227 research outputs found
The coil-globule transition of confined polymers
We study long polymer chains in a poor solvent, confined to the space between
two parallel hard walls. The walls are energetically neutral and pose only a
geometric constraint which changes the properties of the coil-globule (or
"-") transition. We find that the temperature increases
monotonically with the width between the walls, in contrast to recent
claims in the literature. Put in a wider context, the problem can be seen as a
dimensional cross over in a tricritical point of a model. We roughly
verify the main scaling properties expected for such a phenomenon, but we find
also somewhat unexpected very long transients before the asymptotic scaling
regions are reached. In particular, instead of the expected scaling exactly at the (-dependent) theta point we found that increases
less fast than , even for extremely long chains.Comment: 5 pages, 6 figure
Casimir Forces at Tricritical Points: Theory and Possible Experiments
Using field-theoretical methods and exploiting conformal invariance, we study
Casimir forces at tricritical points exerted by long-range fluctuations of the
order-parameter field. Special attention is paid to the situation where the
symmetry is broken by the boundary conditions (extraordinary transition).
Besides the parallel-plate configuration, we also discuss the geometries of two
separate spheres and a single sphere near a planar wall, which may serve as a
model for colloidal particles immersed in a fluid. In the concrete case of
ternary mixtures a quantitative comparison with critical Casimir and van der
Waals forces shows that, especially with symmetry-breaking boundaries, the
tricritical Casimir force is considerably stronger than the critical one and
dominates also the competing van der Waals force.Comment: 18 pages, Latex, 3 postscript figures, uses Elsevier style file
Universality of the thermodynamic Casimir effect
Recently a nonuniversal character of the leading spatial behavior of the
thermodynamic Casimir force has been reported [X. S. Chen and V. Dohm, Phys.
Rev. E {\bf 66}, 016102 (2002)]. We reconsider the arguments leading to this
observation and show that there is no such leading nonuniversal term in systems
with short-ranged interactions if one treats properly the effects generated by
a sharp momentum cutoff in the Fourier transform of the interaction potential.
We also conclude that lattice and continuum models then produce results in
mutual agreement independent of the cutoff scheme, contrary to the
aforementioned report. All results are consistent with the {\em universal}
character of the Casimir force in systems with short-ranged interactions. The
effects due to dispersion forces are discussed for systems with periodic or
realistic boundary conditions. In contrast to systems with short-ranged
interactions, for one observes leading finite-size contributions
governed by power laws in due to the subleading long-ranged character of
the interaction, where is the finite system size and is the
correlation length.Comment: 11 pages, revtex, to appear in Phys. Rev. E 68 (2003
Analytic Solution of Emden-Fowler Equation and Critical Adsorption in Spherical Geometry
In the framework of mean-field theory the equation for the order-parameter
profile in a spherically-symmetric geometry at the bulk critical point reduces
to an Emden-Fowler problem. We obtain analytic solutions for the surface
universality class of extraordinary transitions in for a spherical shell,
which may serve as a starting point for a pertubative calculation. It is
demonstrated that the solution correctly reproduces the Fisher-de Gennes effect
in the limit of the parallel-plate geometry.Comment: (to be published in Z. Phys. B), 7 pages, 1 figure, uuencoded
postscript file, 8-9
Critical dynamics in thin films
Critical dynamics in film geometry is analyzed within the field-theoretical
approach. In particular we consider the case of purely relaxational dynamics
(Model A) and Dirichlet boundary conditions, corresponding to the so-called
ordinary surface universality class on both confining boundaries. The general
scaling properties for the linear response and correlation functions and for
dynamic Casimir forces are discussed. Within the Gaussian approximation we
determine the analytic expressions for the associated universal scaling
functions and study quantitatively in detail their qualitative features as well
as their various limiting behaviors close to the bulk critical point. In
addition we consider the effects of time-dependent fields on the
fluctuation-induced dynamic Casimir force and determine analytically the
corresponding universal scaling functions and their asymptotic behaviors for
two specific instances of instantaneous perturbations. The universal aspects of
nonlinear relaxation from an initially ordered state are also discussed
emphasizing the different crossovers that occur during this evolution. The
model considered is relevant to the critical dynamics of actual uniaxial
ferromagnetic films with symmetry-preserving conditions at the confining
surfaces and for Monte Carlo simulations of spin system with Glauber dynamics
and free boundary conditions.Comment: 64 pages, 21 figure
Critical Casimir effect in films for generic non-symmetry-breaking boundary conditions
Systems described by an O(n) symmetrical Hamiltonian are considered
in a -dimensional film geometry at their bulk critical points. A detailed
renormalization-group (RG) study of the critical Casimir forces induced between
the film's boundary planes by thermal fluctuations is presented for the case
where the O(n) symmetry remains unbroken by the surfaces. The boundary planes
are assumed to cause short-ranged disturbances of the interactions that can be
modelled by standard surface contributions corresponding
to subcritical or critical enhancement of the surface interactions. This
translates into mesoscopic boundary conditions of the generic
symmetry-preserving Robin type .
