On-line Vis-Nir sensor determination of soil variations of sodium, potassium and magnesium

Among proximal measurement methods, visible and near infrared (Vis-Nir) spectroscopy probably has the greatest potential for determining the physico-chemical properties of different natural resources, including soils. This study was conducted to determine the sodium, potassium and magnesium variations in a 10. Ha field located in Karacabey district (Bursa Province, Turkey) using an on-line Vis-Nir sensor. A total of 92 soil samples were collected from the field. The performance and accuracy of the Na, K and Mg calibration models was evaluated in cross-validation and independent validation. Three categories of maps were developed: 1) reference laboratory analyses maps based on 92 points 2) Full-data point maps based on all 6486 on-line points Vis-Nir predicted in 2013 and 3) full- data point maps based on all 2496 on-line points Vis-Nir predicted in 2015. Results showed that the prediction performance in the validation set was successful, with average R2 values of 0.82 for Na, 0.70 for K, and 0.79 for Mg, average root mean square error of prediction (RMSEP) values of 0.02% (Na), 0.20% (K), and 1.32% (Mg) and average residual prediction deviation (RPD) values of 2.13 (Na), 0.97 (K), and 2.20 (Mg). On-line field measurement was also proven to be successful with validation results showing average R2 values of 0.78 (Na), 0.64 (K), and 0.60 (Mg), average RMSEP values of 0.04% (Na), 0.13% (K), and 2.19% (Mg) and average RPD values of 1.57 (Na) 1.68 (K) and 1.56 (Mg). Based on 3297 points, maps of Na, K and Mg were produced after N, P, K and organic fertilizer applications, and these maps were then compared to the corresponding maps from the previous year. The comparison showed a variation in soil properties that was attributed to the variable rate of fertilization implemented in the preceding year

Online measurement of soil organic carbon as correlated with wheat normalised difference vegetation index in a vertisol field

This study explores the potential of visible and near infrared (vis-NIR) spectroscopy for onlinemeasurement of soil organic carbon (SOC). It also attempts to explore correlations and similarities between the spatial distribution of SOC and normalized differential vegetation index (NDVI) of a wheat crop. The online measurement was carried out in a clay vertisol field covering 10 ha of area in Karacabey, Bursa, Turkey. Kappa statistics were carried out between different SOC and NDVI data to investigate potential similarities. Calibration model of SOC in full cross-validationresulted in a good accuracy ( 2 = 0.75, root mean squares error of prediction (RMSEP) = 0.17%, and ratio of prediction deviation (RPD) = 1.81). The validation of the calibration model using laboratory spectra provided comparatively better prediction accuracy ( 2 = 0.70, RMSEP = 0.15%, and RPD = 1.78), as compared to the online measured spectra ( 2 = 0.60, RMSEP = 0.20%, and RPD = 1.41). Although visual similarity was clear, low similarity indicated by a lowKappa value of 0.259 was observed between the online vis-NIR predicted full-point (based on all pointsmeasured in the field, e.g., 6486 points)map of SOC and NDVI map

Prediction of soil sand and clay contents via visible and near-infrared (Vis-NIR) spectroscopy

Visible and near infrared (Vis-NIR) spectroscopy is a non-destructive analytical method that can be used to complement, enhance or potentially replace conventional methods of soil analysis. The aim of this research was to predict the particle size distribution (PSD) of soils using a Vis-NIR) spectrophotometry in one irrigate field having a vertisol clay texture in the Karacabey district of Bursa Province, Turkey. A total of 86 soil samples collected from the study area were subjected to optical scanning in the laboratory with a portable, fiber-type Vis-NIR spectrophotometer (AgroSpec, tec5 Technology for Spectroscopy, Germany). Before the partial least square regression (PLSR) analysis, the entire reflectance spectra were randomly split into calibration (80%) and validation (20%) sets. A leave-one-out cross-validation PLSR analysis was carried out using the calibration set with Unscrambler (R) software, whereas the model prediction ability was tested using the validation (prediction) set. Models developed were used to predict sand and clay content using on-line collected spectra from the field. Results showed an "excellent" laboratory prediction performance for both sand (R-2 = 0.81, RMSEP = 3.84% and RPD = 2.32 in cross-validation; R-2 = 0.90, RMSEP = 2.91% and RPD = 2.99 in the prediction set) and clay (R-2 = 0.86, RMSEP = 3.4% and RPD = 2.66 in cross validation; R-2 = 0.92, RMSEP = 2.67% and RPD = 3.14 in the prediction set). Modelling of silt did not result in any meaningful correlations. Less accurate on-line predictions were recorded compared to the laboratory results, although the on-line predictions were very good (RPD = 2.24-2.31). On-line predicted maps showed reasonable spatial similarity to corresponding laboratory measured maps. This study proved that soil sand and clay content can be successfully measured and mapped using Vis-NIR spectroscopy under both laboratory and on-line scanning conditions