867 research outputs found
Effects of various additives on sintering of aluminum nitride
Effects of thirty additives on sintering A/N were investigated. The addition of alkali earth oxides and rare earth oxides gave fully densified aluminum nitride. This is due to the formation of nitrogen-containing aluminate liquid in the system aluminum nitride-alkali earth oxides or rare earth oxides. Microstructural studies of the sintered specimens with the above two types of additives suggested that the densification was due to the liquid phase sintering. Additions of silicon compounds resulted in poor densification by the formation of highly refractory compounds such as A/N polytypes
Silicon nitride powder
The characteristics and preparation methods of Si3N4 are reviewed. Special emphasis is placed on the correlation between impurities and strength of sintered Si3N4
Effect of ammonium bisulphite and chloride on the pitting and stress corrosion cracking resistance of super duplex stainless steel pipes under combined internal pressure and axial tension
The financial support of Shell UK is acknowledged. The authors would like to thank the following technical staff, Stuart Herbert, Alistair Robertson for the machining of the mini pipes, Derek Logan, and Irene Brand for resolving several electrical issues and providing accessories, and Jim Gall for help with the test set‐up and prompt supply of tools and equipment.Peer reviewedPostprin
Molecular Clouds associated with the Type Ia SNR N103B in the Large Magellanic Cloud
N103B is a Type Ia supernova remnant (SNR) in the Large Magellanic Cloud
(LMC). We carried out new CO( = 3-2) and CO( = 1-0)
observations using ASTE and ALMA. We have confirmed the existence of a giant
molecular cloud (GMC) at 245 km s towards the
southeast of the SNR using ASTE CO( = 3-2) data at an angular
resolution of 25 (6 pc in the LMC). Using the ALMA CO(
= 1-0) data, we have spatially resolved CO clouds along the southeastern edge
of the SNR with an angular resolution of 1.8 (0.4 pc in the
LMC). The molecular clouds show an expanding gas motion in the
position-velocity diagram with an expansion velocity of km s.
The spatial extent of the expanding shell is roughly similar to that of the
SNR. We also find tiny molecular clumps in the directions of optical nebula
knots. We present a possible scenario that N103B exploded in the wind-bubble
formed by the accretion winds from the progenitor system, and is now
interacting with the dense gas wall. This is consistent with a
single-degenerate scenario.Comment: 12 pages, 1 table, 8 figures, accepted for publication in The
Astrophysical Journal (ApJ
A Versatile cascade of intramolecular vilsmeier-haack and azomethine ylide 1,3-dipolar cycloaddition toward tricyclic cores of alkaloids
Abstract: In the pursuit of synthetic efficiency, we developed an innovative one-pot transformation of linear substrates into bi- and tricyclic adducts using a
cascade of amide activation, nucleophilic cyclization, azomethine ylide generation, and subsequent inter- or intramolecular 1,3-dipolar cycloaddition.
Despite the high density and variety of functional groups on the substrates, the sequence occurred with perfect chemoselectivity with good to
excellent yields
ALMA CO Observations of Supernova Remnant N63A in the Large Magellanic Cloud: Discovery of Dense Molecular Clouds Embedded within Shock-Ionized and Photoionized Nebulae
We carried out new CO( = 1-0, 3-2) observations of a N63A supernova
remnant (SNR) from the LMC using ALMA and ASTE. We find three giant molecular
clouds toward the northeast, east, and near the center of the SNR. Using the
ALMA data, we spatially resolved clumpy molecular clouds embedded within the
optical nebulae in both the shock-ionized and photoionized lobes discovered by
previous H and [S II] observations. The total mass of the molecular
clouds is for the shock-ionized region and
for the photoionized region. Spatially resolved X-ray spectroscopy
reveals that the absorbing column densities toward the molecular clouds are
- cm, which are - times less
than the averaged interstellar proton column densities for each region. This
means that the X-rays are produced not only behind the molecular clouds, but
also in front of them. We conclude that the dense molecular clouds have been
completely engulfed by the shock waves, but have still survived erosion owing
to their high-density and short interacting time. The X-ray spectrum toward the
gas clumps is well explained by an absorbed power-law or high-temperature
plasma models in addition to the thermal plasma components, implying that the
shock-cloud interaction is efficiently working for both the cases through the
shock ionization and magnetic field amplification. If the hadronic gamma-ray is
dominant in the GeV band, the total energy of cosmic-ray protons is calculated
to be - erg with the estimated ISM proton density
of cm, containing both the shock-ionized gas and
neutral atomic hydrogen.Comment: 18 pages, 4 tables, 8 figures, accepted for publication in The
Astrophysical Journal (ApJ
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