RG-improved perturbation theory and Abel-Plana techniques are used to compute
the -dependent part of the reduced excess free energy per
film area to two-loop order. When , it takes the scaling
form as
, where are scaling fields associated with the
surface-enhancement variables , while is a standard
surface crossover exponent. The scaling function
and its analogue for the Casimir force
are determined via expansion in and extrapolated to
dimensions. In the special case , the expansion
becomes fractional. Consistency with the known fractional expansions of D(0,0)
and to order is achieved by appropriate
reorganisation of RG-improved perturbation theory. For appropriate choices of
and , the Casimir forces can have either sign. Furthermore,
crossovers from attraction to repulsion and vice versa may occur as
increases.Comment: Latex source file, 40 pages, 9 figure
Normal and Lateral Casimir Forces between Deformed Plates
The Casimir force between macroscopic bodies depends strongly on their shape
and orientation. To study this geometry dependence in the case of two deformed
metal plates, we use a path integral quantization of the electromagnetic field
which properly treats the many-body nature of the interaction, going beyond the
commonly used pairwise summation (PWS) of van der Waals forces. For arbitrary
deformations we provide an analytical result for the deformation induced change
in Casimir energy, which is exact to second order in the deformation amplitude.
For the specific case of sinusoidally corrugated plates, we calculate both the
normal and the lateral Casimir forces. The deformation induced change in the
Casimir interaction of a flat and a corrugated plate shows an interesting
crossover as a function of the ratio of the mean platedistance H to the
corrugation length \lambda: For \lambda \ll H we find a slower decay \sim
H^{-4}, compared to the H^{-5} behavior predicted by PWS which we show to be
valid only for \lambda \gg H. The amplitude of the lateral force between two
corrugated plates which are out of registry is shown to have a maximum at an
optimal wavelength of \lambda \approx 2.5 H. With increasing H/\lambda \gtrsim
0.3 the PWS approach becomes a progressively worse description of the lateral
force due to many-body effects. These results may be of relevance for the
design and operation of novel microelectromechanical systems (MEMS) and other
nanoscale devices.Comment: 20 pages, 5 figure
Critical adsorption on curved objects
A systematic fieldtheoretic description of critical adsorption on curved
objects such as spherical or rodlike colloidal particles immersed in a fluid
near criticality is presented. The temperature dependence of the corresponding
order parameter profiles and of the excess adsorption are calculated
explicitly. Critical adsorption on elongated rods is substantially more
pronounced than on spherical particles. It turns out that, within the context
of critical phenomena in confined geometries, critical adsorption on a
microscopically thin `needle' represents a distinct universality class of its
own. Under favorable conditions the results are relevant for the flocculation
of colloidal particles.Comment: 52 pages, 10 figure
A global charter for the public\u27s health - The public\u27s health: the role, functions, competencies, education
Political leaders increasingly perceive health as being crucial to achieving growth, development, equity and stability throughout the world. Health is now understood as a product of complex and dynamic relations generated by numerous determinants at different levels of governance. Governments need to take into account the impact of social, environmental and behavioural health determinants, including economic constraints, living conditions, demographic changes and unhealthy lifestyles in many of the World Health Organization (WHO) Member States. This understanding and increasing globalization means it is very timely to review the role of (global) public health in this changing societal and political environment
Generalized Casimir forces in non-equilibrium systems
In the present work we propose a method to determine fluctuation induced
forces in non equilibrium systems. These forces are the analogue of the well
known Casimir forces, which were originally introduced in Quantum Field theory
and later extended to the area of Critical Phenomena. The procedure starts from
the observation that many non equilibrium systems exhibit long-range
correlations and the associated structure factors diverge in the long
wavelength limit. The introduction of external bodies into such systems in
general modifies the spectrum of these fluctuations and leads to the appearance
of a net force between these bodies. The mechanism is illustrated by means of a
simple example: a reaction diffusion equation with random noises.Comment: Submitted to Europhysics Letters. 7 pages, 2 figure
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