5,133 research outputs found

    Data Compression System with a Minimum Time Delay Unit-Patent

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    Minimum time delay unit for conventional time multiplexed data compression channel

    The Influence of Reservoir Basin Morphometry on Phytoplankton Community Structure

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    The research protocol was designed to compare three reservoirs with similar physical environments but different morphometry. Three reservoirs on the western edge of the Ozark uplift were selected because of their similar substrate and climatic condition. The reservoirs primarily differed in morphometry. Two of the reservoirs were of identical size, Bob Kidd and Prairie Groves Lakes, but of different configuration, semicircular and linear, respectively. The bifurcated lake, Lincoln Lake, was of smaller size. Each lake is dimictic. Each of the lakes were nitrate-N limited while soluble reactive phosphorus-P is available and not restricting the growth of phytoplankton. Although the pattern of nutrient utilization was similar among the nutrient concentrations varied. Phytoplankton succession was alike in each reservoir but differed in quantity

    Water Quality Sampling, Analysis and Annual Load Determinations for TSS, Nitrogen and Phosphorus at the Washington County Road 195 Bridge on the West Fork of the White River, 2004 Annual Report

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    A water quality sampling station was installed at the Washington County road 195 bridge on the West Fork of the White River just above the confluence of the three main forks of the Upper White River in December 2001. The Quality Assurance Project Plan (QAPP) was approved by EPA Region six on March 2002 and sampling was begun at that time. This station is coordinated with a USGS gauging station at the same location. This station was instrumented to collect samples at sufficient intervals across the hydrograph to accurately estimate the flux of total suspended solids, nitrogen and phosphorus into the upper end of Beaver Lake from the West Fork of the White River. The West Fork is listed on Arkansas\u27 1998 303d list as impaired from sediment. The Upper White was designated as the states highest priority watershed in the 1999 Unified Watershed Assessment. Accurate determination of stream nutrients and sediment is critical for future determinations of TMDLs, effectiveness of best management practices and trends in water quality

    Water Quality Sampling, Analysis and Annual Load Determinations for TSS, Nitrogen and Phosphorus at the Washington County Road 76 Bridge on Ballard Creek

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    The Illinois River Basin has experienced water quality impairment from non-point source pollution for many years. This fact was well documented in the State of Arkansas\u27 Water Quality Assessment report, the Soil Conservation Service River Basin Study, and several University of Arkansas studies. Thirty-seven sub-watersheds have been identified by the SCS in the Arkansas portion of the Illinois River basin. In the Arkansas portion of the Basin, the Illinois River, Evansville Creek, Baron Fork, Cincinnati Creek, Muddy Fork, Moores Creek, Clear Creek, Osage Creek and Flint Creek were all classified as not supporting their designated use as primary contact recreation streams. The identified causes of the impairment were: sediment, bacteria and nutrients. In 1997, the University of Arkansas completed a project that estimated the phosphorus loading from each of the thirty-seven sub-watersheds. This project also prioritized watersheds for implementation work based on phosphorus loads, nitrogen loads and total suspended solids loads per unit area. The thirty-seven sub-watersheds were grouped into Low (16), Medium (10) and High (11) categories based on phosphorus loadings. If all the sub-watersheds above the median value for on phosphorus loading in the Illinois River basin were brought down to the current median value for phosphorus loading, this reduction would result in the agreed to 40% reduction of phosphorus at the state line. The selection of a sub-watershed for targeted intensive voluntary BMP implementation was based on the following criteria: a) the sub-watershed had to be above the current median value for phosphorus loading, b) there would be no sewage treatment plant in the sub-watershed, and c) land user interest. The Upper Ballard Creek watershed met all these requirements. The watershed covers 6700 hectares. The creek is listed in the High category with a unit area loading of 1.75 kg. per hectare per year. The median value for the thirty-seven watersheds is 0.73 kg. per hectare per year

    Electromagnetic resonances of cylinders and aircraft model with resistive wires

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    The natural frequencies of the electromagnetic resonances of conducting bodies with attached wires were determined. The bodies included twp cylinders and an approximate scale model of the NASA F-106B aircraft. All were three feet in length. Time domain waveforms of B-dot and D-dot were obtained from a sampling oscilloscope, and Prony analysis was used to extract the natural frequencies. The first four natural frequencies of the cylinders (and wires) were determined, and a comparison with calculated results of other investigators shows reasonable agreement. Seven natural frequencies were determined for the F-106B model (with wires), and these were compared with results obtained by NASA in 1982 during direct lightning strikes to the aircraft. The agreement between the corresponding natural frequencies of the model and the aircraft is fairly good and is better than that obtained in the previous work using wires with less resistance. The frequencies lie between 6.5 MHz and 41 MHz, and all of the normalized damping rates are between 0.14 and 0.27

