Fate and transport of insensitive high explosives in the environment

The research undertaken for this thesis has contributed to better understanding of the fate and transport on insensitive high explosives (IHE) formulations and suitable extraction methods from soil. Investigations into the dissolution behavior of hexahydro-1,3,5-triazine (RDX) from Polymer Bonded Explosives (PXB) showed that the polymer retained almost 97% of the explosive filling. This indicates that these formulations release their contents slowly although consistently suggesting that cumulative contamination may occur in the environment. Due to low release of RDX from the polymer it was necessary to validate the findings by ensuring all explosives were accounted for. As there was no existing extraction methods for PXB a novel Accelerated Solvent Extraction (ASE) method was successfully developed and optimized. To further understand IHE behaviours in the environment, fate and transport of IHE in soil was then considered. However, as RDX behaviour is well understood attention was then turned to IMX formulations in soil. Again suitable extraction for IHE in soil had not been reported, therefore a comparison of suitable extraction methods for IHE constituents in soil was undertaken. Results showed extraction of IHE is dependent on soil types, which highlighted the need to pre-determine extraction efficiency for soil type and targeted contamination. Therefore pre-testing extraction with known concentrations is recommended. This research was then applied to understanding the behaviour of the mixed constituents in soil, following column transportation studies. Results contributed to and supported work from the literature on the behaviour of individual IHE constituents suggesting that these explosives in combination did not adversely interact with each other when in soil. The novelty of this work was the investigation of IHE as mixtures rather than individually. This work has provided valuable insights into the behaviour of two different IHE (PBX and IMX) in the environment, and has communicated suitable extraction procedures to enable full quantification of contaminant concentrations

The UK Ministry of Defence Project Orientated Environmental Management System (POEMS)

The Project Orientated Environmental Management System (POEMS) is the UK Ministry of Defence (MoD) bespoke environmental management system for the acquisition and use of equipment. The full implementation of a site-specific environmental management system is challenging for the MoD because there are many permanent MoD sites with transient populations, frequently changing site activities and diverse types of equipment. Nevertheless, MoD policy requires that all sites are covered by an environmental management system. POEMS is based on international standards ISO14001 and ISO14040, which focus on environmental management systems and life cycle assessment, respectively. The primary aim of POEMS is to identify and manage any environmental aspects (causes) and impacts (effects) by scrutinising MoD equipment and activities during acquisition, operation and disposal. This is achieved by drawing up a priority list of activities associated with the equipment based on anticipated environmental impact scores, resulting in an environmental management plan that spans the life cycle of the equipment and any corresponding activities. This article describes the POEMS procedure for both experts and non-experts, and demonstrates the implementation of POEMS using a 105-mm artillery round as a theoretical case study. The results anticipated at each stage of the POEMS procedure are discussed in detail, and the documentation necessary to verify the correct application of POEMS is demonstrated

Optimised accelerated solvent extraction of hexahydro‐1, 3, 5‐trinitro‐1, 3, 5 triazine (RDX) from polymer bonded explosives

An Accelerated Solvent Extraction (ASE) method was developed and optimised to extract hexahydro‐1,3,5‐trinitro‐1,3,5‐triazine (RDX) from a polyurethane matrix. The ASE method development was benchmarked against Soxhlet extraction with a view to improving extraction efficiency in terms of time and solvent volume. Key parameters for the ASE method development involved selecting the most appropriate solvent, optimising static time, ensuring a safe oven temperature for explosives, determination of a sufficient number of rinse cycles and effective sample preparation. To achieve optimal extraction, cutting the PBX samples to maximise solvent exposure was essential. The use of acetone with a static time of 10 minutes at 100 °C with three rinse cycles achieved 97 %±10 % extraction of RDX from PBX in 40 minutes using 72 mL solvent. Extraction time was reduced from 48 hours and solvent use by half compared to the standard Soxhlet extraction. To validate the developed ASE method, two other PBX samples containing different quantities of explosive were also fully extracted using the same parameters. Overall, ASE efficiency was comparable to Soxhlet, which places the ASE as a good alternative and shows potential for implementation as a standard method for other polymer based explosives

Release of 1,3,5-trinitroperhydro-1,3,5-triazine (RDX) from polymer-bonded explosives (PBXN 109) into water by artificial weathering

Polymer-bonded explosives (PBX) fulfil the need for insensitive munitions. However, the environmental impacts of PBX are unclear, even though it is likely that PBX residues from low-order detonations and unexploded ordnance are deposited on military training ranges. The release of high explosives from the polymer matrix into the environment has not been studied in detail, although as polymers degrade slowly in the environment we anticipate high explosives to be released into the environment. In this study, PBXN-109 (nominally 64% RDX) samples were exposed to variable UK climatic conditions reproduced in the laboratory to determine the effects of temperature, UV irradiation and rainfall on the release of RDX from the polymer binder. The most extreme conditions for spring, summer and winter in the UK were artificially reproduced. We found that up to 0.03% of RDX was consistently released from PBXN-109. The rate of RDX release was highest in samples exposed to the summer simulation, which had the lowest rainfall, but the highest temperatures and longest UV exposure. This was confirmed by additional experiments simulating an extreme summer month with consistently high temperatures and long periods of sunlight. These results probably reflect the combination of polymer swelling and degradation when samples are exposed to higher temperatures and prolonged UV irradiation

