively. At the exit of the gas cleaning demo plant, a concentration of 0.12 ppmv for H2S and 0.72 ppmv for COS were measured. Consequently, it was concluded that the performance of the gas cleaning demo plant was satisfactory for methanol production

Acute tubulointerstitial nephritis-uveitis (TINU) syndrome developed secondary to paracetamol and codeine phosphate use: two case reports

Tubulointerstitial nephritis (TIN) refers to a group of heterogeneous diseases affecting the interstitial compartment of the kidney. It might be primary or can develop secondary to many urinary systemic diseases. Primary TIN develops mainly following drug usage, exposure to toxins, and also infections and humoral and cell-mediated immune reactions. In some patients, signs of systemic inflammatory reactions can be the first presenting symptoms. Histopathological evaluation reveals mononuclear cells and lymphocytes in the interstitium and tubuli. Acute and chronic TIN can resolve after elimination of the culprit destructive factors, as drugs, toxins and immune reaction. Combination of tubulointerstitial inflammation and uveitis is termed as tubulointerstitial nephritis-uveitis (TINU) syndrome. Uveitis might occur before, after, and also concomitantly with TIN. Herein, two adolescent cases of TIN and TINU, seemingly developed secondary to paracetamol and codeine phosphate use, are presented

Contribution of Electron Microscopy to the Clinicopathologic Diagnosis in Childhood Glomerular Renal Diseases

Background: Electron microscopy (EM) provides another diagnostic assessment of glomerular lesions in addition to light and fluorescent microscopy. Objectives: We evaluated the contribution of diagnostic EM in childhood glomerular diseases. Patients and methods: Forty-eight renal biopsies which were assessed by EM between 2000 and 2014 were evaluated. Results: There were 21 (44%) females and 27 (56%) males, ages ranged between 6 and 204 months. EM findings were compatible with light and immunofluorescence microscopy in 65%, made additional contributions to diagnosis in 31% (especially in focal segmental glomerulosclerosis, Alport disease, membranoproliferative glomerulonephritis, dense deposit disease, thin basement membrane disease, and nephronophthisis), and was non-contributory in 4%. Conclusion: Electron microscopic evaluation supports other histopathological diagnoses in most cases, contributes additional diagnostic information in pediatric glomerular disease, especially in FSGS, thin glomerular basement membrane nephropathy, Alport disease, MPGN, and dense deposit disease, and its utilization should clinically justify the increase in cost and testing time

Co-firing of pine chips with Turkish lignites in 750 kWth circulating fluidized bed combustion system

WOS: 000395691900072PubMed ID: 27825549Two Turkish lignites which have different sulfur levels (2-2.9% dry) and ash levels (17-25% dry) were combusted with a Turkish forest red pine chips in a 750 kW-thermal capacity circulating fluidized bed combustor (CFBC) system. The combustion temperature was held at 850 +/- 50 degrees C. Flue gas emissions were measured by Gasmet DX-4000 flue gas analyzer. Two lignites were combusted alone, and then limestone was added to lignites to reduce SO2 emissions. Ca/S = 3 was used. 30% percent of red pine chips were added to the lignites for co-firing experiments without limestone in order to see the biomass effects. The results showed that with limestone addition SO2 concentration was reduced below the limit values for all lignites. CO emissions are high at low excess air ratios, gets lower as the excess air ratio increases. During co-firing experiments the temperature in the freeboard was 100-150 degrees C higher as compared to coal combustion experiments. (C) 2016 Elsevier Ltd. All rights reserved.TUBITAK-KAMAGTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [105G023]The financial support for this project by TUBITAK-KAMAG (Project Code: 105G023) is greatly appreciated. The views expressed in this paper belong to authors

Henoch-Schonlein purpura, post-streptococcal glomerulonephritis and acute rheumatic carditis after Group A beta-haemolytic streptococcal infection

Besides association with acute rheumatic fever (ARF) and acute glomerulonephritis (APSGN), in up to 40% of cases, Group A beta-haemolytic streptococcal (GABHS) infections are also implicated as a trigger for Henoch-Schonlein purpura (HSP). A 7-year-old girl with GABHS throat infection who developed HSP, APSGN and rheumatic carditis is reported. She presented with palpable purpura and arthritis in both ankles and later developed carditis characterised by mitral/aortic regurgitation and glomerulonephritis characterised by mixed nephritic/nephrotic syndrome. She had a raised anti-streptolysin titre (ASOT), blood urea nitrogen and creatinine and hypocomplementaemia (C-3), and renal biopsy demonstrated endocapillary and extracapillary proliferative glomerulonephritis with crescents. Immunofluorescence microscopy demonstrated a full house' of immunoglobulin and complement, viz. IgA+2, IgG+3, IgM+2, C(3)c+1, Clq+2 with predominantly IgG deposition. One week earlier, her 4-year-old sister had presented to another hospital with HSP complicated by microscopic haematuria, nephrotic-range proteinuria and gastro-intestinal involvement, and with raised ASOT and low C-3 levels. Although HSP has been associated with either ARF or APSGN, this is the first case of a child with HSP, ARF and APSGN in combination