    Electromagnetic resonances of cylinders and aircraft model with resistive wires

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    Laboratory experiments were done to determine the natural frequencies of the electromagnetic resonances of conducting bodies with attached wires. The bodies include two cylinders and an approximate scale model of the NASA F-106B aircraft. All are three feet in length. Time-domain waveforms of B-dot and D-dot were obtained from a sampling oscilloscope, and Prony analysis was used to extract the natural frequencies. This work is an extension of previous work, but smaller, more resistive wires have been used. The first four natural frequencies of the cylinders (and wires) were determined, and a comparison with calculated results of other investigators show reasonable agreement. Seven natural frequencies were determined for the F-106B model (wire wires), and these have been compared with results obtained by NASA in 1982 during direct lightning strikes to the aircraft. The agreement between the corresponding natural frequencies of the model and the aircraft is fairly good and is better than that obtained in the previous work using wires with less resistance. The frequencies lie between 6.5 MHz and 41 MHz, and all of the normalized damping rates are between 0.14 and 0.27

    Structure-Based Rationale for Selectivity in the Asymmetric Allylic Alkylation of Cycloalkenyl Esters Employing the Trost ‘Standard Ligand’ (TSL): Isolation, Analysis and Alkylation of the Monomeric form of the Cationic η3-Cyclohexenyl Complex [(η3-c-C6H9)Pd(TSL)]+

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    The solution-phase structures of the monomeric forms of the cationic Pd-η3-allyl and Pd-η3-cyclohexenyl complexes [Pd(R,R)-1(η3-C3H5)]+ (7+) and [Pd(R,R)-1(η3-C6H9)]+ (8+) bearing the trans-cyclohexylenediamine-based Trost ‘Standard Ligand’ (R,R)-1 have been elucidated by NMR, isotopic labeling and computation. In both complexes, (R,R)-1 is found to adopt a C1-symmetric conformation, leading to a concave shape in the 13-membered chelate in which one amide group in the chiral scaffold projects its NH unit out of the concave surface in close vicinity to one allyl terminus. The adjacent amide has a reversed orientation and projects its carbonyl group out of the concave face in the vicinity of the opposite allyl terminus. Stoichiometric and catalytic asymmetric alkylations of [8+][X−] by MCHE2 (E = ester, M = ‘escort’ counterion, X = Pd allyl counterion) show the same selectivities and trends as have been reported for in situ-generated catalysts, and a new model for the enantioselectivity has been explored computationally. Three factors are found to govern the regioselectivity (pro-S vs pro-R) of attack of nucleophiles on the η3-C6H9 ring in 8+ and thus the ee of the alkylation product: (i) a pro-R torquoselective bias is induced by steric interaction of the η3-C6H9 moiety with one phenyl ring of the ligand; (ii) pro-S delivery of the nucleophile can be facilitated by hydrogen-bonding with the concave orientated amide N−H; and (iii) pro-R delivery of the nucleophile can be facilitated by escort ion (M) binding to the concave orientated amide carbonyl. The latter two opposing interactions lead to the selectivity of the alkylation being sensitive to the identities of X− and M+. The generation of 8+ from cyclohexenyl ester substrate has also been explored computationally. The concave orientated amide N−H is able to activate the leaving group of the allylic ester by hydrogen bonding to its carbonyl group. However, this interaction is only feasible for the (S)-enantiomer of substrate, leading to the prediction of a powerful kinetic resolution (kS kR), as is found experimentally. This new model involving two regiochemically distinct (NH) and (CO) locations for nucleofuge or nucleophile binding, may prove of broad utility for the interpretation of the selectivity in asymmetric allylic alkylation reactions catalyzed by Pd complexes of (R,R)-1 and related ligands.<br/

    Tests of Transfer Reaction Determinations of Astrophysical S-Factors

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    The 16O(3He,d)17F{}^{16}O ({}^{3}He,d) {}^{17}F reaction has been used to determine asymptotic normalization coefficients for transitions to the ground and first excited states of 17F{}^{17}F. The coefficients provide the normalization for the tails of the overlap functions for 17F16O+p{}^{17}F \to{}^{16}O + p and allow us to calculate the S-factors for 16O(p,γ)17F{}^{16}O (p,\gamma){}^{17}F at astrophysical energies. The calculated S-factors are compared to measurements and found to be in very good agreement. This provides the first test of this indirect method to determine astrophysical direct capture rates using transfer reactions. In addition, our results yield S(0) for capture to the ground and first excited states in 17F^{17}F, without the uncertainty associated with extrapolation from higher energies.Comment: 6 pages, 2 figure

    Coherent states for polynomial su(1,1) algebra and a conditionally solvable system

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    In a previous paper [{\it J. Phys. A: Math. Theor.} {\bf 40} (2007) 11105], we constructed a class of coherent states for a polynomially deformed su(2)su(2) algebra. In this paper, we first prepare the discrete representations of the nonlinearly deformed su(1,1)su(1,1) algebra. Then we extend the previous procedure to construct a discrete class of coherent states for a polynomial su(1,1) algebra which contains the Barut-Girardello set and the Perelomov set of the SU(1,1) coherent states as special cases. We also construct coherent states for the cubic algebra related to the conditionally solvable radial oscillator problem.Comment: 2 figure
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