Know thy enemy and know yourself – the role of operational data in managing the mines and booby trap threat in vietnam, 1965–73

Victim operated explosive devices (VOEDs) such as mines and booby traps, have been an enduring problem since their large-scale use started in the 1940s. While the overall problem is often known about in general terms, the real complexion of the problem was not necessarily fully appreciated. Eventually the need to understand the problem and the response to it was partially identified and acted upon in Vietnam through the collection and analysis of operational data. This did not solve the problem of mines and booby traps, but it did offer a means to better manage the threat

Operational data for the risk management of victim operated explosive devices in humanitarian mine action: a practitioner’s perspective

Since Mine Action's inception at the end of the 1980s, operators have collected limited data on the Victim Operated Explosive Devices (VOEDs) they clear. This includes not only data on the explosive ordnance itself but data on how they were found, where they were found and how they were processed and ultimately destroyed. In a context where detection of mines, boobytraps and certain Victim Operated Improvised Explosive Devices (VOIEDs) is an ongoing humanitarian and military challenge, significantly expanded operational data collection provides an achievable way to facilitate enhanced operational risk management. Risk decisions inherent in the clearance of VOEDs are better if made on the basis of extensive operational data. In the absence of a technological solution to detect and positively discriminate VOEDs from false positive indications, the collection of operational data offers the best prospect for “managing” if not “solving” the problem

The detection problem: an eight-decade challenge: the difficulty of practically detecting and discriminating mines, booby traps, and victim operated improvised explosive devices

© The AuthorsReliably detecting and discriminating mines, booby traps, and victim operated improvised explosive devices remains a stubborn problem for both humanitarian demining organizations and the military. Since mines were widely used during the Second World War, much effort has been expended on the detection problem, with limited success. The aim of being able to positively identify a device first time remains elusive since the scientific challenge of positively identifying different substances in the ground is formidable. This article critically examines the detection problem and suggests that in the continued absence of a ‘silver bullet’ technological solution, the best means currently available to manage the risk of concealed explosive devices is the systematic collection and analysis of relevant operational data from the field

Investigation into the environmental fate of the combined Insensitive High Explosive constituents 2, 4-dinitroanisole (DNAN), 1-nitroguanidine (NQ) and nitrotriazolone (NTO) in soil

Contamination of military ranges by the use of explosives can lead to irreversible environmental damage, specifically to soil and groundwater. The fate and effects of traditional explosive residues are well understood, while less is known about the impact of Insensitive High Explosives (IHEs) that are currently being brought into military service. Current research has focussed on the investigation of individual constituents of IHE formulations, which may not be representative of real-world scenarios when explosive residues will be deposited together. Therefore, this study investigated the fate and transport of the combined IHE constituents 2,4-dinitroanisole (DNAN), 1-nitroguanidine (NQ) and 3-nitro-1,2,4-triazol-5-one (NTO) in two UK soil types. Static experiments ran for 9 weeks to determine the fate of the combined explosive constituents in soil by monitoring the rate of degradation. Transport was examined by running soil column experiments for 5 weeks, with a watering regime equivalent to the average yearly UK rainfall. Both static and soil column experiments confirmed that DNAN and NTO started to degrade within twenty-four hours in soil with high organic content, and were both completely degraded within sixty days. NQ was more stable, with 80% of the original material recovered after sixty days. The major degradation product of DNAN in the test soils was 2-amino-4-nitroanisole (2-ANAN), with trace amounts of 4-amino-2-nitroanisole. NTO was rapidly degraded in soil with high organic content, although no degradation products were identified. Results supported work from literature on the individual constituents DNAN, NQ and NTO suggesting that the three explosives in combination did not interact with each other when in soil. This study should provide a useful insight into the behaviour of three combined Insensitive High Explosive constituents for the predication of soil and water contamination during military training

Investigation of energetic particle distribution from high-order detonations of munitions

Military training with munitions containing explosives will result in the deposition of energetic materials on ranges. These residues contain compounds that may result in human health impacts when off-range migration occurs. Models exist that predict the spatial and mass distribution of particles, but they have proven to be difficult to apply to detonating munitions. We have conducted a series of tests to determine if modelling results can be directly applied to simple detonation scenarios. We also command detonated several rounds to obtain an initial indication of high-order detonation particle distributional heterogeneity. The detonation tests indicate that particle distributions will be quite heterogeneous and that the model used did not adequately describe the distribution of detonation residues. This research will need to be expanded to build an empirical database sufficient to enable the refinement of existing models and improve their predictions. Research on low-order detonations should be conducted as low-order detonations will result in higher mass deposition than high-order detonations. Distribution models verified with empirical data may then be incorporated into range management models

The use of a predictive threat analysis to propose revisions to existing risk assessments for precursor chemicals used in the manufacture of home-made explosives (HME)

Improvised explosive devices (IEDs) have generated over 137,000 civilian casualties in the past decade, more than any other explosive weapon system in the same period with a far-reaching impact on personal security freedoms across 50 affected countries. The aim of this paper is to consolidate existing risk management processes to control the availability of chemical precursors used in the manufacture of home-made explosives (HME) and to recommend global standards for market regulations in their composition, sale and use. This will be achieved by assessing the current regional regulations for three common chemical precursors (hydrogen peroxide, ammonium nitrate and potassium chlorate), and proposing a risk management process to identify key precursor chemicals that require greater control